The present invention relates to an improved metal supported solid oxide fuel cell unit, fuel cell stacks, fuel cell stack assemblies, and methods of manufacture.

A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces that pass through the metal support from a front face to a back face. The front face is a face to be provided with an electrode layer. Each of front-side openings that are openings of the penetration spaces formed in the front face has an area of 3.0×10.sup.−4 mm.sup.2 or more and 3.0×10.sup.−3 mm.sup.2 or less.

To provide a conductive member and a cell stack, where a concave groove of a conductive base substrate can be covered with a cover layer, as well as an electrochemical module and an electrochemical device.

A fuel cell module includes a first area where an exhaust gas combustor and a start-up combustor are provided, a second area where a reformer and a heat exchanger are provided, a third area where an evaporator is provided, and a condensed water recovery mechanism for recovering condensed water produced by condensation of water vapor contained in the combustion gas by allowing the condensed water to flow from the third area to the second area and then flow from the second area to the first area.

A fuel cell module includes a first area where an exhaust gas combustor and a start-up combustor are provided, a second area where a reformer and a heat exchanger are provided, a third area where an evaporator is provided, and a condensed water recovery mechanism for recovering condensed water produced by condensation of water vapor contained in the combustion gas by allowing the condensed water to flow from the third area to the second area and then flow from the second area to the first area.

An article having a metallic layer and a glass layer, and a method for preventing or reducing a chemical reaction between a metallic layer and a glass layer are disclosed. The article has a barrier layer disposed between the metallic layer and the glass layer. The barrier layer includes alumina and a phosphate. The phosphate includes an aluminum dihydrogen phosphate, an aluminum-containing phosphate, a phosphate of an element of the metallic layer, a phosphate of an element of the glass layer, or combinations thereof. The method includes disposing a barrier layer between the metallic layer and the glass layer.

An article having a metallic layer and a glass layer, and a method for preventing or reducing a chemical reaction between a metallic layer and a glass layer are disclosed. The article has a barrier layer disposed between the metallic layer and the glass layer. The barrier layer includes alumina and a phosphate. The phosphate includes an aluminum dihydrogen phosphate, an aluminum-containing phosphate, a phosphate of an element of the metallic layer, a phosphate of an element of the glass layer, or combinations thereof. The method includes disposing a barrier layer between the metallic layer and the glass layer.

Various hot box fuel cell system components are provided, such as heat exchangers, steam generator and other components.

Various hot box fuel cell system components are provided, such as heat exchangers, steam generator and other components.

The invention relates to a rechargeable battery and a method to operate a rechargeable battery having high efficiency and high energy density for storing energy. The battery stores electrical energy in the bonds of carbon and oxygen atoms by converting carbon dioxide into solid carbon and oxygen.