Provided is an organometallic compound including a first ligand L.sub.A selected from

##STR00001## ##STR00002##

In ligand L.sub.A, each of Y.sup.1 to Y.sup.10 is carbon or nitrogen; moiety B is a monocyclic or polycyclic fused ring structure including 5-membered and/or 6-membered rings; any two R.sub.A and R.sub.B can be fused or joined to form a ring; X is selected from O, S, Se, or NR; each R.sub.A and R.sub.B is independently hydrogen or a substituent selected from the general substituent defined herein; at least one R, R.sub.A, or R.sub.B is deuterium or a linking group between L.sub.A and another ligand that includes a deuterium substituted aromatic ring; and L.sub.A is coordinated to a metal M, selected from Os, Pd, Pt, Ir, Cu, Ag, or Au; and the compound is capable of emitting light with a peak maximum wavelength (λ.sub.max)≥700 nm at room temperature.

Provided are boron substituted organometallic compounds of Formula I:

##STR00001##

Also provided are formulations including these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

An organic light-emitting device having low-driving voltage, improved efficiency, and long lifespan includes: a first electrode; a second electrode facing the first electrode; a first layer between the first electrode and the second electrode, the first layer including a first compound; a second layer between the first layer and the second electrode, the second layer including a second compound; and a third layer between the second layer and the second electrode, the third layer including a third compound; wherein the first compound does not include a nitrogen-containing heterocyclic group comprising *═N—*′ as a ring forming moiety, and wherein the first compound, the second compound, and the third compound each independently include at least one group selected from groups represented by Formulae A to C:

##STR00001##

An organic light-emitting device having low-driving voltage, improved efficiency, and long lifespan includes: a first electrode; a second electrode facing the first electrode; a first layer between the first electrode and the second electrode, the first layer including a first compound; a second layer between the first layer and the second electrode, the second layer including a second compound; and a third layer between the second layer and the second electrode, the third layer including a third compound; wherein the first compound does not include a nitrogen-containing heterocyclic group comprising *═N—*′ as a ring forming moiety, and wherein the first compound, the second compound, and the third compound each independently include at least one group selected from groups represented by Formulae A to C:

##STR00001##

An organic light-emitting device includes a mixed layer, an emission layer, and a buffer layer and satisfies one of Equation 1 or Equation 2 and Equation 3:

T1(D)≥T1(Mix)+0.3 eV  Equation 1

T1(H)≥T1(Mix)+0.3 eV  Equation 2

T1(Mix)<T1(Buffer)+0.5 eV.  Equation 3

A compound of Formula I: ##STR00001##
wherein: X.sup.1-X.sup.8 are each independently C or N, wherein two adjacent X.sup.1-X.sup.8 are carbon-fused to a structure of Formula II: ##STR00002## X.sup.9-X.sup.12 are each independently C or N; A.sup.1, A.sup.2, and A.sup.3 are each independently selected from the group consisting of O, S, Se, N, NR, CR, CRR′, SiR, SiRR′, GeR, and GeRR′, with at least one of A.sup.1 and A.sup.2 being N or NR; each occurrence of is independently a single bond or a double bond, wherein one occurrence of is a single bond and one occurrence of is a double bond; each of R.sup.A, R.sup.B, and R.sup.c independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each of occurrence R, R′, R.sup.A, R.sup.B, and R.sup.C is independently a hydrogen or a substituent selected from the group consisting of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, Formula IX, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, with at least one of R, R′, R.sup.A, R.sup.B, and R.sup.C comprising a group of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, or Formula IX: ##STR00003## ##STR00004## each occurrence of Y.sup.1, Y.sup.2, and Y.sup.3 is independently absent, O, S, Se, NR, CRR′, SiRR′, or GeRR′; each occurrence of Ar.sup.1, and Ar.sup.2 is independently an optionally substituted aryl group or an optionally substituted heteroaryl group, wherein Ar.sup.1 and Ar.sup.2 are optionally joined or fused together to form a ring; each occurrence of X.sup.13-X.sup.20 is independently C or N, with the proviso that at least one of X.sup.13-X.sup.20 is N; each occurrence of A.sup.4 is selected from the group consisting of O, S, Se, NR, CRR′, SiRR′, and GeRR′; each occurrence of R.sup.X independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each occurrence of R.sup.X is in

Provided is a light-emitting device and an electronic apparatus including the same. The light-emitting device includes: a first electrode; a second electrode facing the first electrode; an interlayer between the first electrode and the second electrode and including an emission layer; and a capping layer, wherein the emission layer includes a first emitter, the first emitter emits a first light having a first emission spectrum, the capping layer is in a path along which the first light travels, an emission peak wavelength of the first light is about 520 nm to about 550 nm, the first emitter includes platinum, the capping layer includes an amine-containing compound, and a value of a ratio of CIEy to reflective index (RCR value) of the first light extracted to the outside through the capping layer is 38 or less, and the RCR value is calculated according to Equation 1.

CIEy/R(cap)×100  Equation 1

A compound comprising a first ligand L.sub.A of Formula I,

##STR00001##

is provided. In Formula I, Ring A is a 5-membered or 6-membered ring, and moiety G has a structure of

##STR00002##

where
the dashed line marked with * is coordinated to Ir; the dashed line marked with # is bonded to Ring A; Y is selected from the group consisting of BR, BRR′, NR, PR, O, S, Se, C═O, C═S, C═Se, C═NR, C═CRR′, S═O, SO.sub.2, CR, CRR′, SiRR′, and GeRR′. Formulations, OLEDs, and consumer products containing the compound are also provided.

A light-emitting device includes an organometallic compound represented by Formula 1, an electronic apparatus including the light-emitting device, and the organometallic compound represented by Formula 1 are provided:

##STR00001##

wherein substituents of Formula 1 are the same as described in the present specification.

Embodiments provide a condensed cyclic compound, a light-emitting device including the condensed cyclic compound, and an electronic apparatus including the light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer; and the condensed cyclic compound. The condensed cyclic compound is represented by Formula 1:

##STR00001##

The description of Formula 1 is provided in the specification.