To provide a high-voltage fuel cell. The fuel cell is a fuel cell comprising an anode-side gas diffusion layer, an anode catalyst layer, an electrolyte membrane, a cathode catalyst layer and a cathode-side gas diffusion layer in this order, wherein a gas diffusion resistance ratio of the anode-side gas diffusion layer to the cathode-side gas diffusion layer is more than 1.50 and less than 2.79; wherein a gas diffusion resistance value of the cathode-side gas diffusion layer is 84 S/m or less at a relative humidity of 165%; and wherein a gas diffusion resistance value of the anode-side gas diffusion layer is less than 234 S/m at a relative humidity of 165%.

An object of the present invention is to provide, in the manufacture of a membrane-catalyst assembly including a polymer electrolyte membrane and a catalyst layer bonded to the polymer electrolyte membrane, a method that achieves both the relaxation of thermocompression bonding conditions and the improvement of adhesion between the catalyst layer and the electrolyte membrane with high productivity. A main object of the present invention is to provide a method of manufacturing a membrane-catalyst assembly including an electrolyte membrane and a catalyst layer bonded to the electrolyte membrane, the method including a liquid application step of applying a liquid to a surface of the catalyst layer before bonding, and a thermocompression bonding step of bonding, to the electrolyte membrane, the catalyst layer to which the liquid is applied by thermocompression bonding.

A method for production of an at least two-layered laminate of a membrane electrode assembly for a fuel cell comprises: preparing a membrane material from a proton-conducting electrolyte, preparing an electrode material comprising at least one catalyst, applying a liquid adhesive on a surface of the membrane material and/or on a surface of the electrode material, and contacting the surfaces of the membrane material and the electrode material to form a material connection by means of the liquid adhesive, wherein additionally a production aid is introduced into or applied onto an assemblage formed from the electrode material, the membrane material and the still unhardened liquid adhesive, the production aid being designed to stabilize the unhardened assemblage.

To provide a high-voltage fuel cell. The fuel cell is a fuel cell comprising an anode-side gas diffusion layer, an anode catalyst layer, an electrolyte membrane, a cathode catalyst layer and a cathode-side gas diffusion layer in this order, wherein a gas diffusion resistance ratio of the anode-side gas diffusion layer to the cathode-side gas diffusion layer is more than 1.50 and less than 2.79; wherein a gas diffusion resistance value of the cathode-side gas diffusion layer is 84 S/m or less at a relative humidity of 165%; and wherein a gas diffusion resistance value of the anode-side gas diffusion layer is less than 234 S/m at a relative humidity of 165%.

A method for manufacturing a composite electrode for a metal-air electrochemical cell with a liquid electrolyte of basic pH. A liquid solution comprising a fluoropolymer suspended in a solvent is synthesized, then deposited on the outer surface of a porous structure forming an air electrode. The fluoropolymer comprises SO.sub.2N groups suitable for conducting hydroxyl ions and is capable of forming a membrane impermeable to at least the liquid electrolyte of basic pH. When the liquid solution is applied to the porous structure, the solvent flows through the porous structure and the fluoropolymer is deposited by aggregating into a layer on the outer surface of the porous structure.

This method for producing an electrode catalyst includes: a dispersion liquid preparation step wherein a dispersion liquid is prepared by mixing (i) at least one solvent selected from the group consisting of sulfoxide compounds and amide compounds, (ii) a catalyst carrier powder composed of a metal oxide, (iii) a platinum compound, (iv) a transition metal compound and (v) an aromatic compound that contains a carboxyl group; a loading step wherein the dispersion liquid is heated so that a platinum alloy of platinum and a transition metal is loaded on the surface of the catalyst carrier powder; a solid-liquid separation step wherein a dispersoid is separated from the dispersion liquid after the loading step, thereby obtaining a catalyst powder wherein the catalyst carrier powder is loaded with the platinum alloy; and a heat treatment step wherein the catalyst powder is heated under vacuum or in a reducing gas atmosphere.

[Problems] To easily and efficiently manufacture a catalyst layer having high catalytic activity and to easily manufacture a fuel cell having high power generation efficiency. [Solution] An apparatus for forming a catalyst layer 3 for a fuel cell on an electrolyte film (application object) 2, the apparatus including: a holding portion 6 that holds a sheet-shaped electrolyte film 2, an application portion 7 that applies a catalyst ink 5 for forming the catalyst layer 3 on at least one side of the electrolyte film 2 held by the holding portion 6, a chamber portion 8 that is capable of forming a space 55 including the holding portion 6, and a suction portion 9 that depressurizes the inside of the space 55 formed by the chamber portion 8 so as to dry the catalyst ink 5.

The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.

Improved catalyst layers for use in fuel cell membrane electrode assemblies, and methods for making such catalyst layers, are provided. Catalyst layers can comprise structured units of catalyst, catalyst support, and ionomer. The structured units can provide for more efficient electrical energy production and/or increased lifespan of fuel cells utilizing such membrane electrode assemblies. Catalyst layers can be directly deposited on exchange membranes, such as proton exchange membranes.

An anion exchange membrane is made by mixing 2 trifluoroMethyl Ketone [nominal] (1.12 g, 4.53 mmol), 1 Biphenyl (0.70 g, 4.53 mmol), methylene chloride (3.0 mL), trifluoromethanesulfonic acid (TFSA) (3.0 mL) to produce a pre-polymer. The pre-polymer is then functionalized to produce an anion exchange polymer. The pre-polymer may be functionalized with trimethylamine in solution with water. The pre-polymer may be imbibed into a porous scaffold material, such as expanded polytetrafluoroethylene to produce a composite anion exchange membrane.