Provided is a method of manufacturing a separator for a fuel cell comprising: accumulating fibers obtained by electrospinning a spinning solution in which a polymer and a solvent are mixed to obtain a first support having first pores in a three-dimensional network structure; electrospraying a spraying solution in which a first ion exchange resin and a solvent are mixed to spray droplets of the first ion exchange resin on the first support body; accumulating fibers obtained by electrospinning a spinning solution in which a polymer and a solvent are mixed on the first support to form a second support having second pores in a three-dimensional network structure; and electrospraying a spraying solution in which a second ion exchange resin and a solvent are mixed to spray droplets of the second ion exchange resin on the second support body and fill the second ion exchange resin in the second pores.

Provided is a method of manufacturing a separator for a fuel cell comprising: accumulating fibers obtained by electrospinning a spinning solution in which a polymer and a solvent are mixed to obtain a first support having first pores in a three-dimensional network structure; electrospraying a spraying solution in which a first ion exchange resin and a solvent are mixed to spray droplets of the first ion exchange resin on the first support body; accumulating fibers obtained by electrospinning a spinning solution in which a polymer and a solvent are mixed on the first support to form a second support having second pores in a three-dimensional network structure; and electrospraying a spraying solution in which a second ion exchange resin and a solvent are mixed to spray droplets of the second ion exchange resin on the second support body and fill the second ion exchange resin in the second pores.

A fuel cell includes a pair of separators for clamping a laminate including a membrane electrode assembly, an anode gas diffusion layer, and a cathode gas diffusion layer, and a frame formed from thermosetting resin and disposed between the separators to surround a periphery of the laminate. At least one of the anode and the cathode gas diffusion layers is formed from a composite of thermoplastic resin and conductive particles, and includes a protrusion protruding beyond a level of a surface of the frame which faces one of the separators in a state that the laminate is not clamped between the separators under a predetermined pressure. The one of the separators presses the protrusion and gets the one of the gas diffusion layers to be deformed and put into contact with the frame in a state that the laminate is clamped between the separators under the predetermined pressure.

A fuel cell includes a pair of separators for clamping a laminate including a membrane electrode assembly, an anode gas diffusion layer, and a cathode gas diffusion layer, and a frame formed from thermosetting resin and disposed between the separators to surround a periphery of the laminate. At least one of the anode and the cathode gas diffusion layers is formed from a composite of thermoplastic resin and conductive particles, and includes a protrusion protruding beyond a level of a surface of the frame which faces one of the separators in a state that the laminate is not clamped between the separators under a predetermined pressure. The one of the separators presses the protrusion and gets the one of the gas diffusion layers to be deformed and put into contact with the frame in a state that the laminate is clamped between the separators under the predetermined pressure.

The present invention relates to a self-humidifying ion-exchange composite membrane including an aromatic hydrocarbon polymer ion-exchange membrane formed on the surface of a porous polymer support and a thin hydrophobic coating layer having a nanocracked morphology pattern on the surface of the ion-exchange membrane. The self-humidifying ion-exchange composite membrane of the present invention has good thermal/chemical stability, high mechanical strength, high ion-exchange capacity, and good long-term operational stability. Particularly, the self-humidifying ion-exchange composite membrane of the present invention is able to self-hydrate even under high-temperature and low-humidity conditions. Due to these advantages, it is expected that the self-humidifying ion-exchange composite membrane of the present invention will be commercialized as an electrolyte membrane for a fuel cell or a membrane for water treatment.

The present invention relates to a self-humidifying ion-exchange composite membrane including an aromatic hydrocarbon polymer ion-exchange membrane formed on the surface of a porous polymer support and a thin hydrophobic coating layer having a nanocracked morphology pattern on the surface of the ion-exchange membrane. The self-humidifying ion-exchange composite membrane of the present invention has good thermal/chemical stability, high mechanical strength, high ion-exchange capacity, and good long-term operational stability. Particularly, the self-humidifying ion-exchange composite membrane of the present invention is able to self-hydrate even under high-temperature and low-humidity conditions. Due to these advantages, it is expected that the self-humidifying ion-exchange composite membrane of the present invention will be commercialized as an electrolyte membrane for a fuel cell or a membrane for water treatment.

Embodiments are directed to composite membranes having a microporous polymer structure, and an ion exchange material forming a continuous ionomer phase within the composite membrane. The continuous ionomer phase refers to absence of any internal interfaces in a layer of ionomer or between any number of layers coatings of the ion exchange material provided on top of one another. The composite membrane exhibits a haze change of 0% or less after being subjected to a blister test procedure. No bubbles or blisters are formed on the composite membrane after the blister test procedure. A haze value of the composite membrane is between 5% and 95%, between 10% and 90% or between 20% and 85%. The composite membrane may have a thickness of more than 17 microns at 0% relative humidity.

Embodiments are directed to composite membranes having a microporous polymer structure, and an ion exchange material forming a continuous ionomer phase within the composite membrane. The continuous ionomer phase refers to absence of any internal interfaces in a layer of ionomer or between any number of layers coatings of the ion exchange material provided on top of one another. The composite membrane exhibits a haze change of 0% or less after being subjected to a blister test procedure. No bubbles or blisters are formed on the composite membrane after the blister test procedure. A haze value of the composite membrane is between 5% and 95%, between 10% and 90% or between 20% and 85%. The composite membrane may have a thickness of more than 17 microns at 0% relative humidity.

An electrochemical element is provided. The electrochemical element may comprise an anode, a cathode on the anode, and an anion exchange membrane disposed between the cathode and the anode and including cellulose and chitosan.

An electrochemical element is provided. The electrochemical element may comprise an anode, a cathode on the anode, and an anion exchange membrane disposed between the cathode and the anode and including cellulose and chitosan.