A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

An electrochemical energy conversion device 10 comprising a stack of solid oxide electrochemical cells 12 alternating with gas separators 14, 16, wherein scavenger material selected from one or both of free alkali metal oxygen-containing compounds and free alkaline earth metal oxygen-containing compounds is provided in or on one or more of the positive electrode-side of the cell 12, the adjacent gas separator 14 and any other structure of the device 10 forming a gas chamber 64 between the cell and the gas separator. The invention also extends to the treated cell 12.

An electrochemical energy conversion device 10 comprising a stack of solid oxide electrochemical cells 12 alternating with gas separators 14, 16, wherein scavenger material selected from one or both of free alkali metal oxygen-containing compounds and free alkaline earth metal oxygen-containing compounds is provided in or on one or more of the positive electrode-side of the cell 12, the adjacent gas separator 14 and any other structure of the device 10 forming a gas chamber 64 between the cell and the gas separator. The invention also extends to the treated cell 12.

A fuel cell device includes: a reformer that generates a reformed gas; a fuel cell; a combustor that combusts off-gas of the reformed gas and air for power generation, and generates a combustion exhaust gas; a first air heat exchanger that has a combustion exhaust gas path and a first air supply path, and that performs heat exchange between the combustion exhaust gas and the air for power generation; a fuel cell storage which stores the fuel cell; a second air heat exchanger that has a second air supply path that supplies the air for power generation to the fuel cell, and that performs heat exchange between the off-gas of the air for power generation and the air for power generation; and a housing that stores members. The first air supply path and the second air supply path are disposed to cover whole members stored in the housing.

A fuel cell device includes: a reformer that generates a reformed gas; a fuel cell; a combustor that combusts off-gas of the reformed gas and air for power generation, and generates a combustion exhaust gas; a first air heat exchanger that has a combustion exhaust gas path and a first air supply path, and that performs heat exchange between the combustion exhaust gas and the air for power generation; a fuel cell storage which stores the fuel cell; a second air heat exchanger that has a second air supply path that supplies the air for power generation to the fuel cell, and that performs heat exchange between the off-gas of the air for power generation and the air for power generation; and a housing that stores members. The first air supply path and the second air supply path are disposed to cover whole members stored in the housing.

An onboard electrochemical system of an electrochemical cell including a cathode and an anode separated by an electrolyte separator is selectively operated in either of two modes. In a first mode of operation, water or air is directed to the anode, electric power is provided to the anode and cathode to provide a voltage difference between the anode and the cathode, and nitrogen-enriched air is directed from the cathode to an aircraft fuel tank or aircraft fire suppression system. In a second mode of operation, fuel is directed to the anode, electric power is directed from the anode and cathode to one or more aircraft electric power-consuming systems or components, and nitrogen-enriched air is directed from the cathode to a fuel tank or fire suppression system.

An onboard electrochemical system of an electrochemical cell including a cathode and an anode separated by an electrolyte separator is selectively operated in either of two modes. In a first mode of operation, water or air is directed to the anode, electric power is provided to the anode and cathode to provide a voltage difference between the anode and the cathode, and nitrogen-enriched air is directed from the cathode to an aircraft fuel tank or aircraft fire suppression system. In a second mode of operation, fuel is directed to the anode, electric power is directed from the anode and cathode to one or more aircraft electric power-consuming systems or components, and nitrogen-enriched air is directed from the cathode to a fuel tank or fire suppression system.

An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.

An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.