A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

Provided is a technique with high strength, superior ionic conductivity, and superior electrical characteristics.

A lithium ion secondary battery includes a positive electrode, a negative electrode, and a polymer electrolyte. The polymer electrolyte contains a lithium salt, an ionic liquid, and a polymer. The ionic liquid contains a bis(fluorosulfonyl)imide anion as an anion component. The content of the lithium salt is 2 mol/kg or more and 6 mol/kg or less based on the sum of the content of the ionic liquid and the content of the polymer. The content of the polymer is 25% by mass or more and 40% by mass or less based on the sum of the content of the ionic liquid and the content of the polymer.

A battery having a metal sulfide electrode, and an aluminum containing electrolyte and methods are shown. In one example, the electrolyte includes one or more organic salts. In one example, the metal sulfide includes molybdenum sulfide. In one example, the metal sulfide includes titanium sulfide.

A method of forming a thermally stable film on a cathode surface that allows reversable lithiation and delithiation reactions at high temperatures without structural degradations may include introducing a functional additive containing at least one of fluorine, boron, and phosphorus to an electrolyte, operating a first charge-discharge cycle of a lithium-ion battery with a cathode surface at 100° C., decomposing the functional additives during the first charge-discharge cycle, and forming a cathode electrolyte interphase film on the cathode surface from products of the functional additive decomposition. The cathode electrolyte interphase film may reduce contact between the cathode surface and the electrolyte in subsequent charge-discharge cycles of the lithium-ion battery.

Disclosed is a method for activating a surface of metals, such as self-passivated metals, and of metal-oxide dissolution, effected using a fluoroanion-containing composition. Also disclosed is an electrochemical cell utilizing an aluminum-containing anode material and a fluoroanion-containing electrolyte, characterized by high efficiency, low corrosion, and optionally mechanical or electrochemical rechargeability. Also disclosed is a process for fusing (welding, soldering etc.) a self-passivated metal at relatively low temperature and ambient atmosphere, and a method for electrodepositing a metal on a self-passivated metal using metal-oxide source.

A nonaqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material layer provided on a positive electrode collector, a negative electrode having a negative electrode active material layer provided on a negative electrode collector, and a nonaqueous electrolyte. The nonaqueous electrolyte contains at least one member selected from the group consisting of sulfone compounds represented by the following formulae (1) and (2); and an inorganic phosphorus compound represented by the following formula (3) exists on the surface of a positive electrode active material: ##STR00001##
R.sup.1 represents C.sub.mH.sub.2m-n1X.sub.n2; X represents a halogen; m represents an integer of from 2 to 7; each of n1 and n2 independently represents an integer of from 0 to 2m; R2 represents C.sub.jH.sub.2j-k1Z.sub.k2; Z represents a halogen; j represents an integer of from 2 to 7; each of k1 and k2 independently represents an integer of from 0 to 2j; each of R3, R4 and R5 independently represents H or OH; and a is 0 or 1.

A lithium air battery includes: a lithium negative electrode; a positive electrode; and an ion conductive oxygen-blocking film which is disposed on the lithium negative electrode, wherein the ion conductive oxygen-blocking film includes a first polymer including a polyvinyl alcohol or a polyvinyl alcohol blend, and a lithium salt, and wherein the ion conductive oxygen-blocking film has an oxygen transmission rate of about 10 milliliters per square meter per day to about 10,000 milliliters per square meter per day. Also a method of manufacturing a lithium air battery is disclosed.

An electrolyte includes a lithium salt dissolved in a solvent mixture. The solvent mixture may include a first solvent component including an organic solvent having no carbonate groups; a second solvent component configured to improve the electrochemical properties of the first solvent at low temperatures; a third solvent compound configured to promote formation of a passivating SEI layer between the electrolyte and an electrode layer; and a fourth solvent compound configured to stabilize a lithium salt at high temperatures.

This electricity storage device which is configured to contain an ionic liquid represented by formula (1) in, for example, an electrolyte or an electrode has the advantage of being usable in a low-temperature environment in spite of the ionic liquid contained therein.

##STR00001##

(In the formula, each of R.sup.1 and R.sup.2 independently represents an alkyl group having 1-5 carbon atoms; and n represents 1 or 2.)

A solid electrolyte including a compound represented by Formula 1 or 3, the compound having a glass transition temperature of −30° C. or less, and a glass or glass-ceramic structure,
AQX—Ga.sub.1−zM.sub.z1(F.sub.1−kCl.sub.k).sub.3−3zZ.sub.3z1  Formula 1
wherein, in Formula 1, Q is Li or a combination of Li and Na, K, or a combination thereof, M is a trivalent cation, or a combination thereof, X is a halogen other than F, pseudohalogen, OH, or a combination thereof, Z is a monovalent anion, or a combination thereof, 1<A<5, 0≤z≤1, 0≤z1≤1, and 0≤k<1,
AQX-aM.sub.z1Z.sub.3z1-bGa.sub.1−z(F.sub.1−kCl.sub.k).sub.3−3z  Formula 3 wherein, in Formula 3, Q is Li or a combination of Li and Na, K, or a combination thereof; M is a trivalent cation, or a combination thereof, X is a halogen other than F, pseudohalogen, OH, or a combination thereof, Z is a monovalent anion, or a combination thereof, 0<a≤1, 0<b≤1, 0<a+b, a+b=4−A, 1<A<5, 0≤z<1, 0≤z1≤1, and 0≤k<1.