The present disclosure pertains to motion-generating mechanisms for desulfation of lead-acid batteries, lead-acid batteries including such motion-generating mechanisms, and methods of making and using the same. For example, the present disclosure provides a lead-acid battery that includes one or more electroactive plates disposed within a casing; an electrolyte disposed within the casing and surrounding the electroactive plates; and one or more movable members disposed on or adjacent to one or more interior surfaces of the casing and in communication with the electrolyte. The one or more movable members each have a first position and a second position and movement between the first position and the second position agitates the electrolyte.

Provided is an electrolyte for a flow battery, the electrolyte being supplied to a flow battery, in which a total concentration of ions of elements of groups 1 to 8 and ions of elements of groups 13 to 16 in the fifth period of the periodic table, and ions of elements of groups 1, 2, and 4 to 8 and ions of elements of groups 13 to 15 in the sixth period of the periodic table, the ions being impurity element ions involved in generation of a gas containing elemental hydrogen, may be 610 mg/L or less and a concentration of vanadium ions may be 1 mol/L or more and 3 mol/L or less.

In one or more embodiment described herein, a precursor of an active material of an electrode of a lead-acid battery may be made by a process that includes forming an active material paste and curing the active material paste to form the precursor of the active material of the electrode of the lead-acid battery. The active material paste may be made by combining at least water, an acid, a glass composition having at least 25 wt. % of a single metal oxide, and lead oxide. The metal oxide may be selected from barium oxide, lead oxide, zinc oxide, or antimony oxide.

Disclosed is a lead acid battery having a negative electrode plate and a positive electrode plate, each plate formed of a lead-antimony grid coated with an active material. A separator is disposed between the first and second electrode plate faces and an electrolyte solution immersing the negative electrode plate, the positive electrode plate the separator. At least one of the lead-antimony electrode grids, the separator or the electrolyte solution contains TiO.sub.2, an amount sufficient to suppress the migration of antimony from the positive electrode plate to the negative electrode plate.

Provided herein is a redox flow battery comprising an anode comprising anodic redox mediators; a negative electrolyte tank comprising an anolyte; and an anode pump capable of circulating the anolyte through the anode. The redox flow battery further comprises a cathode comprising cathodic redox mediators; a positive electrolyte tank comprising a catholyte and a cathode pump capable of circulating the catholyte through the cathode. A separator is between the anode and cathode.

The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.

Methods of reducing acid stratification with an acid-soluble and acid-stable polymer with a high molecular weight are disclosed herein. Electrolytes and separators for an energy storage device are disclosed herein. The separator includes a coating containing an acid-soluble and acid-stable polymer with a high molecular weight. The electrolyte includes sulfuric acid and an acid-soluble and acid-stable polymer with a high molecular weight. Methods of making the separators disclosed herein and methods of making batteries are also disclosed herein.

A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

Provided are passivation layers for batteries. The batteries may be aqueous aluminum batteries. The passivation layer may be disposed on a portion of or all of a surface or surfaces of an anode, which may be an aluminum or aluminum alloy anode. The passivation layer is bonded to the surface of the anode. The passivation layer may be an organic, nitrogen-rich material and inorganic Al-halide rich or Al-nitrate rich material. The passivation layer may be formed by contacting an aluminum or aluminum alloy substrate, which may be aluminum or aluminum alloy anode, with one or more aluminum halide and one or more ionic liquid.

A flow battery that includes an electrode and a catholyte including a sulfate solution where, during charge of the flow battery, the sulfate solution becomes a persulfate solution, and during discharge of the flow battery, the persulfate solution becomes a sulfate solution. The electrode may be an anolyte, or it may be an amorphous metal electrode.