Methods of forming memory structures are discussed. Specifically, methods of forming 3D NAND devices are discussed. Some embodiments form memory structures with a metal nitride barrier layer, an α-tungsten layer, and a bulk metal material. The barrier layer comprises a TiXN or TaXN material, where X comprises a metal selected from one or more of aluminum (Al), silicon (Si), tungsten (W), lanthanum (La), yttrium (Yt), strontium (Sr), or magnesium (Mg).

Some embodiments include methods of forming integrated assemblies. A conductive structure is formed to include a semiconductor-containing material over a metal-containing material. An opening is formed to extend into the conductive structure. A conductive material is formed along a bottom of the opening. A stack of alternating first and second materials is formed over the conductive structure either before or after forming the conductive material. Insulative material and/or channel material is formed to extend through the stack to contact the conductive material. Some embodiments include integrated assemblies.

An embodiment of a method of integration of a non-volatile memory device into a logic MOS flow is described. Generally, the method includes: forming a pad dielectric layer of a MOS device above a first region of a substrate; forming a channel of the memory device from a thin film of semiconducting material overlying a surface above a second region of the substrate, the channel connecting a source and drain of the memory device; forming a patterned dielectric stack overlying the channel above the second region, the patterned dielectric stack comprising a tunnel layer, a charge-trapping layer, and a sacrificial top layer; simultaneously removing the sacrificial top layer from the second region of the substrate, and the pad dielectric layer from the first region of the substrate; and simultaneously forming a gate dielectric layer above the first region of the substrate and a blocking dielectric layer above the charge-trapping layer.

Electronic apparatus and methods of forming the electronic apparatus may include one or more charge trap structures for use in a variety of electronic systems and devices, where each charge trap structure includes a dielectric barrier between a gate and a blocking dielectric on a charge trap region of the charge trap structure. In various embodiments, a void is located between the charge trap region and a region on which the charge trap structure is disposed. In various embodiments, a tunnel region separating a charge trap region from a semiconductor pillar of a charge trap structure, can be arranged such that the tunnel region and the semiconductor pillar are boundaries of a void. Additional apparatus, systems, and methods are disclosed.

Embodiments of three-dimensional (3D) memory devices having through stair contacts (TSCs) and methods for forming the same are disclosed. In an example, a 3D memory device includes a memory stack and a TSC. The memory stack includes a plurality of interleaved conductive layers and dielectric layers. Edges of the interleaved conductive layers and dielectric layers define a staircase structure on a side of the memory stack. The TSC extends vertically through the staircase structure of the memory stack. The TSC includes a conductor layer and a spacer circumscribing the conductor layer.

A semiconductor device includes a first stacked structure and a second stacked structure spaced apart from each other on a substrate, and a plurality of separation structures and a plurality of vertical memory structures alternately arranged between the first stacked structure and the second stacked structure in a first direction parallel to an upper surface of the substrate. Each of the first and second stacked structures includes a plurality of interlayer insulating layers and a plurality of gate layers alternately repeatedly stacked on the lower structure. Each of the vertical memory structures includes a first data storage structure facing the first stacked structure and a second data storage structure facing the second stacked structure. Side surfaces of the first and second stacked structures facing the vertical memory structures are concave in a plan view.

Some embodiments include a memory cell having charge-trapping-material between a semiconductor channel material and a gating region. The charge-trapping-material includes silicon, nitrogen and trap-enhancing-additive. The trap-enhancing-additive includes one or more of carbon, phosphorus, boron and metal. Some embodiments include an integrated assembly having a stack of alternating first and second levels. The first levels include conductive structures and the second levels are insulative. Channel-material-pillars extend through the stack. Charge-trapping-regions are along the channel-material-pillars and are between the channel-material-pillars and the conductive structures. The charge-trapping-regions include a charge-trapping-material which contains silicon, nitrogen and trap-enhancing-additive. The trap-enhancing-additive includes one or more of carbon, phosphorus, boron and metal.

A memory device includes an alternating stack of insulating layers, dielectric barrier liners and electrically conductive layers located over a substrate and a memory stack structure extending through each layer in the alternating stack. Each of the dielectric barrier liners is located between vertically neighboring pairs of an insulating layer and an electrically conductive layer within the alternating stack. The memory stack structure includes a memory film and a vertical semiconductor channel, the memory film includes a tunneling dielectric layer and a vertical stack of discrete memory-level structures that are vertically spaced from each other without direct contact between them, and each of the discrete memory-level structures includes a lateral stack including, from one side to another, a charge storage material portion, a silicon oxide blocking dielectric portion, and a dielectric metal oxide blocking dielectric portion.

A semiconductor device includes a substrate having a first region and a second region, a first stack structure in the first region, a first channel structure penetrating through the first stack structure and in contact with the substrate, and a second stack structure on the first stack structure and the first channel structure. The device includes a second channel structure penetrating through the second stack structure and connected to the first channel structure, a first molding structure in the second region, a first alignment structure penetrating through the first molding structure and in contact with the substrate, and a second molding structure on the first molding structure and the first alignment structure. The device includes a second alignment structure penetrating through the second molding structure and connected to the first alignment structure, and a protective layer between the first molding structure and the second molding structure.

A semiconductor device includes a semiconductor layer including a first main surface, a first region of a first conduction type that is formed at a surface layer portion of the first main surface, a second region of a first conduction type that is formed at the surface layer portion of the first main surface and is separated from the first region in a first direction, a channel region of a second conduction type that is formed between the first region and the second region in the surface layer portion of the first main surface, a first gate electrode that is formed in a vicinity of the first region in the first main surface, faces the channel region, and includes a first side portion and a second side portion on an opposite side of the first side portion in the first direction.