Patent classifications
H01M4/9025
Metal-Supported Electrochemical Element, Solid Oxide Fuel Cell and Method of Manufacturing Such Metal-Supported Electrochemical Element
Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.
DURABLE FUEL ELECTRODE
The present invention relates to a composite for an electrode, a composite precursor, a method of manufacturing a composite, and the composite obtained by said method. The invention further relates to an electrode comprising the composite, as well as a solid state electrochemical cell comprising the composite. The invention also relates to the use of the composite as a fuel electrode, solid oxide fuel cell, and/or solid oxide electrolyser. The invention discloses a composite for an electrode, comprising a three-dimensional network of dispersed metal particles, stabilised zirconia particles and pores, wherein the size of the pores is smaller than the size of the metal particles, wherein the size of the metal particles is essentially equal to or smaller than the size of the stabilised zirconia particles, wherein the porosity is below 33, 30, or 29 vol %, more preferably below 26 or 24 vol %, and most preferably below 23, 22, 21, 18, 15, or 13 vol %, and/or wherein the pores are essentially exclusively generated from the volume created by reducing a corresponding metal oxide to the metal particles.
Solid electrolyte laminate, method for manufacturing solid electrolyte laminate, and fuel cell
Provided is a solid electrolyte laminate comprising a solid electrolyte layer having proton conductivity and a cathode electrode layer laminated on one side of the solid electrolyte layer and made of lanthanum strontium cobalt oxide (LSC). Also provided is a method for manufacturing the solid electrolyte. This solid electrolyte laminate can further comprise an anode electrode layer made of nickel-yttrium doped barium zirconate (NiBZY). This solid electrolyte laminate is suitable for a fuel cell operating in an intermediate temperature range less than or equal to 600 C.
Porous ceramic molten metal composite solid oxide fuel cell anode
A fuel cell anode comprises a porous ceramic molten metal composite of a metal or metal alloy, for example, tin or a tin alloy, infused in a ceramic where the metal is liquid at the temperatures of an operational solid oxide fuel cell, exhibiting high oxygen ion mobility. The anode can be employed in a SOFC with a thin electrolyte that can be a ceramic of the same or similar composition to that infused with the liquid metal of the porous ceramic molten metal composite anode. The thicknesses of the electrolyte can be reduced to a minimum that allows greater efficiencies of the SOFC thereby constructed.
CATALYST ELECTRODE FOR OXYGEN EVOLUTION AND METHOD FOR PREPARING THE SAME
The present invention provides a catalyst electrode for oxygen evolution comprising an electrode current collector comprising a carbon fiber fabric, a nanowire layer comprising a metal oxide-based porous nanowire grown radially from the surface of the carbon fiber, and a porous carbon coating layer disposed around the outer surface of the nanowire, thereby maximizing the specific surface area and increasing the electron transfer rate, and thus exhibiting an excellent catalytic activity for oxygen evolution reaction, and a preparation method thereof.
Pre-Equilibrium System and Method Using Solid-State Devices as Energy Converters Using Nano-Engineered Porous Network Materials
An energy conversion device for conversion of various energy forms into electricity. The energy forms may be chemical, photovoltaic or thermal gradients. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The substrate itself can be planar, two-dimensional, or three-dimensional, and possess internal and external surfaces. These substrates may be rigid, flexible and/or foldable. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous conductor material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous conductor material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.
Fuel cell system with interconnect
The present invention includes an integrated planar, series connected fuel cell system having electrochemical cells electrically connected via interconnects, wherein the anodes of the electrochemical cells are protected against Ni loss and migration via an engineered porous anode barrier layer.
LOW TEMPERATURE SOLID OXIDE CELLS
The present invention provides solid oxide cells such as fuel cells, electrolyzers, and sensors comprising an electrolyte having an interface between an yttria-stabilized zirconia material and a glass material, in some embodiments. Other embodiments add an interface between a platinum oxide material and the yttria-stabilized zirconia material in the electrolyte. Further embodiments of solid oxide cells have an ion-conducting species such as an ionic liquid or inorganic salt in contact with at least one electrode of the cell. Certain embodiments provide room temperature operation of solid oxide cells.
Strontium magnesium molybdenum oxide material having double perovskite structure and method for preparing the same
The present invention relates to a strontium magnesium molybdenum oxide material having perovskite structure and the method for preparing the same. Citric acid is adopted as the chelating agent. By using sol-gel pyrolysis and replacing a portion of strontium in Sr.sub.2MgMoO.sub.6- by cerium and a portion of magnesium by copper, a material with a chemical formula of Sr.sub.2-xCe.sub.xMg.sub.1-yCu.sub.yMoO.sub.6- is produced, where 0x<2, 0<y<1, and 0<<6. Thereby, the electrical conductivity of the material is improved. The perovskite-type cerium- and copper-replaced strontium magnesium molybdenum oxide significantly increases the electrical conductivity of the material and can be applied as the anode material for solid oxide fuel cell (SOFC).
Fuel cell
A fuel cell comprises an anode, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. The solid electrolyte layer contains a zirconia-based material as a main component. A first intensity ratio of tetragonal crystal zirconia to cubic crystal zirconia in a Raman spectrum in a central portion of the solid electrolyte layer is greater than a second intensity ratio of tetragonal crystal zirconia to cubic crystal zirconia in a Raman spectrum of an outer edge.