Patent classifications
H01M4/8892
ELECTRODE FOR FUEL CELL COMPRISING NON-PLATINUM CATALYST AND GRAPHENE LAYERED STRUCTURE, AND MEMBRANE-ELECTRODE ASSEMBLY COMPRISING SAME
The present invention relates to an electrode for a fuel cell, comprising a non-platinum catalyst and a graphene layered structure, and a membrane-electrode assembly comprising the same and, more specifically, to a membrane-electrode assembly for a fuel cell and a fuel cell comprising the same, which implement excellent electrode efficiency through relatively inexpensive transition metals while not using platinum, by stacking alternately with a graphene layer, a catalyst layer comprising both a non-platinum catalyst complex including a carbon support, nitrogen, and non-platinum transition metal, and a conductive polymer.
COAXIAL NANOWIRE ELECTRODE
A polymer electrolyte fuel cell (PEFC), comprises a first electrode and a second electrode, wherein the first electrode includes a coaxial nanowire electrode. In some embodiments, the coaxial nanowire electrode comprises a plurality of ionomer nanowires, and a catalyst coating that coats at least part of the ionomer nanowires. Moreover, in some embodiments, a nanowire of the plurality of ionomer nanowires and a section of the catalyst coating that coats the nanowire form two coaxial cylinders.
ELECTROLYTE MEMBRANE FOR MEMBRANE-ELECTRODE ASSEMBLY AND METHOD OF MANUFACTURING SAME
A highly durable electrolyte membrane using cerium oxide supported with an alloy catalyst that is a hydrogen-oxygen reaction catalyst for improving chemical durability of an electrolyte membrane increases durability of a membrane-electrode assembly including the same and decreases the manufacturing cost thereof.
Mesoporous carbon, electrode catalyst for fuel cell, catalyst layer, fuel cell, and method for producing mesoporous carbon
Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm.sup.3/g or more and 1.34 cm.sup.3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.
CATALYST COATED MEMBRANE (CCM) FOR ALKALINE EXCHANGE MEMBRANE FUEL CELL AND METHOD OF MAKING SAME
A catalyst coated membrane (CCM) for an alkaline exchange membrane fuel cell may include: a membrane including at least one of: a polymer or a copolymer having a first functional chemical group; an anode catalyst layer coated on one side of the membrane including: anode catalyst nano-particles and a polymer or a copolymer having a second functional chemical group; and a cathode catalyst layer coated on a side of the membrane opposite the anode catalyst layer, including: cathode catalyst nano-particles and a polymer or a copolymer having a third functional chemical group, wherein the first functional chemical group, the second functional chemical group and the third functional chemical group are all crosslinked with the same crosslinking chemical group.
Fuel cell with selectively conducting anode
Use of a selectively conducting anode component in solid polymer electrolyte fuel cells can reduce the degradation associated with repeated startup and shutdown, but can also adversely affect a cell's tolerance to voltage reversal along with its performance. It was shown that these adverse affects can be mitigated against in certain ways. However, improved results can be obtained by employing a selectively conducting component which comprises a mixed layer of a selectively conducting material and carbon. The mixed layer contacts the side of the anode opposite the solid polymer electrolyte.
Cathode electrocatalyst and fuel cell
The present invention is related to fuel cells and fuel cell cathodes, especially for fuel cells using hydrogen peroxide, oxygen or air as oxidant. A supported electrocatalyst (204) or unsupported metal black catalyst (206) of cathodes according to an embodiment of the present invention is bonded to a current collector (200) by an intrinsically electron conducting adhesive (202). The surface of the electrocatalyst layer is coated by an ion-conducting ionomer layer (210). According to an embodiment of the invention these fuel cells use cathodes that employ ruthenium alloys RuMe.sub.IMe.sub.II such as ruthenium-palladium-iridium alloys or quaternary ruthenium-rhenium alloys RuMe.sub.IMe.sub.IIRe such as ruthenium-palladium-iridium-rhenium alloys as electrocatalyst (206) for hydrogen peroxide fuel cells. Other embodiments are described and shown.
Metal gas diffusion layer for fuel cells, and method for manufacturing the same
A method for manufacturing a metal gas diffusion layer made of a metal porous body, the method includes forming a conductive layer of carbon film layer on the metal porous body, and forming a water-repellent layer on the metal porous body formed with the conductive layer. The forming a water-repellent layer includes coating a solution containing a fluorine resin which constitutes the water-repellent layer and a volatile component which does not constitute the water-repellent layer on the metal porous body, and heat-treating the metal porous body coated with the solution at or above a temperature at which a component which contains the volatile component and which does not constitute the water-repellent layer contained in the solution and less than a temperature at which an electrical resistance of the conductive layer is increased and electron conductivity is deteriorated to thereby form the water-repellent layer composed of the fluorine resin.
Inks for nanofiber fuel cell electrode and membrane-electrode-assemblies, and methods of ink formulations
An ink for forming nanofiber fuel cell electrodes, and methods of ink formulations, and membrane-electrode-assemblies for electrochemical devices. The ink includes a first amount of a catalyst, a second amount of an ionomer in a salt form, and a third amount of a carrier polymer dispersed in one or more solvents, where a weight ratio of the first amount to the second and third amounts is in a range of about 1-1.5, and a weight ratio of the second amount to the third amount is in a range of about 1-3. The ink has a solids concentration in a range of about 1-30 wt %. Preferably, the solids concentration is in a range of about 10-15%.
Catalyst for solid polymer fuel cell and method for manufacturing the same
Provided is a catalyst for solid polymer fuel cell that exhibits excellent initial activity and favorable durability and a method for manufacturing the same. The invention is a catalyst for solid polymer fuel cell which is formed by supporting catalyst particles including platinum, cobalt and manganese on a carbon powder carrier, wherein a composition ratio (molar ratio) among platinum, cobalt and manganese in the catalyst particles is Pt:Co:Mn=1:0.06 to 0.39:0.04 to 0.33, a peak intensity ratio of a CoMn alloy appearing in the vicinity of 2=27 is 0.15 or less with respect to a main peak appearing in the vicinity of 2=40 in X-ray diffraction analysis of the catalyst particles, and a fluorine compound having a CF bond is supported at least on the surface of the catalyst particles. The amount of the fluorine compound supported is preferably from 3 to 20% with respect to the entire mass of the catalyst.