An energy conversion device for conversion of various energy forms into electricity. The energy forms may be chemical, photovoltaic or thermal gradients. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The substrate itself can be planar, two-dimensional, or three-dimensional, and possess internal and external surfaces. These substrates may be rigid, flexible and/or foldable. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous conductor material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous conductor material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.

A process for preparing a catalyst material, said catalyst material comprising a support material, a first metal and one or more second metals, wherein the first metal and the second metal(s) are alloyed and wherein the first metal is a platinum group metal and the second metal(s) is selected from the group of transition metals and tin provided the second metal(s) is different to the first metal is disclosed. The process comprises depositing a silicon oxide before or after deposition of the second metal(s), alloying the first and second metals and subsequently removing silicon oxide. A catalyst material prepared by this process is also disclosed.

Embodiments described herein relate to methods for preparing catalysts and catalyst supports. In one embodiment, transition metal carbide materials, having a nanotube like morphology, are utilized as a support for a precious metal catalyst, such as platinum. Embodiments described herein also relate to proton exchange membrane fuel cells that incorporate the catalysts described herein.

The present disclosure relates to a fluorine-doped tin oxide support, a platinum catalyst for a fuel cell comprising the same, and a method for producing the same. The present disclosure has a high electrical conductivity and electrochemical durability by doping fluorine to the tin oxide-based support through an electrospinning process. Thus, while resolving a degradation issue of the carbon support in the conventional commercially available platinum/carbon (Pt/C) catalyst, the present disclosure is designed to minimize an electrochemical elution of dopant or tin, which is a limitation of the tin oxide support itself and has excellent performance as a catalyst for a fuel cell.

The invention relates to electrocatalysts comprising a carbonitride (CN) shell featuring good electrical conductivity, coordinating suitable catalytically active sites. In a preferred aspect of the invention, the aforesaid carbonitride shell coordinates nanoparticles or aggregates of nanoparticles, on which the active sites of the electrocatalyst are located. In a preferred form of the invention, said carbonitride shell covers suitable cores with good electrical conductivity. Said electrocatalysts are obtained through a process involving the pyrolysis of suitable precursors; in one aspect of the invention, the preparation process requires certain further steps. In one preferred aspect, the steps comprise one or more of the following: chemical treatments; electrochemical treatments; further pyrolysis processes.

A system produces inert gas and generates electrical power with an electrochemical cell with an anode and a cathode separated by a proton transfer medium separator. The anode includes an oxygen evolution reaction catalyst and a hydrogen oxidation reaction catalyst, and the system is operated in alternate modes: a first mode in which water is electrolyzed at the anode with an oxygen evolution reaction catalyst to form protons and oxygen, the protons are transported across the separator to the cathode and reacted with oxygen at the cathode, and an inerting gas depleted of oxygen is discharged from the cathode; and a second mode in which protons and electrons are produced from a fuel at the anode with a hydrogen oxidation reaction catalyst, protons are transported across the separator to the cathode, and electrons are transported to the cathode through an electrical circuit to produce electrical power.

The use of an electrocatalyst material in an anode catalyst layer, wherein the electrocatalyst material comprises a support material, the support material comprising a plurality of individual support particles or aggregates wherein each individual support particle or aggregate has dispersed thereon (i) first particles and (ii) second particles, wherein: (i) the first particles comprise Pt optionally alloyed with an alloying metal X1; wherein the optional alloying metal X1 is selected from the group consisting of Rh, Ti, Os, V, Co, Ni, Ga, Hf, Sn, Ir, Pd, Mo, Zn, W, Zr and Re; (ii) the second particles consist essentially of a second metal or a second metal compound wherein the second metal is selected from the group consisting of Ir and Ru and the second metal compound comprises IrX2 wherein X2 is selected from the group consisting of Ta, Nb, Ru, Ni and Co; and wherein if the first particles consist of Pt then the second particles do not comprise IrTa; and wherein if the first particles consist of Pt without alloying metal X1 and the second particles consist essentially of a second metal which is Ir, each individual support particle or aggregate of the support material of the electrocatalyst material has dispersed thereon only the said first and second particles; or wherein each individual support particle or aggregate has dispersed thereon (i) first particles and (ii) third particles, wherein: (iii) the third particles comprise Au or a third metal alloy; wherein the third metal alloy is selected from the group consisting of AuX3 and PdX4, wherein X3 is selected from the group consisting of Pt, Pd, Cu, Ir and Sn; and X4 is selected from the group consisting of Hg, Au, Sn, Co, Ni, Ga, In, Zn, W and Pb.

Described herein relates to a high-entropy alloy (hereinafter HEA) catalyst and a method of optimizing a catalytic reaction within an electrochemical cell. The HEA catalyst may be fabricated from the following which includes but is not limited to Platinum acetylacetonate, Palladium acetylacetonate, Iron acetylacetonate, Cobalt acetylacetonate, Nickel acetylacetonate, Manganese acetylacetonate, Potassium, Ethanol, Perchloric Acid, Oleylamine, 1-Octadecene, and/or Cyclohexane. The HEA catalyst may provide a substantially decreased polarization overpotential and active energy barrier for the electrochemical cell. In addition, the HEA catalyst may operate stably at a constant working voltage for a substantial period of time, with a negligible performance decay of the output density, whether using O.sub.2 and/or air as cathode feeding. As such, the HEA catalyst may be used with the electrochemical cell to replace a H.sub.2O.sub.2 fuel cell, since the HEA catalyst provides similar power density with long-term operating, solving the storage and transportation problems of H.sub.2.

An energy conversion device for conversion of various energy forms into electricity. The energy forms may be chemical, photovoltaic or thermal gradients. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The substrate itself can be planar, two-dimensional, or three-dimensional, and possess internal and external surfaces. These substrates may be rigid, flexible and/or foldable. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous conductor material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous conductor material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.

An inorganic structure body has a free-standing structure including a fibrous member and/or a shell. The fibrous member and/or the shell include a metal and/or an inorganic material and have a three-dimensionally continuous configuration. The free-standing structure may have a structure that is based on a nonwoven fabric or a porous membrane used as a substrate.