An electrochemical apparatus includes: a reformer that produces a first hydrogen-containing gas by reforming a raw material; a combustor that heats the reformer; an electrochemical device that includes an anode and a cathode, the electrochemical device operating by using the first hydrogen-containing gas supplied to the anode; a first flow rate controller that controls a flow rate of the first hydrogen-containing gas supplied to the anode and a flow rate of a second hydrogen-containing gas supplied from a supply source, the second hydrogen-containing gas being different from the first hydrogen-containing gas; a second flow rate controller that controls a flow rate at which an anode-off gas exhausted from the anode is recycled to the anode and a flow rate at which the anode-off gas is supplied to the combustor; and a controller that controls the first flow rate controller and the second flow rate controller.

An electrochemical apparatus includes: a reformer that produces a first hydrogen-containing gas by reforming a raw material; a combustor that heats the reformer; an electrochemical device that includes an anode and a cathode, the electrochemical device operating by using the first hydrogen-containing gas supplied to the anode; a first flow rate controller that controls a flow rate of the first hydrogen-containing gas supplied to the anode and a flow rate of a second hydrogen-containing gas supplied from a supply source, the second hydrogen-containing gas being different from the first hydrogen-containing gas; a second flow rate controller that controls a flow rate at which an anode-off gas exhausted from the anode is recycled to the anode and a flow rate at which the anode-off gas is supplied to the combustor; and a controller that controls the first flow rate controller and the second flow rate controller.

Solid-state energy harvesters comprising layers of metal suboxides and cerium dioxide utilizing a solid-state electrolyte to produce power and methods of making and using the same are provided. The solid-state energy harvester may have two or three electrodes per cell and produces power in the presence of water vapor and oxygen.

Solid-state energy harvesters comprising layers of metal suboxides and cerium dioxide utilizing a solid-state electrolyte to produce power and methods of making and using the same are provided. The solid-state energy harvester may have two or three electrodes per cell and produces power in the presence of water vapor and oxygen.

A planar SOFC cell unit is formed from a plurality of planar elements (1100, 1200, 1300) stacked one above another. The cell unit encloses a cell chamber (1400) that includes a solid oxide fuel cell (2000) configured for electro-chemical generation, compliantly supported within the cell chamber. The plurality planar elements each comprise a thermally conductive material having a co-efficient of thermal conductivity that is a least 100 W/mK such as aluminum or copper. The planar elements are thermally conductively coupled to each other to provide a continuous thermally conductive pathway that extends from perimeter edges of the cell chamber to perimeter edges of the plurality of planar elements. An SOFC stack comprises a plurality of the planar SOFC cell units stacked one above another.

A planar SOFC cell unit is formed from a plurality of planar elements (1100, 1200, 1300) stacked one above another. The cell unit encloses a cell chamber (1400) that includes a solid oxide fuel cell (2000) configured for electro-chemical generation, compliantly supported within the cell chamber. The plurality planar elements each comprise a thermally conductive material having a co-efficient of thermal conductivity that is a least 100 W/mK such as aluminum or copper. The planar elements are thermally conductively coupled to each other to provide a continuous thermally conductive pathway that extends from perimeter edges of the cell chamber to perimeter edges of the plurality of planar elements. An SOFC stack comprises a plurality of the planar SOFC cell units stacked one above another.

In this disclosure, an ion-conducting membrane (10), a component (100) having the ion-conducting membrane (10) and a process for making the membrane (10) and the component (100) are disclosed. The ion-conducting membrane (10) includes a homogenous blend (12) and one or more additives (14). The selected one or more polymers are present in a mass-percentage in a range from 1% to 40. The present ion-conducting membrane (10) simultaneously increases the power and efficiency of the devices by combining advances in materials chemistry, nanotechnology, and manufacturing. The present ion-conducting membrane (10) overcomes limitations in the currently known technologies without compromising the advantageous properties. The present membrane (10) provides non-linear performance enhancement in electrochemical devices that leads to overall system level cost reduction.

In this disclosure, an ion-conducting membrane (10), a component (100) having the ion-conducting membrane (10) and a process for making the membrane (10) and the component (100) are disclosed. The ion-conducting membrane (10) includes a homogenous blend (12) and one or more additives (14). The selected one or more polymers are present in a mass-percentage in a range from 1% to 40. The present ion-conducting membrane (10) simultaneously increases the power and efficiency of the devices by combining advances in materials chemistry, nanotechnology, and manufacturing. The present ion-conducting membrane (10) overcomes limitations in the currently known technologies without compromising the advantageous properties. The present membrane (10) provides non-linear performance enhancement in electrochemical devices that leads to overall system level cost reduction.

A fuel cell system may include: a reformer performing a reforming process of producing hydrogen gas from a gasified fuel; a burner supplying heat to the reformer; a stack generating electrical energy by generating an electrochemical reaction using reforming gas and air discharged from the reformer; a first supply pipe supplying external air to the burner; a second supply pipe supplying external air to the stack; a first storage tank storing a liquid fuel; a second storage tank supplying a gasified fuel to the reformer; and a fuel evaporator making a liquid fuel discharged from the first storage tank exchange heat with air flowing through the first supply pipe or air flowing through the second supply pipe, and sending a gasified gaseous fuel to the second storage tank.

A fuel cell system may include: a reformer performing a reforming process of producing hydrogen gas from a gasified fuel; a burner supplying heat to the reformer; a stack generating electrical energy by generating an electrochemical reaction using reforming gas and air discharged from the reformer; a first supply pipe supplying external air to the burner; a second supply pipe supplying external air to the stack; a first storage tank storing a liquid fuel; a second storage tank supplying a gasified fuel to the reformer; and a fuel evaporator making a liquid fuel discharged from the first storage tank exchange heat with air flowing through the first supply pipe or air flowing through the second supply pipe, and sending a gasified gaseous fuel to the second storage tank.