To provide a fuel cell device capable of extending the years of service life of a reformer by suppressing thermal runaways. The present invention is a solid oxide fuel cell device, including a fuel cell module having fuel cell units; a reformer disposed above the fuel cell units, for producing hydrogen by a partial oxidation reforming reaction and a steam reforming reaction; a vaporizing chamber disposed adjacent to the reformer; a combustion chamber for heating the vaporization chamber; a water supply device; an electrical generation oxidant gas supply device; and a controller for raising the fuel cell units to a temperature at which electrical generation is possible; whereby over the entire period of the startup step, the reforming oxidant gas supply device and water supply device are controlled so that partial oxidation reforming reactions do not occur independently in the reformer.

An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.

An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.

A solid electrolytic fuel battery having a battery structure part that includes a plurality of cells each composed of fuel electrode layers, a solid electrolytic layer, and air electrode layers. A cell separation part is arranged between the plurality of cells, and formed of a material containing ceramics. A gas supply path structure part has fuel gas supply paths to supply a fuel gas to each cell, and an air supply path to supply air to each cell. The air supply path is arranged in an inside of the battery structure part.

A solid electrolytic fuel battery having a battery structure part that includes a plurality of cells each composed of fuel electrode layers, a solid electrolytic layer, and air electrode layers. A cell separation part is arranged between the plurality of cells, and formed of a material containing ceramics. A gas supply path structure part has fuel gas supply paths to supply a fuel gas to each cell, and an air supply path to supply air to each cell. The air supply path is arranged in an inside of the battery structure part.

Disclosed is a high-temperature operating fuel cell system including: a fuel cell stack; a combustor that combusts a cathode off-gas and an anode off-gas; a heat insulator that covers at least part of the fuel cell stack and at least part of the combustor; a first preheater that covers at least part of the heat insulator and preheats an oxidant gas; an oxidant gas feeder that supplies the oxidant gas to the first preheater; a vacuum heat insulator that covers at least part of the first preheater; a sensor that detects information indicating stopping of a power generation operation; and a controller. When a determination is made that the power generation has stopped, the controller controls the oxidant gas feeder to supply the oxidant gas to the first preheater so that the temperature of the vacuum heat insulator is equal to or lower than a prescribed temperature.

Disclosed is a high-temperature operating fuel cell system including: a fuel cell stack; a combustor that combusts a cathode off-gas and an anode off-gas; a heat insulator that covers at least part of the fuel cell stack and at least part of the combustor; a first preheater that covers at least part of the heat insulator and preheats an oxidant gas; an oxidant gas feeder that supplies the oxidant gas to the first preheater; a vacuum heat insulator that covers at least part of the first preheater; a sensor that detects information indicating stopping of a power generation operation; and a controller. When a determination is made that the power generation has stopped, the controller controls the oxidant gas feeder to supply the oxidant gas to the first preheater so that the temperature of the vacuum heat insulator is equal to or lower than a prescribed temperature.

A high-temperature operating fuel-cell module includes a fuel-cell stack; a fuel-cell stack container in which the fuel-cell stack is contained and cathode off-gas discharged from the fuel-cell stack flows; a cathode off-gas collector that is provided in the fuel-cell stack container and in which the cathode off-gas is collected; an anode off-gas passage through which anode off-gas discharged from the fuel-cell stack flows; and a combustor that combusts the cathode off-gas collected in the cathode off-gas collector and the anode off-gas flowing through the anode off-gas passage, the combustor comprising: a combustion chamber in which the anode and cathode off-gas are mixed and combusted, an ejector that is connected to the anode off-gas passage and ejects the anode off-gas into the combustion chamber, and a diffusion plate that surrounds the ejector so that the ejector is located at the center of the diffusion plate, and ejects the cathode off-gas into the combustion chamber.

A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.