H01M4/921

METHOD FOR PRODUCING ALLOY FINE PARTICLE-SUPPORTED CATALYST, ELECTRODE, FUEL CELL, METHOD FOR PRODUCING ALLOY FINE PARTICLE, ALLOY FINE PARTICLE-SUPPORTED CATALYST, ALLOY FINE PARTICLE, METHOD FOR PRODUCING MEMBRANE ELECTRODE ASSEMBLY, AND METHOD FOR PRODUCING FUEL CELL
20220238892 · 2022-07-28 · ·

A method for producing an alloy fine particle-supported catalyst that supports alloy fine particles containing a noble metal includes: a step of mixing a noble metal salt, a base metal salt, an alcohol having 1 to 5 carbon atoms, and a support to form a mixture; and a heating step of heating the mixture at a temperature of 150° C. or higher and 800° C. or lower to produce an alloy fine particle-supported catalyst.

CATALYST

Catalyst comprising an Ir layer having an outer layer with a layer comprising Pt directly thereon, wherein the Ir layer has an average thickness in a range from 0.04 to 30 nanometers, wherein the layer comprising Pt has an average thickness in a range from 0.04 to 50 nanometers, and wherein the Pt and Ir are present in an atomic ratio in a range from 0.01:1 to 10:1. Catalysts described herein are useful, for example, in fuel cell membrane electrode assemblies.

Method of generating energy from a hydrazide containing anode fuel, and fuel cell

The present disclosure relates to a method of generating energy. This method involves providing a fuel cell comprising anode and cathode electrodes; a separator positioned between the anode and cathode electrodes; and anode and cathode catalysts. The anode catalyst comprises (i) a low-loading of platinum group metals (PGMs) supported on a Group 4-6 transition metal carbide (TMC) or nitride (TMN); (ii) an alloy or physical mixture comprising a Group 10 transition metal selected from Pt, Pd, and Ni and one or more of the following elements: Pt, Pd, Ni, Ir, Rh, Ru, Fe, Re, Sn, W, Mo, Ta, and Nb; or (iii) mixtures thereof. According to the method, a liquid anode fuel comprising one or more hydrazide compounds is added to the fuel cell to generate energy from the liquid anode fuel. Also disclosed is a fuel cell for generating energy from a liquid anode fuel comprising one or more hydrazide compounds.

FUEL CELL CATALYST, MANUFACTURING METHOD THEREFOR, AND MEMBRANE-ELECTRODE ASSEMBLY INCLUDING SAME

Disclosed are a fuel cell catalyst of which only a portion, which has relatively low catalytic activity and in which the greatest amount of platinum elution occurs and platinum oxide is easily formed, is selectively coated with a protective layer, and thus degradation due to the long-term operation of a fuel cell can be effectively prevented while also minimizing a deterioration in catalytic activity; a manufacturing method therefor; and a membrane-electrode assembly including same. The fuel cell catalyst of the present invention comprises: a nanoparticle containing platinum; and a protective layer which is selectively coated on only a portion of the surface of the nanoparticle and can suppress the oxidation of the platinum through electronic interaction with the nanoparticle.

INTERMETALLIC CATALYST AND METHOD FOR PREPARING THE SAME
20220231306 · 2022-07-21 ·

Provided is a method of preparing an intermetallic catalyst. The method includes form core-shell particles including a transition metal oxide coating layer by irradiating ultrasonic waves to a precursor mixture solution including a noble metal precursor, a transition metal precursor, and a carrier to; forming intermetallic particles including a transition metal oxide coating layer by annealing the core-shell particles; and removing the transition metal oxide coating layer from the intermetallic particles.

CATALYST AND METHOD FOR PREPARING THE SAME

The present specification relates to a carrier-nanoparticle complex, a catalyst including the same, an electrochemical cell or a fuel cell including the catalyst, and a method for preparing the same.

HIGH STABILITY PLATINUM-BASED ELECTROCHEMICAL CATALYSTS

An electrode material includes: (1) a catalyst support; and (2) PtNiN-M nanostructures affixed to the catalyst support, wherein N is a transition metal selected from Group 9 and Group 11 of the Periodic Table, and M is a transition metal selected from Group 5 and Group 6 of the Periodic Table.

PATTERNED CATALYST LAYERS IN FUEL CELLS

A fuel cell includes a flow field plate having at least one channel and at least one land, where each of the at least one channel is positioned between two adjacent lands. The fuel cell further includes a gas diffusion layer (GDL) positioned between the flow field plate and a catalyst layer, where the catalyst layer has a first region aligned with the at least one channel and a second region aligned with the at least one land. The first region may have a first catalyst material supported by a first catalyst support region, and the second region may have a second catalyst material supported by a second catalyst support region.

Carbon Dioxide Redox Flow Battery Having a Bi-Functional Negative Electrode
20210399328 · 2021-12-23 ·

A redox flow battery (“CRB”) performs as an energy storage system and has a negative electrode that directly utilizes CO.sub.2 in the battery charge step as an active species instead of metals. The CRB also has a positive electrode utilizing a metallic or non-metallic redox species, and a cation exchange membrane in between the negative and positive electrodes. The negative electrode comprises a porous base layer, a porous intermediate layer containing a metal oxide and a bi-functional catalyst layer for electrochemical reduction of CO.sub.2 or carbonate to formate and for formate oxidation to either carbonate or CO.sub.2. The bi-functional catalyst can be a PdSn based catalyst, such as PdSn, PdSnIn, and PdSnPb. The metal oxide in the intermediate layer acts as a catalyst support and can be a non-Platinum group metal (PGM) oxide, such as LaCoO.sub.3 or LaNiO.sub.3.

PROCESS FOR PRODUCING ALLOY NANOPARTICLES

The present invention relates to a process for the production of metal alloy nanoparticles which catalyse the oxygen reduction reaction (ORR) for use in proton exchange membrane fuel cells (PEMFC) or electrolyser cells. In particular, the present invention relates to a process for producing alloy nanoparticles from platinum group metals and other metals under reductive conditions. In particular the present invention relates to a process for producing alloy nanoparticles comprising the steps of mixing a salt of at least one metal, a material comprising a platinum group metal, a nitrogen-rich compound, and optionally a support material, to provide a precursor mixture, and heating said precursor mixture to a temperature of at least 400° C., in the presence of a gas comprising hydrogen (H.sub.2), to provide said alloy nanoparticles.