Provided is a sheet-type cell with excellent reliability. The sheet-type cell of the present invention includes power generation elements, including a positive electrode, a negative electrode, a separator, and an electrolyte solution, and a sheet-type outer case made of a resin film in which the power generation elements are contained. The electrolyte solution is an aqueous electrolyte solution. The resin film has an electrically insulating moisture barrier layer. The sheet-type cell is a primary cell. The moisture barrier layer of the resin film is preferably composed of at least an inorganic oxide. The pH of the electrolyte solution is preferably 3 or more and less than 12.

Aluminum-air battery units and stacks are provided with frames configured to mechanically support the anode of each unit, within a housing configured to support the frame and the air cathode(s) mechanically, sealably hold the electrolyte within the housing and in fluid communication with openings in the housingforming one or two sided electrochemical cell in each unit. The frame comprises a protective strap configured to protect edges of the rectangular anode against corrosion by the electrolyte during operation, and also an external trapezoid shape that is configured to press the protective strap against the edges of the rectangular anode upon insertion of the frame with the anode into the housing. Various embodiments comprise, spacers between the anode and cathodes and grids supporting airways to the cathodes. In disclosed configurations, anode may be replaced after electrolyte evacuation while maintaining the stack sealed and quickly ready for renewed operation.

A battery case containing an electrode group including an air electrode and a separator includes main walls on which the air electrode is opposingly disposed and a surrounding portion that is disposed at marginal portions of the main walls and that surrounds a side edge portion of the opposingly disposed air electrode. The surrounding portion is covered by an edge portion of the separator disposed opposing the air electrode.

Disclosed in the invention is a zinc-iodine battery structure, which includes a housing, a cavity is formed in the housing, and a cation exchange membrane for dividing the cavity into two parts is disposed in a middle of the cavity; a glass fiber component for protecting the cation exchange membrane is disposed at a negative output end; a graphite felt impregnated with a ZnI.sub.2 solution is disposed on an outside of the glass fiber component; and the graphite felt of the negative output end is coated with Bi powder, and a graphite felt of a positive output end is coated with Sm powder. Carbon plates serving as current leading-out channels of a battery are disposed on outsides of the graphite felts; and a return flow channel is disposed between the two graphite felts. By using a homogeneous cation exchange membrane with a low electrical resistance, a problem of serious self-discharging is overcome; and by using a flow battery with an open flow system, a problem of a change in pressure caused by a change in volume during charging and discharging is effectively solved. By disposing glass fiber products on two sides of the cation exchange membrane, a dendritic crystal generated during charging is unable to reach a separator, so that short circuit caused by puncture of the separator is avoided.

The utility model provides a liquid-proof metal-air electrode component and a metal-air cell. The liquid-proof metal-air electrode component comprises: a plastic bottom shell, an air electrode and a metal electrode, wherein the metal electrode and the air electrode are respectively provided on the back surface and the front surface of the plastic bottom shell, the metal electrode is fixed to the plastic bottom shell, and the periphery of the air electrode is encapsulated in the plastic bottom shell. The utility model further provides a metal-air cell using the liquid-proof metal-air electrode component. In the liquid-proof metal-air electrode component, an injection molding edge sealing is formed on the periphery of the air electrode, which ensures the sealing performance between the air electrode and the plastic bottom shell, and compared with the fixing method using screws and other fixing parts, it has better sealing performance and product consistency.

In a battery casing a metal negative electrode that contains metal serving as a negative electrode active material and an air electrode are arranged so as to face each other in a state where at least a part of the metal negative electrode and the air electrode is immersed in an electrolytic solution inside a casing. The metal negative electrode is housed in a negative electrode housing in the casing. A separator separating the metal negative electrode and the air electrode is arranged at a side surface of the negative electrode housing. An opening through which inside of the negative electrode housing and outside of the negative electrode housing communicate with each other is provided on an upper surface of the negative electrode housing.

An object is especially to provide a metal-air battery unit that has a compact configuration including a water supply space and an electrical system space. The metal-air battery unit of the present invention includes a unit main body including a plurality of metal-air battery cells, a water supply space supplying an electrolyte to the metal-air battery cells and an electrical system space coupling to a positive electrode and a negative electrode of the metal-air battery cell to control a battery output, disposed on an outer surface of the unit main body.

A metal air battery according to one embodiment of the present invention includes a pair of air cathodes having planar shapes respectively, which have a first bonding portion bonded along edges of the pair of the air cathodes and are disposed to face each other; a pair of separators disposed in contact with the pair of the air cathodes; an anode having a planar shape disposed between the pair of the separators and electrically insulated from the pair of the air cathodes; and then a zinc gel disposed in an accommodation space between the pair of the air cathodes. The accommodation space is a space formed by elastic deformation of the pair of the air cathodes.

The present technology provides a battery that includes an air cathode, an anode, an aqueous electrolyte that includes an amphoteric surfactant, and a housing that includes one or more air access ports defining a total area of void space (vent area), where (1) the battery is a size 13 metal-air battery and the total vent area defined by all of the air access ports is from about 0.050 mm.sup.2 to about 0.115 mm.sup.2; or (2) the battery is a size 312 metal-air battery and the total vent area defined by all of the air access ports is from about 0.03 mm.sup.2 to about 0.08 mm.sup.2.

A zinc-air battery includes an air cathode, a zinc anode, an electrolyte, and a housing, wherein the zinc-air battery includes a carbon dioxide scrubbing agent. A packaging for a zinc-air battery, wherein the packing includes a chamber having a carbon dioxide scrubbing agent, and the chamber is configured to contain the zinc-air battery during storage.