In one aspect, the disclosure relates to method of forming an electrocatalyst structure on an electrode, comprising depositing a first layer on the electrode using atomic layer deposition (ALD), wherein the first layer comprises a plurality of discrete nanoparticles of a first electrocatalyst, and depositing one or more of a second layer on the first layer and the electrode using ALD, wherein the one or more second layer comprises a second electrocatalyst, wherein the first layer and the one or more second layers, collectively, form a multi-layer electrocatalyst structure on the electrode. Also disclosed are electrodes having a multi-layer electrocatalyst structure. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Electrode-supported tubular solid-oxide electrochemical cells suitable for use in electrochemical chemical synthesis and processes for manufacturing such are provided.

A metal-supported cell comprises a laminate wherein a fuel electrode layer and a solid electrolyte layer are sequentially arranged in this order on a front surface of a metal support provided with a pore continuing from the front surface to the back surface. The solid electrolyte layer covers all parts of the surface of the fuel electrode layer, the parts being not in contact with the metal support. The peripheral part of the solid electrolyte layer is in contact with the front surface of the metal support. The metal support has a metal oxide layer. The fuel electrode layer contains NiO and Ni with molar ratio NiO/(Ni+NiO) of 45% or more, while containing gadolinium-doped ceria. The solid electrolyte layer mainly contains scandia-stabilized zirconia, while containing 0.1-10.0 mol of Bi atoms per 100 mol of Zr atoms having cross-sectional void fraction of 5.0% or less.

The present embodiment describes a method of forming different layers in a solid oxide fuel cell. The method begins by preparing slurries which are then delivered to a spray nozzle. The slurries are then atomized and sprayed subsequently onto a support to produce a layer which is then dried. In this embodiment different layers can comprise an anode, an electrolyte and a cathode. Also the support can be a metal or a metal oxide which is later removed.

A battery performance of a metal-air battery is improved while still maintaining a low environmental burden. A metal-air battery includes an air electrode formed from a co-continuous substance having a three-dimensional network structure in which a plurality of nanostructures are integrated by noncovalent bonds; an anode; and an electrolyte disposed between the air electrode and the anode, in which the electrolyte is a gel electrolyte obtained by gelling an aqueous solution containing an ion conductor with a gelling agent, and the gelling agent is constituted of at least one of a plant-derived polysaccharide, a seaweed-derived polysaccharide, a microbial polysaccharide, an animal-derived polysaccharide, and a group of acetic acid bacteria that produce the polysaccharides.

A novel method to modify the surface of lanthanum and strontium containing cathode powders before or after sintering by depositing layers of gadolinium doped ceria (GDC) and/or samarium doped ceria or similar materials via atomic layer deposition on the powders. The surface modified powders are sintered into porous cathodes that have utility enhancing the electrochemical performance of the cathodes, particularly for use in solid oxide fuel cells. Similar enhancements are observed for surface treatment of sintered cathodes.

A catalyst layer comprising an electrocatalyst and an oxygen evolution catalyst, wherein the oxygen evolution catalyst comprises a crystalline metal oxide comprising: (i) one of more first metals selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, magnesium, calcium, strontium, barium, sodium, potassium, indium, thallium, tin, lead, antimony and bismuth; (ii) one or more second metals selected from the group consisting of Ru, Ir, Os and Rh; and (iii) oxygen
characterised in that: (a) the atomic ratio of first metal(s):second metal(s) is from 1:1.5 to 1.5:1 (b) the atomic ratio of (first metal(s)+second metal(s)):oxygen is from 1:1 to 1:2 is disclosed.

A solid oxide cell includes a fuel electrode, an air electrode, and an electrolyte disposed between the fuel electrode and the air electrode. The fuel electrode may include a porous metal body having pores and a barrier portion disposed in the pores of the porous metal body, and the barrier portion has a shape of at least one of a sheet shape and a flake shape.

This invention relates to aqueous ink compositions comprising an aqueous solvent, particles comprising a metal or a metal compound or a mixture thereof, a dispersant, preferably selected from an electrostatic dispersant, a steric dispersant, an ionic dispersant, a non-ionic dispersant or a combination thereof, a polymeric binder and a non-ionic surfactant which may be used for 3D inkjet printing components, primarily for high-temperature electrochemical devices.

An air electrode material according to the present disclosure contains a plurality of composite particles, wherein each of the composite particles contains a core particle and a plurality of covering particles covering the core particle, the core particle is formed of a material with catalytic activity for an oxygen reduction reaction, the covering particles are formed of an electrically conductive material and are mechanically bonded to the core particles or other covering particles, and the median size of the core particles ranges from 100 to 1000 times the average primary particle size of the covering particles.