A heterocyclic compound and an organic light-emitting device including the same are provided. The heterocyclic compound is represented by Formula 1: ##STR00001## Details of R1, R2, R3, X1, L1, and a1 and b1 are provided in the disclosure.

The present invention relates to an organic electroluminescent device comprising a mixture comprising an electron-transporting host material and a hole-transporting host material, and to a formulation comprising a mixture of the host materials and to a mixture comprising the host materials. The electron-transporting host material corresponds to a compound of the formula (1) from the class of compounds containing a bispirofluorenyl unit.

A light emitting diode of an embodiment includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region. The hole transport region includes a first hole transport layer disposed adjacent to the first electrode and having a first refractive index, a second hole transport layer disposed adjacent to the emission layer and having a second refractive index, and a third hole transport layer disposed between the first hole transport layer and the second hole transport layer and having a third refractive index which is greater than each of the first refractive index and the second refractive index, thereby showing high light extraction efficiency and high emission efficiency properties.

Provided are organometallic compounds including a ligand L.sub.A of the following Formula I

##STR00001##

Also provided are formulations including these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

A compound including a first ligand L.sub.A of Formula I,

##STR00001##

is disclosed. In Formula I, ring B is a 5- or 6-membered ring; X.sup.1, X.sup.2, and X.sup.3 are each CR.sup.A or N; R is a 5- or 6-membered carbocyclic or heterocyclic ring, which can be further fused or substituted; and (1) when ring B is an unfused 6-membered ring, X.sup.1 and X.sup.2 are N, and X.sup.3 is C; and (2) when ring B is a fused 6-membered ring, ring B has the structure of Formula II,

##STR00002##

In this structure, the wavy line indicates the point of connection to ring A; Q.sup.1 to Q.sup.6 are each C or N; and, when proviso (2) applies, (I) at least one of X.sup.1, X.sup.2, and X.sup.3 is N; or (II) R is two or more fused or unfused 5- or 6-membered carbocyclic or heterocyclic rings, or (III) at least ring A or R is substituted with a partially or fully deuterated alkyl or partially or fully deuterated cycloalkyl group.

A composition which is useful for producing a light emitting device having excellent external quantum efficiency contains two or more compounds represented by the formula (C-1) and a phosphorescent compound, in which at least one of the compounds represented by the formula (C-1) is a compound in which R.sup.C is a group represented by the formula (C′-1). ##STR00001##
Ring R.sup.1C and Ring R.sup.2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R.sup.C represents an oxygen atom, a sulfur atom or a group represented by the formula (C′-1). ##STR00002##
Ring R.sup.3C and Ring R.sup.4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R.sup.C′ represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.

The present specification provides a compound of Chemical Formula 1, and an organic light emitting device including the same. The compound provides a low driving voltage, high light emission efficiency and a long lifetime of the organic light emitting device. ##STR00001##

The present specification provides a heterocyclic compound represented by Chemical Formula 1, an organic light emitting device comprising the same, a composition for an organic material layer of an organic light emitting device, and a method for manufacturing an organic light emitting device.

Provided is a compound of Formula I

##STR00001##

in which at least one moiety A, moiety B, moiety C, or moiety D is a 6-membered carbocyclic or heterocyclic ring, and at least one R.sup.A, R.sup.B, R.sup.C, or R.sup.D includes a group having Formula II

##STR00002##

where R.sup.X can be silyl, germyl, boryl, nitrile, F, CF.sub.3, cycloalkyl, heterocycloalkyl, or monocyclic heteroaryl. The compounds are useful as emitters in OLEDs providing improved efficiency.

An organic photodetector includes: an anode; a cathode facing the anode; and an active layer disposed between the anode and the cathode and including a first layer and a second layer. The first layer is disposed between the anode and the second layer, the first layer includes a p-type organic semiconductor and an n-type organic semiconductor, and the second layer includes the p-type organic semiconductor.