A thermionic dispenser cathode having a refractory metal matrix with scandium and barium compounds in contact with the metal matrix and methods for forming the same. The invention utilizes atomic layer deposition (ALD) to form a nanoscale, uniform, conformal distribution of a scandium compound on tungsten surfaces and further utilizes in situ high pressure consolidation/impregnation to enhance impregnation of a BaOCaOAl.sub.2O.sub.3 based emissive mixture into the scandate-coated tungsten matrix or to sinter a tungsten/scandate/barium composite structure. The result is a tungsten-scandate thermionic cathode having improved emission.

A thermionic dispenser cathode having a refractory metal matrix with scandium and barium compounds in contact with the metal matrix and methods for forming the same. The invention utilizes atomic layer deposition (ALD) to form a nanoscale, uniform, conformal distribution of a scandium compound on tungsten surfaces and further utilizes in situ high pressure consolidation/impregnation to enhance impregnation of a BaOCaOAl.sub.2O.sub.3 based emissive mixture into the scandate-coated tungsten matrix or to sinter a tungsten/scandate/barium composite structure. The result is a tungsten-scandate thermionic cathode having improved emission.

In an example, a method to form a low work function insert includes preparing a mixture that includes a first powder that contains barium, a second powder that contains calcium, a third powder that contains at least one of aluminum, samarium, or magnesium, and a fourth powder that contains a refractory metal. The method may also include heating the mixture, contained in a crucible, in a furnace. Oxygen concentration in the furnace may be maintained at a low partial pressure during heating of the mixture in the furnace. The low work function of the insert allows electrons to be readily extracted from its surface.

The invention relates to the field of production of barium-scandate dispenser cathodes or other barium-scandate materials. A target (66) containing a mixture of BaO, CaO, Al.sub.2O.sub.3 and Sc.sub.2O.sub.3 tends to be more stable, the higher the scandia (scandium oxide) content is. However, an increased scandia content results in a reduced emission capability. A destabilizing effect of BaO and CaO reactions is counteracted by the more inert Sc.sub.2O.sub.3 and also Al.sub.2O.sub.3 components, as not only an increased scandia content stabilizes the material but also an increased alumina (aluminum oxide) content improves the stability.

The invention relates to the field of production of barium-scandate dispenser cathodes or other barium-scandate materials. A target (66) containing a mixture of BaO, CaO, Al.sub.2O.sub.3 and Sc.sub.2O.sub.3 tends to be more stable, the higher the scandia (scandium oxide) content is. However, an increased scandia content results in a reduced emission capability. A destabilizing effect of BaO and CaO reactions is counteracted by the more inert Sc.sub.2O.sub.3 and also Al.sub.2O.sub.3 components, as not only an increased scandia content stabilizes the material but also an increased alumina (aluminum oxide) content improves the stability.

A high-temperature component made of a refractory metal or a refractory metal alloy, includes a coating for increasing thermal emissivity. The coating is formed substantially of tungsten and rhenium, i.e. of at least 55 wt. % rhenium and at least 10 wt. % tungsten, and has a Re3W phase of at least 35 wt. %. A process for producing a high-temperature component having a coating for increasing thermal emissivity, is also provided.

A high-temperature component made of a refractory metal or a refractory metal alloy, includes a coating for increasing thermal emissivity. The coating is formed substantially of tungsten and rhenium, i.e. of at least 55 wt. % rhenium and at least 10 wt. % tungsten, and has a Re3W phase of at least 35 wt. %. A process for producing a high-temperature component having a coating for increasing thermal emissivity, is also provided.

A method of manufacturing carburized Lu.sub.2O.sub.3 doped Mo cathodes for thermionic emission for magnetrons is described. The Lu.sub.2O.sub.3 doped Mo powder is prepared by sol-gel method. The powder is reduced thoroughly in hydrogen atmosphere. Afterwards, the powder is die-pressed into pellets, followed by sintering in hydrogen and carburization in activated carbon powder to obtain the carburized Lu.sub.2O.sub.3 doped Mo cathode.

A method of manufacturing carburized Lu.sub.2O.sub.3 doped Mo cathodes for thermionic emission for magnetrons is described. The Lu.sub.2O.sub.3 doped Mo powder is prepared by sol-gel method. The powder is reduced thoroughly in hydrogen atmosphere. Afterwards, the powder is die-pressed into pellets, followed by sintering in hydrogen and carburization in activated carbon powder to obtain the carburized Lu.sub.2O.sub.3 doped Mo cathode.