Various embodiments provide a method of manufacturing an oxygen electrode. The method comprises: providing an electrically conductive substrate; depositing an electrocatalyst layer on the substrate; and intercalating alkali-metal ions into the catalyst layer. Some other embodiments provide an oxygen electrode manufactured in accordance with the method and a metal-air battery, a regenerative H.sub.2O.sub.2 fuel cell, a direct fuel cell, and an electrochemical cell comprising the oxygen electrode.

The present invention provides a lithium-air battery air electrode, the air electrode comprises: a collector, an in-situ loading catalyst on collector. The invention also provides a preparation method of the air electrode for lithium-air batteries and the lithium-air batteries. The air electrode of the present invention can greatly improve the performance of the lithium-air battery.

Electrodes, separators, half-cells, and full cells of electrical energy storage devices are made with electrospinning and isostatic compression. The electrical energy storage device may include electrochemical double layer capacitors (EDLCs, also known as supercapacitors), hybrid supercapacitors (HSCs), Li-ion capacitors and electrochemical storage devices, Na-ion capacitors and electrochemical storage devices, polymer electrolyte fuel cells, and still other capacitors and electrochemical storage cells.

Disclosed are a reversible fuel cell oxygen electrode in which IrO.sub.2 is electrodeposited and formed on a porous carbon material and platinum is applied thereon to form a porous platinum layer, a reversible fuel cell including the same, and a method for preparing the same. According to the corresponding reversible fuel cell oxygen electrode, as the loading amounts of IrO.sub.2 and platinum used in the reversible fuel cell oxygen electrode can be lowered, it is possible to exhibit excellent reversible fuel cell performances (excellent fuel cell performance and water electrolysis performance) by improving the mass transport of water and oxygen while being capable of reducing the loading amounts of IrO.sub.2 and platinum. Further, it is possible to exhibit a good activity of a catalyst when the present disclosure is applied to a reversible fuel cell oxygen electrode and to reduce corrosion of carbon.

A method of depositing contiguous, conformal submonolayer-to-multilayer thin films with atomic-level control is described. The process involves electrochemically exchanging a mediating element on a substrate with a noble metal film by alternatingly sweeping potential in forward and reverse directions for a predetermined number of times in an electrochemical cell. By cycling the applied voltage between the bulk deposition potential for the mediating element and the material to be deposited, repeated desorption/adsorption of the mediating element during each potential cycle can be used to precisely control film growth on a layer-by-layer basis.

A novel catalyst layer (CL) composition and structure that provides exceptional durability with sustained catalytic performance for intended heavy duty vehicle (HDV) application. This inventive composition and structure of the CL includes an internal composition composed of binder-coated nanoparticles, binder-free catalyst nanoparticles and orderly electric, ionic, gas and liquid pathways; a multi-layered structure of different packing densities among multiple sublayers; and external patterning of an outer surface of the CL. Extended durability and catalytic performance of the CL is achieved, and through use of the inventive CL, a novel solid-state electroplating process is demonstrated to achieve a novel thin-film coated catalyst product. The binder-coated nanoparticles serve as an interconnection base or site to whose binder-coated surface the uncoated nanoparticles are attached in glue-like fashion, achieving an orderly structure in which binder-free catalyst nanoparticles are consistently interspersed between binder-coated nanoparticles and agglomerates thereof.

The present invention is to provide fine catalyst particles with better catalytic performance than ever before and a carbon-supported catalyst with better catalytic performance than ever before. Disclosed is a method for producing fine catalyst particles, comprising: a potential applying step of applying a potential to the fine palladium-containing particles in a first dispersion, until a peak indicating a Pd{111} surface in a reduction wave of a cyclic voltammogram becomes larger than a peak indicating a Pd{110} or Pd{100} surface in the reduction wave of the cyclic voltammogram; a copper covering step of covering at least part of the fine palladium-containing particle with copper by preparing a second dispersion by mixing the first dispersion and a copper-containing solution after the potential applying step, and applying a potential that is nobler than the oxidation-reduction potential of copper to the fine palladium-containing particles in the second dispersion; and a platinum covering step of covering at least part of the fine palladium-containing particle with platinum by mixing the second dispersion and a platinum-containing solution after the copper covering step.

A method of producing a displacement plating precursor, including a deposition step of depositing a Cu layer on a surface of a core particle formed of Pt or a Pt alloy by contacting a Cu ion-containing acidic aqueous solution with at least a portion of a Cu electrode, and contacting the Cu electrode with the core particle or with a composite, in which the core particle is supported on an electroconductive support, within the acidic aqueous solution or outside the acidic aqueous solution, and moreover contacting the core particle with the acidic aqueous solution under an inert gas atmosphere.

The present invention relates to a method for the preparation of fibers from a catalyst solution by electrospinning and further to articles comprising such fibers.

The present invention relates to stable catalyst ink formulations comprising am electrospinning polymer selected from halogen-comprising polymers. The present invention further relates to electrospinning of such ink formulation, to the so-obtained electrospun fibrous mat as well as to articles comprising such electrospun fibrous mat.