Patent classifications
H01M4/925
Catalyst complex for fuel cell, method of manufacturing the catalyst complex, electrolyte membrane including the catalyst complex and method of manufacturing the electrolyte membrane
Disclosed are a catalyst complex and a method of manufacturing the same. The catalyst complex may be manufactured by uniformly depositing metal catalyst particles on pretreated support particles through an atomic layer deposition process using a fluidized-bed reactor, which may be then uniformly dispersed throughout the ionomer solution. As such, manufacturing costs may be reduced due to the use of a small amount of metal catalyst particles and the durability of an electrolyte membrane and OCV may increase. Further disclosed are a method of manufacturing the catalyst complex, an electrolyte membrane including the catalyst complex, and a method of manufacturing the electrolyte membrane.
HYBRID CATALYST SUITABLE FOR USE IN PROTON EXCHANGE MEMBRANE FUEL CELL
Hybrid catalyst suitable for use in a proton exchange membrane fuel cell and method of preparing same. In one embodiment, the hybrid catalyst is iron-free and includes an Mn—N—C support and platinum-containing nanoparticles that are dispersed on the Mn—N—C support. The Mn—N—C support preferably comprises atomically dispersed and nitrogen coordinated MnN.sub.4 moieties and has a particle size of about 30 to 200 nm. The platinum-containing nanoparticles preferably have a particle size ranging from about 2 to 8 nm and are made of platinum or a platinum-cobalt intermetallic alloy, such as a cubic L1.sub.2 Pt.sub.3Co alloy or a tetragonal L1.sub.0 PtCo alloy. The hybrid catalyst may be made by combining a quantity of a hexachloroplatinic acid solution with a quantity of an Mn—N—C support, sonicating the mixture in an ice bath, freeze-drying the sonicated product, calcinating the freeze-dried product under a forming gas, and heating the calcinated product.
Method of manufacturing catalyst ink free of eluted transition metal for fuel cell
Disclose is a method of manufacturing catalyst ink for a fuel cell, and particularly the method includes removing eluted transition metal from a noble-metal/transition-metal alloy catalyst.
Fuel cell components protected with nitride materials
A fuel cell component including a fuel cell substrate and a nitride material. The material may be a nitride compound having a chemical formula A.sub.xB.sub.yN.sub.z, where A is a metal, B is a metal different than A, N is nitrogen, x>0, y<7 and 0<z<12. The nitride compound may have a ratio of a stoichiometric factor to a reactivity factor of greater than 1.0. The stoichiometric factor indicates the reactivity of a nitride compound with chemical species as compared to a baseline nitride compound. The reactivity factor indicates the reaction enthalpy of the nitride compound and the chemical species as compared to a baseline nitride compound and the chemical species. The nitride compound may be Fe.sub.3Mo.sub.3N, Ni.sub.2Mo.sub.3N, Ni.sub.2W.sub.3N, CuNi.sub.3N, Fe.sub.3WN, Zn.sub.3Nb.sub.3N, V.sub.3Zn.sub.2N or a combination thereof. The nitride compound may be Si.sub.6Y.sub.3N.sub.11, Ni.sub.2Mo.sub.4N, Fe.sub.3Mo.sub.5N.sub.6 or a combination thereof.
Cathode electrode catalyst of fuel cell, and reaction acceleration method
Provided are (i) a catalyst that has a core-shell structure and is highly active in an oxygen reduction reaction, which is a cathode reaction of a fuel cell, and (ii) a reaction acceleration method in which the catalyst is used. A core-shell catalyst for accelerating an oxygen reduction reaction, contains: silver or palladium as a core material; and platinum as a shell material, the core-shell catalyst having, on a surface thereof, a (110) surface of a face centered cubic lattice.
METHOD FOR CONSTRUCTING STARCH FUEL CELL WITH ANODE
A method for constructing a starch fuel cell with an anode belongs to the field of fuel cells. The method includes using a PdNFs/FeNPs/MFC electrode as a working electrode, an Ag/AgCl electrode as a reference electrode, and a platinum wire as an auxiliary electrode to form a three-electrode system. The method includes placing the three-electrode system in a starch solution and a supporting electrolyte; setting the potential as −0.2 to 1.3V. The method includes recording the cyclic voltammetry curves of the starch with concentrations of 1 mmol/L, 3 mmol/L, 5 mmol/L, 7 mmol/L, and 10 mmol/L. The method includes analyzing the control process of the electrode electrocatalytic oxidization of the starch solution by the standard curve method. The present fuel cell can be used to manufacture portable power banks, and can be used in power plants, electric vehicles and other fields.
TUBE-SHAPED CATALYST COMPLEX AND CATALYST SLURRY INCLUDING SAME FOR FUEL CELL
The present disclosure relates to a tube-shaped catalyst complex and a catalyst slurry including the same for a fuel cell. The catalyst complex for a fuel cell comprises a tubular inner layer including an ionomer and an outer layer provided on an outer surface of the inner layer and including a catalyst.
MATERIALS AND METHODS OF MANUFACTURE
An array includes a support substrate, surface structures protruding from a surface of the support substrate formed from or coated with a first material, a second material deposited on at least some of the surface structures such that the second material is in contact with the first material; and wherein the first material, the second material or the first and second material is conducting or semiconducting, and wherein the first and second material at least partially form a composite.
Membrane electrode assembly with a catalyst layer including an inorganic oxide catalyst carrier and a highly hydrophobic substance and solid polymer fuel cell using the assembly
A membrane-electrode assembly including a catalyst layer that includes a catalyst-supporting carrier in which a catalyst is supported on a carrier made of an inorganic oxide, and a highly hydrophobic substance having a higher degree of hydrophobicity than the inorganic oxide, the catalyst layer being formed on at least one surface of a polymer electrolyte membrane. It is preferable that, in the membrane-electrode assembly, the degree of hydrophobicity of the highly hydrophobic substance is from 0.5 vol % to 45 vol % at 25° C., the degree of hydrophobicity being defined as a concentration of methanol (vol %) when a light transmittance of a dispersion obtained by dispersing the highly hydrophobic substance in a mixed solution of water and methanol reaches 80%.
Electrode catalyst layer, membrane electrode assembly and polymer electrolyte fuel cell
Provided are an electrode catalyst layer, a membrane electrode assembly and a polymer electrolyte fuel cell, having sufficient drainage property and gas diffusibility with high power generation performance over a long term. An electrode catalyst layer (10) bonded to a surface of a polymer electrolyte membrane (11) includes at least a catalyst substance (12), a conductive carrier (13), a polymer electrolyte (14) and fibrous substances (15). The number of the fibrous substances (15) in which inclination θ of axes with respect to a surface of the electrode catalyst layer (10) bonded to the surface of the polymer electrolyte membrane (11) is 0°≤θ<45°, among the fibrous substances (15), is greater than 50% of the total number of the fibrous substances (15) contained.