The disclosure relates to bipolar plates used in fuel cells and to methods for forming bipolar plates. A bipolar plate of a fuel cell with a composite corrosion-resistant, gastight, conductive coating comprises a core of a required shape, a first layer having high contact conductivity on the core, and a second layer having corrosion resistance, high gas-tightness, electric conductivity on the first layer and in pores of the first layer, the second layer covering at least the pores in the first layer. The first layer is preferably formed by a magnetron sputtering method, and the second layer is preferably formed by a method of thermolysis of a metalorganic compound. This ensures high gas-tightness and elasticity of a bipolar plate without compromising its corrosion resistance and contact conductivity.

The disclosure relates to bipolar plates used in fuel cells and to methods for forming bipolar plates. A bipolar plate of a fuel cell with a composite corrosion-resistant, gastight, conductive coating comprises a core of a required shape, a first layer having high contact conductivity on the core, and a second layer having corrosion resistance, high gas-tightness, electric conductivity on the first layer and in pores of the first layer, the second layer covering at least the pores in the first layer. The first layer is preferably formed by a magnetron sputtering method, and the second layer is preferably formed by a method of thermolysis of a metalorganic compound. This ensures high gas-tightness and elasticity of a bipolar plate without compromising its corrosion resistance and contact conductivity.

Solid oxide fuel cells that include an alumina substrate as support are described. The alumina substrate supported SOFCs can exhibit desirable electrochemical characteristics including high performance at intermediate temperatures and excellent thermal stability. The alumina substrate support is formed according to a modified phase-inversion process that forms a series of aligned micro-channels extending from a first side to a second opposite side of the support enabling gas distribution between an electrode (e.g., an anode) located on one side of the alumina substrate and the other, opposite side of the alumina substrate.

Solid oxide fuel cells that include an alumina substrate as support are described. The alumina substrate supported SOFCs can exhibit desirable electrochemical characteristics including high performance at intermediate temperatures and excellent thermal stability. The alumina substrate support is formed according to a modified phase-inversion process that forms a series of aligned micro-channels extending from a first side to a second opposite side of the support enabling gas distribution between an electrode (e.g., an anode) located on one side of the alumina substrate and the other, opposite side of the alumina substrate.

A solid oxide fuel cell includes a support of which a main component is a metal, a mixed layer that is provided on the support and includes a metallic material and a ceramics material, an intermediate layer that is provided on the mixed layer and includes an electron conductive ceramics material, and an anode that is provided on the intermediate layer and includes an oxygen ion conductive ceramics material and Ni. A ratio of a metal component in the intermediate layer is smaller than a ratio of the metallic material in the mixed layer.

Provided is a hydroxide ion-conductive separator including a porous substrate and a layered double hydroxide (LDH)-like compound filling pores of the porous substrate, wherein the LDH-like compound is a hydroxide and/or an oxide with a layered crystal structure, containing: Mg; and one or more elements, which include at least Ti, selected from the group consisting of Ti, Y, and Al.

Provided is a hydroxide ion-conductive separator including a porous substrate and a layered double hydroxide (LDH)-like compound filling pores of the porous substrate, wherein the LDH-like compound is a hydroxide and/or an oxide with a layered crystal structure, containing: Mg; and one or more elements, which include at least Ti, selected from the group consisting of Ti, Y, and Al.

Disclosed is a gas diffusion layer for a fuel cell that may be made thinner by integrally forming a base and a fine pore layer, and a method for manufacturing the same. A gas diffusion layer for a fuel cell which constitutes a unit cell of the fuel cell includes: a base layer formed by impregnating a first slurry, in which carbon powder and polytetrafluoroethylene (PTFE) are mixed, in the interior of a carbon fiber base; and a fine pore layer formed by coating a second slurry, in which carbon powder and polytetrafluoroethylene (PTFE) are mixed and which has a viscosity that is higher than the viscosity of the first slurry, on a surface of the base layer.

An electrochemical reaction unit cell including an electrolyte layer containing a solid oxide; a cathode and an anode which face each other in a first direction with the electrolyte layer intervening therebetween; and an intermediate layer disposed between the electrolyte layer and the cathode and containing a first cerium oxide. In the electrochemical reaction unit cell, the cathode includes an active layer containing a strontium-containing perovskite oxide, a second cerium oxide, sulfur, and strontium sulfate and having ion conductivity and electron conductivity, and a grain of the strontium sulfate covers at least a portion of the surface of a grain of the second cerium oxide.

An electrochemical reaction unit cell including an electrolyte layer containing a solid oxide; a cathode and an anode which face each other in a first direction with the electrolyte layer intervening therebetween; and an intermediate layer disposed between the electrolyte layer and the cathode and containing a first cerium oxide. In the electrochemical reaction unit cell, the cathode includes an active layer containing a strontium-containing perovskite oxide, a second cerium oxide, sulfur, and strontium sulfate and having ion conductivity and electron conductivity, and a grain of the strontium sulfate covers at least a portion of the surface of a grain of the second cerium oxide.