Described herein is a coating composition comprising: (a) a metal catalyst, wherein the metal catalyst comprises at least one of platinum, ruthenium, iridium, and alloys and combinations thereof; (b) an at least highly fluorinated ionomer comprising a polymer backbone and a plurality of first side chains pendant therefrom, wherein the first side chain comprises at least one protogenic group, wherein the protogenic group is selected from a sulfonic acid, a bis(sulfonyl)imide, a sulfonamide, a sulfonyl methide, and salts and combinations thereof, and wherein the polymer backbone comprises an average of at least 14 carbon atoms between adjacent first side chains along the polymer backbone; and (c) a solvent. Such coating compositions may be used to make electrodes for electrochemical cells and have been shown to have reduced poisoning of the catalyst.

A method of producing electrical power includes: a cathode having a porphyrin precursor attached to a substrate, and having a first enzyme, wherein the first enzyme reduces oxygen; an anode having a first region of an anode substrate and having a gold nanoparticle composition located thereon, and having a second region of the anode substrate having an enzyme composition located thereon, wherein the enzyme composition includes a second enzyme, wherein the first region and second region are separate regions; and a neutral fuel liquid in contact with the anode and cathode, the neutral fuel liquid having a neutral pH and a fuel reagent; and operating the fuel cell to produce electrical power with the neutral fuel liquid having the neutral pH and the fuel reagent.

A composite electrode includes two or more types of fibers forming a fiber network, comprising at least a first type of fibers and a second type of fibers. The first type of fibers comprises a first polymer and a first type of particles. The second type of fibers comprises a second polymer and a second type of particles. The second polymer is same as or different from the first polymer. The second type of particles are same as or different from the first type of particles.

In an example, a process includes applying a platinum catalyst ink solution to a polymeric substrate to form a platinum-coated polymeric material having a first catalytic surface area. The process further includes utilizing a laser to process a portion of the platinum-coated polymeric material to form a patterned platinum-coated proton exchange membrane (PEM) material. The patterned platinum-coated PEM material has a second catalytic surface area that is greater than the first catalytic surface area.

A method for manufacturing a membrane electrode and gas diffusion layer assembly includes: applying a catalyst ink including an ionomer to a second surface of an electrolyte membrane while conveying a first sheet in which a first surface of the electrolyte membrane is supported by a back sheet; drying the catalyst ink by blowing air vibrated with ultrasonic waves onto a surface of the catalyst ink to produce a second sheet in which a catalyst layer is provided on the second surface of the electrolyte membrane; forming a first roll by winding the second sheet; and producing a third sheet by stacking a gas diffusion layer on the catalyst layer and pressing them in a stacking direction as heating to join the catalyst layer and the gas diffusion layer while conveying the second sheet unwound from the first roll.

An adhesive layer is placed in a region outside an outer peripheral edge part of a second catalyst layer, on a second surface of an electrolyte membrane. A support frame is placed via the adhesive layer such that the second catalyst layer and a second gas diffusion layer are placed inside an opening of the support frame. A specific region as a region between the outer peripheral edge part of the second catalyst layer and an inner peripheral edge part of the opening of the support frame is present. A predetermined material is placed inside a recessed portion present on a surface of the adhesive layer inside the specific region, the predetermined material containing at least one of a first substance having an action of decomposing hydrogen peroxide and a second substance having an action of decomposing hydroxyl radicals.

Ways of making electrodes and electrodes produced thereby are provided. Dry blending of a powder mixture including a catalyst, an ionomer, and a polyether forms a blended mixture, which can be comminuted to obtain a desired particle size. A slurry of the blended mixture is formed with an aqueous medium and the slurry is coated onto a substrate to form a coated substrate. The coating can be transferred to another substrate or material for use as an electrode and/or the substrate of the coated substrate can form part of a structure, such as a membrane electrode assembly for use in a fuel cell.

Described herein are novel alumina substrate-supported thin film SOFCs that may be produced at significantly reduced cost while providing improved robustness, high electrochemical performance, and the capability of effective carbon deposition resistance while still using Ni-cermet as an anode functional layer.

Methods of making catalyst-coated membranes are provided. Application of a first catalyst ink to first side of a proton-exchange membrane forms a first electrode coating thereon. Removal of a backing from the proton-exchange membrane exposes a second side of the proton-exchange membrane permitting application of a second catalyst ink to the exposed second side of the proton-exchange membrane to form a second electrode coating thereon. The cathode catalyst ink includes a cathode catalyst, a cathode ionomer, and a cathode solvent. The anode catalyst ink includes anode particles dispersed in an inert, fluorinated, and nonpolar solvent. The anode particles include an anode catalyst, a water electrolysis catalyst, and an anode ionomer.

Disclosed is a method for manufacturing a large-area thin-film solid oxide fuel cell, the method including: preparing an anode support slurry, an anode functional layer slurry, an electrolyte slurry, and a buffer layer slurry for tape casting; preparing an anode support green film, an anode functional layer green film, an electrolyte green film, and a buffer layer green film by tape casting the slurries onto carrier films; staking the green films, followed by hot press and warm iso-static press (WIP), to prepare a laminated body; and co-sintering the laminated body.