A membrane electrode assembly includes an electrolyte membrane stacked between different electrodes, wherein an ionomer layer of the electrolyte membrane comprises an adjacent electrode, a first layer having at least a same cross-sectional area as that of the adjacent electrode, a reinforcing layer and a second layer stacked at a side of the first layer, the second layer having at least the same cross-sectional area as that of the reinforcing layer.

There are provided a positive electrode active material at which an oxygen 1s X-ray photoelectron spectroscopy spectrum obtained by X-ray photoelectron spectroscopy measurement satisfies the following condition 1 or the following condition 2: condition 1: a peak top does not exist in a region in which a binding energy is from 525 eV to less than 531 eV, and a peak top exists in a region in which the binding energy is from 531 eV to 538 eV; or condition 2: a ratio of discharge photoelectron intensity I.sub.he at a peak top, which exists in a region in which the binding energy is from 531 eV to 538 eV, with respect to discharge photoelectron intensity I.sub.le at a peak top, which exists in a region in which the binding energy is from 525 eV to less than 531 eV, is 1 or more.

A method of manufacturing a membrane-electrode assembly including an electrolyte membrane and a catalyst layer-formed gas diffusion layer bonded to the electrolyte membrane, the method including: a liquid application step of applying, in the atmosphere, a liquid to only a surface of the catalyst layer before bonding; and a thermocompression bonding step of bonding, to the electrolyte membrane, the catalyst layer-formed gas diffusion layer to which the liquid is applied, by thermocompression bonding. Provided is a method of manufacturing a membrane-electrode assembly including a polymer electrolyte membrane and a catalyst layer-formed gas diffusion layer bonded to the polymer electrolyte membrane, in which the manufacturing method can achieve both the relaxation of thermocompression bonding conditions and the improvement of adhesion between the catalyst layer-formed gas diffusion layer and the electrolyte membrane with high productivity.

The invention provides a method of treating waste comprising the steps of: providing an electrochemical cell comprising a cathode, and an anode; supplying a waste stream comprising an organic compound which is a liquid or dissolved in a solvent and contacting the anode and cathode with the waste stream; electrochemically oxidising the organic compound at the anode; supplying oxygen to the cathode; electrochemically reducing the oxygen at the cathode; wherein the cathode comprises a poison resistant oxygen reduction catalyst.

A positive electrode (10) for an air cell of the present invention includes: a catalyst layer (11) composed of a porous layer containing electrical conductive carbon (1), a binder (2), and a catalyst component (3); and a fluid-tight gas-permeable layer (12) composed of a porous layer containing an electrical conductive carbon (1a) and a binder (2). The fluid-tight gas-permeable layer is stacked on the catalyst layer. This configuration can facilitate series connection of the air cells while preventing electrolysis solution from leaking out of a positive electrode. It is therefore possible to enhance the manufacturing efficiency and handleability of the air cells.

An electrolyte membrane with a backsheet is sent out from an electrolyte membrane unwinding roller, and is separated with its second side sucked on a suction roller by a first press roller. While the electrolyte membrane from which the backsheet has been separated is transported with the electrolyte membrane sucked and supported on the suction roller, an electrode ink is applied to a first side of the electrolyte membrane to form an electrode ink layer, which is dried by blowing hot air thereto to form a catalyst layer. Thereafter, in a state in which the outer surface of a second press roller disposed close to the suction roller is in contact with and supported on the first side of the electrolyte membrane, a support film is pressed against the second side of the electrolyte membrane by a third press roller and attached thereto to manufacture a catalyst-coated membrane.

One variation of a method for fabricating an electrolyte includes: depositing an electrolyte material over a substrate, the electrolyte material including a monomer miscible in a first volume of solvent, a polymer semi-miscible in the monomer and miscible in the first volume of solvent, and a photoinitiator; exposing the electrolyte material to electromagnetic radiation to disassociate the photoinitiator into a reactive subspecie that crosslinks the monomer to form an electrolyte structure with the polymer phase-separated from the electrolyte structure; dissolving the polymer out of the electrolyte structure with a second volume of solvent to render a network of open-cell pores in the electrolyte structure; and exposing the electrolyte structure to a third volume of solvent and ions to fill the network of open-cell pores with solvated ions.

A method of manufacturing a membrane electrode assembly for hydrogen fuel cells includes mixing an electrode binder with a catalyst, followed by dispersing and thermal treatment, to prepare an electrode slurry, coating release paper with the electrode slurry to produce an electrode, and bonding the release paper-coated electrode to an electrolyte membrane, followed by thermal treatment, to perform electrode-membrane bonding.

This disclosure provides systems, methods, and apparatus related to electrode structures. In one aspect, a method includes: providing an electrode layer comprising a ceramic, the ceramic being porous; providing a catalyst precursor, the catalyst precursor being a cathode catalyst precursor or an anode catalyst precursor; infiltrating the catalyst precursor in a first side of the electrode layer; after the infiltrating operation, heating the electrode layer to about 750 C. to 950 C., the catalyst precursor forming a catalyst, the catalyst being a cathode catalyst or an anode catalyst; infiltrating the catalyst precursor in the first side of the electrode layer; after the infiltrating operation, heating the electrode layer to about 300 C. to 700 C., the catalyst precursor forming the catalyst, the catalyst being the cathode catalyst or the anode catalyst.

A fuel cell electrode comprises a three-dimensional porous composite structure comprising a porous structure comprising a plurality of metal ligaments and a plurality of pores; and at least one carbon nanotube structure embedded in the porous structure and comprising a plurality of carbon nanotubes joined end to end by van der Waals attractive force, wherein the plurality of carbon nanotubes are arranged along a same direction.