A compound of Formula I ##STR00001## wherein Z.sup.1, Z.sup.2, Z.sup.3, and Z.sup.4 are independently selected from C or N; wherein one of Z.sup.1 or Z.sup.3 is N and the other is C, and one of Z.sup.2 or Z.sup.4 is N and the other is C; and if Z.sup.3 and Z.sup.4 are N, then one of R.sup.B and one of R.sup.C is selected from the group consisting of aryl, substituted aryl, heteroaryl, and substituted heteroaryl; or if Z.sup.1 and Z.sup.2 are N and, then one of R.sup.A, one of R.sup.B or one of R.sup.C is selected from the group consisting of an optionally substituted aryl, and an optionally substituted heteroaryl. An organic light emitting diode/device (OLED) that includes an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer includes a compound of Formula I above. The OLED can be incorporated into a consumer product, an electronic component module, and/or a lighting panel.

A light-emitting device and an electronic apparatus including the same are provided. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and a capping layer. The emission layer includes a first emitter, the first emitter emits a first light having a first emission spectrum, the capping layer is in a path on which the first light travels, an emission peak wavelength of the first light is about 520 nm to about 550 nm. The first emitter includes iridium, the capping layer includes an amine-free compound, and the value of ratio of CIEy to reflective index (RCR value) of the first light extracted to the outside through the capping layer is 38 or less, and the RCR value is calculated according to CIEy/R(cap)×100.

A light-emitting device and an electronic apparatus including the same are provided. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and a capping layer. The emission layer includes a first emitter, the first emitter emits first light having a first emission spectrum, the capping layer is in the path on which the first light travels, an emission peak wavelength of the first light is from about 520 nm to about 550 nm. The first emitter includes iridium, the capping layer includes an amine-containing compound, and the value of ratio of CIEy to reflective index (RCR value) of the first light extracted to the outside through the capping layer is 38 or less, and the RCR value is calculated according to

CIEy/R(cap)×100.

Provided are a light-emitting device and an electronic apparatus including the same. The light-emitting device includes a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode. The interlayer includes an emission layer, and a hole transport region between the first electrode and the emission layer. The emission layer includes a transition metal-containing organometallic compound. The hole transport region includes an electron-blocking layer. The electron-blocking layer includes a first electron-blocking material and a second electron-blocking material, and the first electron-blocking material and the second electron-blocking material have different hole mobilities.

A compound comprising a first ligand L.sub.A of Formula I,

##STR00001##

is provided. In Formula I, Ring A is a 5-membered or 6-membered ring, and moiety G has a structure of

##STR00002##

where
the dashed line marked with * is coordinated to Ir; the dashed line marked with # is bonded to Ring A; Y is selected from the group consisting of BR, BRR′, NR, PR, O, S, Se, C═O, C═S, C═Se, C═NR, C═CRR′, S═O, SO.sub.2, CR, CRR′, SiRR′, and GeRR′. Formulations, OLEDs, and consumer products containing the compound are also provided.

An organometallic compound represented by Formula 1:

M.sub.1(Ln.sub.1).sub.n1(Ln.sub.2).sub.n2  Formula 1

wherein M.sub.1 is a transition metal, Ln.sub.1 is a ligand represented by Formula 1A, Ln.sub.2 is a ligand represented by Formula 1B, n1 is 1 or 2, and n2 is 1 or 2,

##STR00001##

wherein ring CY.sub.1 and ring CY.sub.2 are each independently a C.sub.5-C.sub.30 carbocyclic group or a C.sub.1-C.sub.30 heterocyclic group, ring CY.sub.41 is a phenyl group, ring CY.sub.42 is a 5-membered aromatic heterocyclic group, and the other substituents are as described herein.

A light-emitting device includes a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode. The interlayer includes an emission layer and a hole transport layer between the first electrode and the emission layer. The emission layer includes a first host, a second host, and a dopant, wherein the first host includes a hole-transporting host, and the second host includes an electron-transporting host or a bipolar host. The hole transport layer includes multiple hole transport layers, the hole transport layers each include a carbazole-based compound, and highest occupied molecular orbital (HOMO) energy levels of the carbazole-based compounds respectively included in neighboring ones of the hole transport layers are different from each other.

A compound comprising a ligand L.sub.A, having a structure of Formula I,

##STR00001##

is provided. In Formula I, A.sup.1 to A.sup.8 are each independently CR or N; at least two adjacent ones of A.sup.1 to A.sup.8 are CR and the Rs are joined together to form a six-membered ring fused to ring A or ring C; X is O, S, or Se; each R and R.sup.B is independently hydrogen or a substituent; any adjacent substituents are optionally joined or fused into a ring; the ligand L.sub.A is coordinated to a metal M; the metal M is bonded to ring A through a M-C bond; the metal M can be coordinated to other ligands; and the ligand L.sub.A is optionally linked with other ligands. Formulations, OLEDs, and consumer products containing such compounds are also disclosed.

A compound having the formula Ir(L.sub.A).sub.n(L.sub.B).sub.3−n, having the structure ##STR00001##
Formula I, is disclosed. In Formula I, each of Z.sup.1, Z.sup.2, Z.sup.3, and Z.sup.4 is CR.sup.2; X is O, S, or Se; n is an integer from 1 to 3; R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 each independently represent mono- to a maximum possible number of substitutions, or no substitution; R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are each independently selected from a variety of substituents; any two substitutions in R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are optionally joined to form a ring; at least one pair of substitutions in R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are joined together to form a bridge structure comprising a backbone structure that forms a fused first ring, which can be further substituted; and the backbone structure is saturated. Organic light emitting devices and consumer products containing the compounds are also disclosed.

A compound comprising a first ligand L.sub.A of Formula I, ##STR00001##
is disclosed. In the structure of Formula I, ring A is a 5-membered or 6-membered carbocyclic or heterocyclic ring; Z.sup.1-Z.sup.4 are each independently C or N; at least two consecutive Z.sup.1-Z.sup.4 are C, and are fused to a structure of Formula II ##STR00002##
or Formula III ##STR00003##
Y.sup.1; Y.sup.1 and Y.sup.2 are each independently O, S, Se, CRR′, SiRR′, or GeRR′; each R.sup.A, R.sup.B, R.sup.C, R, and R′ is a hydrogen or a substituent; and any two substituents may be joined or fused together to form a ring. In the compound, L.sub.A is complexed to a metal M by the dashed lines in Formula I to form a five-membered chelate ring, and M has an atomic weight greater than 40. Organic light emitting devices and consumer products containing the compounds are also disclosed.