The present invention discloses an organic polymer having an asymmetric structure, a preparation method thereof and a use as a photoelectric material thereof. The organic polymer with an asymmetric structure is obtained by polymerization after performing Stille coupling reaction between an electron-donating unit D and an electron-withdrawing unit A in the presence of a solvent and a catalyst. The compound of the present application has good heat stability, controllable absorption level, and is suitable for the preparation of hole transport materials of high-performance perovskite solar cells with high efficiency, flexibility, good stability and a large area as well as donor materials of organic solar cells.

A liquid composition contains a thiophene polymer and a solvent, and the difference |δp.sub.2−δp.sub.1| is 7.7 MPa.sup.0.5 or more and 13.4 MPa.sup.0.5 or less between a dipole-dipole force term δp.sub.1 of Hansen solubility parameter of the thiophene polymer and a dipole-dipole force term δp.sub.2 of Hansen solubility parameter of the solvent.

A repeat unit comprising

##STR00001##

In the repeat unit, X.sub.1 and X.sub.2 are independently selected from the group consisting of: F, Cl, H, and combinations thereof. Additionally, in this monomer, R′ and R″ are independently selected from an alkyl group, an aryl group, or combinations thereof. Also, R.sub.3, and R.sub.4 are independently selected from unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.

The present specification relates to a photoactive layer including: an electron donor; and an electron acceptor, in which the electron donor includes: a single molecular material; and a polymer material, and the single molecular material is represented by Formula 1, and an organic solar cell including the same.

Semiconductor devices comprising: a semiconductor device comprising: a first electrode comprising conductive material, wherein the conductive material is deposited by ink deposition (for example, layered material inks such as graphene and/or graphite), or wherein the conductive material comprises CVD grown graphene or carbon nanotubes; a first charge transportation layer, wherein the first charge transportation layer is doped with the conductive material of the first electrode; an optional insulation layer; a perovskite active layer; a second charge transportation layer; and a second electrode.

A formulation for preparing organic electronic devices, has: a p-type organic semiconductor polymer including a conjugated aryl compound, a conjugated heteroaryl compound, or a mixture of at least two of these compounds; an n-type semiconductor material having fullerene, substituted fullerene, or a mixture of at least two of these compounds; and a non-aqueous solvent. The concentration of the p-type organic semiconductor polymer is in the range from 12 mg/mL to 17 mg/mL per milliliter of solvent and the concentration of the p-type organic semiconductor material is in the range from 24 mg/mL to 28 mg/mL per milliliter of solvent.

A formulation for preparing organic electronic devices, has: a p-type organic semiconductor polymer including a conjugated aryl polymer, a conjugated heteroaryl compound or a mixture of at least two of these compounds; an n-type semiconductor material including fullerene, substituted fullerene, or a mixture of at least two of these compounds; and a non-aqueous solvent. The concentration of the p-type organic semiconductor polymer is in the range from 8 mg/mL to 12 mg/mL per milliliter of solvent and the concentration of the p-type organic semiconductor material is in the range from 18 mg/mL to 22 mg/mL per milliliter of solvent.

A formulation for preparing organic electronic devices, has: a p-type organic semiconductor polymer including a conjugated aryl polymer, a conjugated heteroaryl compound, or a mixture of at least two of these compounds; an n-type semiconductor material including fullerene, substituted fullerene, or a mixture of at least two of these compounds; and a non-aqueous solvent. The concentration of the p-type organic semiconductor polymer is in the range from 4 mg/mL to 8 mg/mL per milliliter of solvent and the concentration of the p-type organic semiconductor material is in the range from 10 mg/mL to 14 mg/mL per milliliter of solvent.

The present invention relates to an organic light-emitting device, comprising: a light- emitting layer, which is a quantum dot composite film, wherein the quantum dot composite film comprises a conductive polymer, a quantum dot, and a coordination group connected to the conductive polymer, and the coordination group is connected to the quantum dot.

A method of combining different materials to produce the polymer

##STR00001##

In this polymer X.sub.1, X.sub.2, X.sub.3, and X.sub.4 are independently selected from the group consisting of: F, Cl, H, and combinations thereof. Additionally, in this polymer R.sub.15, R.sub.16, R.sub.17, and R.sub.18 are independently selected from the group consisting of: F, Cl, H, and combinations thereof. Finally, in this polymer R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, and R.sub.8 are independently selected from unsubstituted branched alkyls with 1 to 60 carbon atoms unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.