Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A solid electrolyte film for sulfide-based all-solid-state batteries, and more particularly a composition of a solid electrolyte, a binder, and a solvent used to manufacture a solid electrolyte film for sulfide-based all-solid-state batteries that is thin and has high ion conductivity. In particular, a solid electrolyte film composition for sulfide-based all-solid-state batteries including a solvent having a dielectric constant of x (1.5<x<3.0). The thickness of a solid electrolyte film for sulfide-based all-solid-state batteries manufactured using the solid electrolyte film composition is 60 m or less, and the solid electrolyte film is capable of being stably used for at least 1000 hours or more, and up to 2000 hours, based on the evaluation of Li plating and stripping.

Solid-state lithium ion electrolytes of lithium borate based composites are provided which contain an anionic framework capable of conducting lithium ions. Materials of specific formulae are provided and methods to alter the materials with inclusion of aliovalent ions shown. Lithium batteries containing the composite lithium ion electrolytes are provided. Electrodes containing the lithium borate based materials and batteries containing the electrodes are also provided.

Solid-state lithium ion electrolytes of lithium borate based composites are provided which contain an anionic framework capable of conducting lithium ions. Materials of specific formulae are provided and methods to alter the materials with inclusion of aliovalent ions shown. Lithium batteries containing the composite lithium ion electrolytes are provided. Electrodes containing the lithium borate based materials and batteries containing the electrodes are also provided.

A solid electrolyte for an all-solid secondary battery, wherein the solid electrolyte has a composition represented by Formula (1):
Li.sub.7-xPS.sub.6-xBr.sub.x(1)
wherein 1.2<x<1.75, the solid electrolyte has an argyrodite crystal structure, and the solid electrolyte has at least one peak at a position of a 29.650.50 2 when analyzed by X-ray diffraction using CuK radiation.

A solid electrolyte for an all-solid secondary battery, wherein the solid electrolyte has a composition represented by Formula (1):
Li.sub.7-xPS.sub.6-xBr.sub.x(1)
wherein 1.2<x<1.75, the solid electrolyte has an argyrodite crystal structure, and the solid electrolyte has at least one peak at a position of a 29.650.50 2 when analyzed by X-ray diffraction using CuK radiation.

Provided is a lithium secondary battery, comprising a cathode, an anode, and a porous separator or electrolyte, wherein the anode comprises: (a) an anode active layer containing a layer of lithium or lithium alloy, in a form of a foil, coating, or multiple particles aggregated together, as an anode active material; (b) a first anode-protecting layer having a thickness from 1 nm to 100 m (preferably <1 m and more preferably <100 nm) and comprising a lithium ion-conducting material having a lithium ion conductivity from 10.sup.8 S/cm to 510.sup.2 S/cm; and (c) a second anode-protecting layer having a thickness from 1 nm to 100 m and comprising an elastomer having a fully recoverable tensile elastic strain from 2% to 1,000% and a lithium ion conductivity from 10.sup.8 S/cm to 510.sup.2 S/cm.

Methods for producing ceramic films Yttria Stabilized Zirconia (3YSZ) and aluminum titanate (Al.sub.2TiO.sub.5), and the physical properties of these films are described. The films produced have thicknesses and integrity suitable for handling and corrosion resistance to electrolytes, porosity, ion permeability and electrical resistivity suitable for use as separators between positive and negative layers for forming electrical batteries, particularly lithium batteries.

The present disclosure relates to a novel surface-modified carbonaceous particulate material having a hydrophilic non-graphitic carbon coating. The material can for example be produced by CVD-coating of a carbonaceous particulate material such as graphite followed by an oxidation treatment under defined conditions. The resulting material exhibits a more hydrophilic surface compared to an unmodified CVD-coated carbon material, which is desirable in many applications, such as when used as an active material in the negative electrode of lithium ion batteries or in a polymer composite material.