A carbon monoxide (CO) tolerant membrane electrode assembly (MEA) includes an ionically-conductive proton exchange membrane, an anode contacting a first side of the membrane and including a hydrophobic bonding agent, an ionomer bonding agent, first catalyst particles, second catalyst particles, and an anode gas diffusion layer (GDL), a cathode contacting a second side of the membrane and including a cathode GDL. The first catalyst particles are configured to preferentially catalyze oxidation of CO, and the second catalyst particles are configured to preferentially catalyze generation of hydrogen ions.

Systems for creating electrodes for polymer electrolyte membrane fuel cells include an XY stage having a heated vacuum table physically coupled to the XY stage. The vacuum table has a working face with a plurality of channels formed therein to communicate vacuum pressure from a port coupled to a vacuum source to the channels. A sheet of perforated heat-conductive material has staggered holes configured to evenly distribute the vacuum pressure from the channels through the perforated sheet. A heat-conductive wire mesh is placed over the perforated sheet, and has openings smaller than the staggered holes such that a membrane material placed on the wire mesh is not deformed by the vacuum pressure. A nanopipette or micropipette coupled to a pump is configured to deposit electrode ink onto an exposed surface of the membrane material as the controller device causes the XY stage to move the vacuum table to control deposition of the electrode ink onto the surface of the membrane material.

Coatings on carbon are of interest to the battery, fuel cell, and catalyst industries. However, carbon is difficult to process because of its cohesiveness and low density. This invention describes a method for decreasing the interparticle forces between carbon particles so that the powder does not agglomerate as much during processing. This prevents the formation of hard agglomerates during gas phase processes such as Atomic Layer Deposition (ALD) coating. The same method for decreasing agglomeration of the powder during processing may also improve the dispersion of deposited platinum onto carbon particles, either by ALD or other methods. A suspension of carbon particles coated with ionomer is also described.

A solid oxide electrochemical cell includes a solid oxide electrolyte, an anode located on a first side of the solid oxide electrolyte, and a cathode located on a second side of the solid oxide electrolyte. The cathode includes lanthanum nickel ferrite.

An object of the present invention is to provide, in the manufacture of a membrane-catalyst assembly including a polymer electrolyte membrane and a catalyst layer bonded to the polymer electrolyte membrane, a method that achieves both the relaxation of thermocompression bonding conditions and the improvement of adhesion between the catalyst layer and the electrolyte membrane with high productivity. A main object of the present invention is to provide a method of manufacturing a membrane-catalyst assembly including an electrolyte membrane and a catalyst layer bonded to the electrolyte membrane, the method including a liquid application step of applying a liquid to a surface of the catalyst layer before bonding, and a thermocompression bonding step of bonding, to the electrolyte membrane, the catalyst layer to which the liquid is applied by thermocompression bonding.

Disclosed are a mixed catalyst, a method for preparing same, a method for forming an electrode by using same, and a membrane-electrode assembly comprising same, the mixed catalyst having uniform physical features within a predetermined range, which are suitable for the manufacture of an electrode and membrane-electrode assembly having desired performance and durability. The mixed catalyst comprises: a first catalyst, which includes a first support and first catalyst metal particles distributed on the first support, and has a first BET surface area and a first total pore volume; and a second catalyst, which includes a second support and second catalyst metal particles distributed on the second support, and has a second BET surface area different from the first BET surface area and a second total pore volume different from the first total pore volume.

To make adhesiveness of a catalyst layer and a solid polymer electrolyte membrane be compatible with electrolysis performance without the need for weighting components even when an electrolyte is included in the catalyst layer, the rate of mass of the electrolyte/the catalyst of the catalyst layer including a catalyst and the electrolyte is more than 0.05 and less than 0.2.

A solid polymer electrolyte membrane having a first surface and a second surface opposite the first surface, where the solid polymer electrolyte membrane has a failure force greater than about 115 grams and comprises a composite membrane consisting essentially of (a) at least one expanded PTFE membrane having a porous microstructure of polymeric fibrils, and (b) at least one ion exchange material impregnated throughout the porous microstructure of the expanded PTFE membrane so as to render an interior volume of the expanded PTFE membrane substantially occlusive; (c) at least one substantially occlusive, electronically insulating first composite layer interposed between the expanded PTFE membrane and the first surface, the first composite layer comprising a plurality of first carbon particles supporting a catalyst comprising platinum and an ion exchange material, wherein a plurality of the first carbon particles has a particle size less than about 75 nm, or less than about 50 nm, or less than about 25 nm.

The present disclosure provides a membrane electrode assembly (MEA) with high-efficiency water and heat management for a direct ethanol fuel cell (DEFC), and a fabrication method therefor, and belongs to the technical field of fuel cells. In the MEA for a DEFC in the present disclosure, a cathode catalyst layer is designed to be convex and ordered and an anode catalyst layer is designed to be concave and ordered, which is conducive to the timely discharge of the generated heat. The MEA for a DEFC can be fabricated by gradually fabricating each layer of the MEA on an inner surface and an outer surface of a proton-exchange membrane (PEM) or by step-by-step dip coating on an anode support tube. The present disclosure can effectively improve the working capacity of the cell.

An active layer for a proton-exchange membrane fuel cell (PEMFC) including at least two perfluorosulfonate ionomers.