A composition for forming an electroactive coating includes an acid as a polymerization catalyst, at least one functional component, and at least one compound of formula (1) as a monomer: ##STR00001##
wherein X is selected from S, O, Se, Te, PR.sup.2 and NR.sup.2, Y is hydrogen (H) or a precursor of a good leaving group Y.sup.− whose conjugate acid (HY) has a pK.sub.a of less than 45, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pK.sub.a of less than 45, b is 0, 1 or 2, each R.sup.1 is a substituent, and the at least one compound of formula (1) includes at least one compound of formula (1) with Z═H and Y≠H.

A novel dopant according to the present disclosure includes an anion represented by the following Formula (1) and a counter cation. In Formula (1), R.sup.1 and R.sup.2 may be each at least one group selected from a nitro group, a cyano group, an acyl group, a carboxyl group, an alkoxycarbonyl group, a haloalkyl group, a sulfo group, an alkylsulfonyl group, an halosulfonyl group, and a haloalkylsulfonyl group, or may be a group formed by R.sup.1 and R.sup.2 bonded to each other [—SO.sub.2-L-SO.sub.2—] (where L represents a haloalkylene group). The counter cation may be a radical cation represented by Formula (2), where R.sup.1 and R.sup.2 represent electron-withdrawing groups that may be bonded to each other to form a heterocycle, and R.sup.3 to R.sup.5 represent a hydrogen atom, a hydrocarbon group that may have a substituent, or a heterocyclic group that may have a substituent. The dopant is capable of forming an electroconductive composition that shows a high conductivity.

A conductive composition including a conductive polymer (A), a water-soluble polymer (B) other than the conductive polymer (A), and a solvent (C), wherein a peak area ratio is 0.44 or less, which is determined based on results of analysis performed using a high performance liquid chromatograph mass spectrometer with respect to a test solution obtained by extracting the water-soluble polymer (B) from the conductive composition with n-butanol, and calculated by formula (I):

Area ratio=Y/(X+Y)

wherein X is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of 600 or more from a total ion current chromatogram, Y is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of less than 600 from the total ion current chromatogram.

This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

Provided is a dopant with which a conductor material having high electrical conductivity can be formed. The present disclosure relates to a dopant containing a radical cation represented by Formula (1) and a counter anion. In Formula (1), R.sup.1 to R.sup.3 may be the same or different, and each denotes a monovalent aromatic group or a group represented by Formula (r). at least one of R.sup.1 to R.sup.3 is a group represented by Formula (r), and n indicates the valence of the radical cation and is equal to the quantity (n) of nitrogen atoms in the formula. In Formula (r), Ar.sup.1, Ar.sup.2, and Ar.sup.3 may be the same or different, and each denotes a divalent aromatic group, and Ar.sup.4, Ar.sup.5, Ar.sup.6, and Ar.sup.7 may be the same or different, and each denotes a monovalent aromatic group optionally having a substituent represented by Formula (sb) below. Furthermore, m and n may be the same or different, and each represents an integer of 0 or greater.

##STR00001##

Previous electrochemically-powered yarn muscles cannot be usefully operated between extreme negative and extreme positive potentials, since strokes during electron injection and during hole injection partially cancel because they are in the same direction. Unipolar-stroke carbon nanotube yarn muscles are described in which muscle strokes are additive between extreme negative and extreme positive potentials, and stroke increases with potential scan rate. These electrochemical artificial muscles include an electrically conducting twisted or coiled yarn and a material that dramatically shifts the potential of zero charge of the electrochemically actuated yarn.

An electrically conductive material includes an anionic polymer having a polymer backbone that is bonded to a plurality of terminal catechol moieties and a plurality of terminal sulfonate moieties. It also includes a cationic polymer including poly(3,4-ethylenedioxythiophene).

A method for producing an organic conductive film includes a step of preparing a coating liquid containing an acid-based organic conductive polymer, an alkali neutralizing agent, and a liquid medium, and having a pH of 4.0 to 6.5 at 25° C., a step of applying the coating liquid to a base layer, and a step of removing the liquid medium from the applied coating liquid.

A process for producing polymer-supported metal nanoparticles involves confinement of metal nanoparticles in polymeric nanotubes or nanosheets in an aqueous environment using hydrophobic reactants. Metal nanoparticles supported in the polymeric nanotubes or nanosheets are substantially monodisperse and have an average particle size of 4 nm or less. The polymer-supported metal nanoparticles are useful in fuel cells, sensors, bioanalysis, biological labeling or semi-conductors, especially as catalysts.

Disclosed are an organic heterocyclic compound represented by Chemical Formula A and an organic light-emitting diode comprising the same.

##STR00001## wherein substituents R1 to R8, X1 to X4, W1, and Y1 are each as defined in the specification.