The present disclosure provides an electrolytic solution having high reduction stability. An electrolytic solution, wherein the electrolytic solution is used in a fluoride ion battery, and the electrolytic solution includes a Li salt, a F salt, and a trialkyl phosphate.

An electrolyte composition comprising: a) a solvent comprising: a mixture of at least two saturated cyclic carbonates, at least one of these saturated cyclic carbonates being fluorinated, at least one ether, said at least one saturated cyclic carbonate representing at most 1.5% by weight of the solvent, said at least one ether representing at least 40% by weight of the solvent; b) at least one lithium salt other than lithium difluorophosphate; c) lithium difluorophosphate in an amount representing from 0.1 to 1% by weight relative to the sum of weight of the solvent and weight of said at least one lithium salt. The use of this composition in an electrochemical cell comprising a lithium anode allows increased performance of the cell when it is discharged under a strong current at low temperature, and limited self-discharging when in operation at ambient temperature.

The present disclosure relates to an electrolyte suitable for a lithium primary battery. In order to solve the problems of poor safety performance, high-rate discharge and poor discharge performance of electrolytes of the existing lithium primary batteries under a high-temperature condition, the electrolyte includes an electrolyte lithium salt, an additive, and an organic solvent, wherein the electrolyte lithium salt includes one or more of lithium trifluoromethanesulfonate, lithium bis(triflu-oromethanesulphonyl)imide, lithium difluorophosphate, and lithium difluoro(oxalato)borate; the additive includes one or more of (2-trimethylsilylethyl)2-cyanoacetate, diphenyldimethoxysilane, and citraconic anhydride; and the organic solvent comprises a carbon-ate solvent and a glycol ether solvent. A selective combination of the electrolyte lithium salt, the additive, and the solvent, normal-temperature discharge can be met when the electrolyte is applied to the lithium primary battery. The lithium primary battery can take into account the constant/high temperature performance, high-rate discharge performance and safety performance.