A fuel cell system includes a fuel cell stack having a plurality of fuel cells that each contain a plurality of fuel electrodes and air electrodes. The system includes a fuel receiving unit connected to the fuel cell stack, which receives a hydrocarbon fuel from a fuel supply. The system includes a fuel exhaust processing unit fluidly coupled to the fuel cell stack by a slip stream, where the fuel exhaust processing unit processes fuel exhaust from the fuel cell stack, and the slip stream is fluidly connected to an exhaust stream flowing from the fuel cell stack. The fuel processing unit removes a first portion of carbon dioxide (CO.sub.2) from fuel exhaust within the slip stream, outputs the first portion of CO.sub.2 in a first stream, and outputs a second portion of CO.sub.2 remaining from the fuel exhaust in the slip stream into a second stream, which includes hydrogen.

A high temperature electrolyzer assembly comprising at least one electrolyzer fuel cell including an anode and a cathode separated by an electrolyte matrix, and a power supply for applying a reverse voltage to the at least one electrolyzer fuel cell, wherein a gas feed comprising steam and one or more of CO2 and hydrocarbon fuel is fed to the anode of the at least one electrolyzer fuel cell, and wherein, when the power supply applies the reverse voltage to the at least one electrolyzer fuel cell, hydrogen-containing gas is generated by an electrolysis reaction in the anode of the at least one electrolyzer fuel cell and carbon dioxide is separated from the hydrogen-containing gas so that the at least one electrolyzer fuel cell outputs the hydrogen-containing gas and separately outputs an oxidant gas comprising carbon dioxide and oxygen.

A fuel cell system includes a molten carbonate fuel cell module including an anode section configured to output an anode exhaust stream including carbon dioxide and hydrogen and a cathode section configured to receive a cathode input stream. The fuel cell system further includes a drying system configured to receive and remove water from the anode exhaust stream and to output a dried anode exhaust stream comprising less than 0.1 percent water and a carbon dioxide solvent extraction system configured to receive the dried anode exhaust stream, expose the dried anode exhaust stream to a physical solvent to absorb carbon dioxide, output a carbon dioxide product stream comprising at least 99 percent carbon dioxide, and output a sweet gas stream.

A high temperature electrolyzer assembly comprising at least one electrolyzer fuel cell including an anode and a cathode separated by an electrolyte matrix, and a power supply for applying a reverse voltage to the at least one electrolyzer fuel cell, wherein a gas feed comprising steam and one or more of CO2 and hydrocarbon fuel is fed to the anode of the at least one electrolyzer fuel cell, and wherein, when the power supply applies the reverse voltage to the at least one electrolyzer fuel cell, hydrogen-containing gas is generated by an electrolysis reaction in the anode of the at least one electrolyzer fuel cell and carbon dioxide is separated from the hydrogen-containing gas so that the at least one electrolyzer fuel cell outputs the hydrogen-containing gas and separately outputs an oxidant gas comprising carbon dioxide and oxygen.