A membrane electrode assembly includes an electrolyte membrane, and a pair of electrodes sandwiching the electrolyte membrane. The pair of electrodes each include a catalyst layer, and a gas diffusion layer disposed on the catalyst layer on an opposite side to the electrolyte membrane. At least one of the catalyst layers contains first catalyst particles, and second catalyst particles. The first catalyst particles are either platinum particles or platinum alloy particles, or both. The second catalyst particles are core-shell particles having a core part and a shell part, the core part formed of at least one selected from transition metals other than platinum, the shell part covering the core part and formed of at least one of platinum and a platinum alloy. In the catalyst layer, the second catalyst particles are present in a smaller percentage in an electrolyte membrane side than they are in a gas diffusion layer side.

An electrochemical reaction unit cell including an electrolyte layer containing a solid oxide; a cathode and an anode which face each other in a first direction with the electrolyte layer intervening therebetween; and an intermediate layer disposed between the electrolyte layer and the cathode and containing a first cerium oxide. In the electrochemical reaction unit cell, the cathode includes an active layer containing a strontium-containing perovskite oxide, a second cerium oxide, sulfur, and strontium sulfate and having ion conductivity and electron conductivity, and a grain of the strontium sulfate covers at least a portion of the surface of a grain of the second cerium oxide.

Disclosed are a manufacturing method of a membrane electrode assembly capable of increasing the interfacial adhesion between a polymer electrolyte membrane and a catalyst layer, improving substance delivery and performance, and enhancing hydrogen permeation resistance or oxygen permeability; a membrane electrode assembly manufactured thereby; and a fuel cell comprising the membrane electrode assembly. The manufacturing method of the present invention comprises the steps of: adding a catalyst and a first ionomer to a solvent and dispersing the same, thereby producing a dispersed mixture; adding a second ionomer to the dispersed mixture, thereby producing a coating composition; and applying the coating composition directly onto at least one side of the polymer electrolyte membrane.

A method of manufacturing a membrane electrode assembly, includes: forming catalyst coated membrane using an electrode catalyst layer containing an ionomer having a sulfonic acid group and a catalyst carrier, and an electrolyte membrane; applying an ionization accelerator having a low molecular weight component represented by a chemical formula C.sub.lH.sub.mO.sub.n (where l, m, and n are natural numbers) for accelerating generation of sulfate ions, to the catalyst coated membrane; performing UV irradiation on the ionization accelerator applied to the catalyst coated membrane; heating the catalyst coated membrane having the ionization accelerator subjected to the UV irradiation; and bonding a gas diffusion layer containing a radical inhibiting substance to an outer surface of at least one of the ionization accelerator subjected to the UV irradiation or the catalyst coated membrane.

A membrane electrode assembly comprises an anode electrode comprising an anode catalyst layer; a cathode electrode comprising a cathode catalyst layer; and a polymer electrolyte membrane interposed between the anode electrode and the cathode electrode; wherein at least one of the anode and cathode catalyst layers comprises a block co-polymer comprising poly(ethylene oxide) and poly(propylene oxide).

A membrane-electrode assembly, a method for manufacturing the membrane-electrode assembly, and a fuel cell including the membrane-electrode assembly are disclosed. The membrane-electrode assembly includes: an ion exchange membrane; catalyst layers disposed on both sides of the ion exchange membrane respectively; and a functional modification layer disposed between the ion exchange membrane and each of the catalyst layers. The membrane-electrode assembly has a low hydrogen permeability without a reduction of hydrogen ion conductivity, has excellent interfacial bonding properties between the catalyst layers and the ion exchange membrane, and has excellent performance and durability under high temperature/low humidity conditions.

An electrode joining method includes: an electrode sheet conveying step of conveying the cathode electrode sheet of a size enabling a plurality of cathode electrode layers to be acquired; an anomaly detecting step of detecting anomalies in the cathode electrode sheet; a specifying step of specifying a predetermined shape from an area excluding a location having an anomaly that was detected in the anomaly detecting step; a cutting step of cutting out the cathode electrode layer of the predetermined shape specified in the specifying step; and a step of joining the cathode electrode layer of the predetermined shape that was cut out to the PEM.

A method for manufacturing a membrane electrode and gas diffusion layer assembly includes: applying a catalyst ink including an ionomer to a second surface of an electrolyte membrane while conveying a first sheet in which a first surface of the electrolyte membrane is supported by a back sheet; drying the catalyst ink by blowing air vibrated with ultrasonic waves onto a surface of the catalyst ink to produce a second sheet in which a catalyst layer is provided on the second surface of the electrolyte membrane; forming a first roll by winding the second sheet; and producing a third sheet by stacking a gas diffusion layer on the catalyst layer and pressing them in a stacking direction as heating to join the catalyst layer and the gas diffusion layer while conveying the second sheet unwound from the first roll.

The present disclosure relates to an electrolyte membrane for fuel cells having improved chemical durability and a method of manufacturing the same. Specifically, the method includes preparing a polymer film, depositing catalyst metal on one surface or opposite surfaces of the polymer film to obtain a reinforcement layer, and impregnating the reinforcement layer with an ionomer to obtain an electrolyte membrane.

The present disclosure relates to an electrolyte membrane for fuel cells including a hydrogen peroxide generating catalyst and a hydrogen peroxide decomposing catalyst, the electrolyte membrane exhibiting highly improved durability, and a method of manufacturing the same. Specifically, the electrolyte membrane includes a support and a catalyst particle including a catalyst metal supported by the support, the catalyst metal including one selected from the group consisting of a first metal having catalyst activity to generate hydrogen peroxide, a second metal having catalyst activity to decompose hydrogen peroxide, and a combination thereof.