The invention relates to metal supported solid oxide fuel cells (SOFC), fuel cell stacks containing the same, methods of their manufacture and use thereof. The SOFC of the invention utilises an extended electrolyte and barrier layers to prevent specific types of corrosion of the metal substrate. This new coating approach reduces the rate of degradation of the fuel cells and improves system reliability when operated over long durations.

The invention relates to metal supported solid oxide fuel cells (SOFC), fuel cell stacks containing the same, methods of their manufacture and use thereof. The SOFC of the invention utilises an extended electrolyte and barrier layers to prevent specific types of corrosion of the metal substrate. This new coating approach reduces the rate of degradation of the fuel cells and improves system reliability when operated over long durations.

The present invention relates to composite sealing materials for a gasket. The gaskets are useful in solid oxide fuel/electrolyser cells (SOFC and SOEC). The fuel cell gaskets contain sealing material based upon chemically exfoliated vermiculite that has improved corrosion resistance. The sealing material comprises chemically exfoliated vermiculite; filler; and insoluble carbonate.

The present invention relates to composite sealing materials for a gasket. The gaskets are useful in solid oxide fuel/electrolyser cells (SOFC and SOEC). The fuel cell gaskets contain sealing material based upon chemically exfoliated vermiculite that has improved corrosion resistance. The sealing material comprises chemically exfoliated vermiculite; filler; and insoluble carbonate.

A single fuel cell according to the present disclosure includes a power generation section, a power non-generation section which does not include the power generation section, and an oxygen-ion-insulating gas seal film arranged so as to cover the surface of the power non-generation section, and the gas seal film is configured by a structure formed by firing a material containing MTiO.sub.3 (M: alkaline earth metal element) and metal oxide. The structure may include a first structure and a second structure which are different in composition, the first structure may include components derived from MTiO.sub.3 in larger amounts than the second structure, the second structure may include a metal element contained in the metal oxide in a larger amount than the first structure, and the area ratio of the second structure in the structure may be not less than 1% and not more than 50%.

A single fuel cell according to the present disclosure includes a power generation section, a power non-generation section which does not include the power generation section, and an oxygen-ion-insulating gas seal film arranged so as to cover the surface of the power non-generation section, and the gas seal film is configured by a structure formed by firing a material containing MTiO.sub.3 (M: alkaline earth metal element) and metal oxide. The structure may include a first structure and a second structure which are different in composition, the first structure may include components derived from MTiO.sub.3 in larger amounts than the second structure, the second structure may include a metal element contained in the metal oxide in a larger amount than the first structure, and the area ratio of the second structure in the structure may be not less than 1% and not more than 50%.

An assembly includes an SOEC/SOFC-type solid oxide stack, a clamping system for clamping the stack, including at least two clamping rods that can be used to assemble upper and lower clamping plates, and a coupling system for high-temperature fluid-tight coupling of the stack to a heating system for supplying and discharging gas. The coupling system includes a collector with collection ducts for supplying and discharging gas, each provided with a collecting port positioned facing a corresponding communication port of at least one of the upper and lower clamping plates, and seals each placed between a collecting port and a corresponding communication port.

An assembly includes an SOEC/SOFC-type solid oxide stack, a clamping system for clamping the stack, including at least two clamping rods that can be used to assemble upper and lower clamping plates, and a coupling system for high-temperature fluid-tight coupling of the stack to a heating system for supplying and discharging gas. The coupling system includes a collector with collection ducts for supplying and discharging gas, each provided with a collecting port positioned facing a corresponding communication port of at least one of the upper and lower clamping plates, and seals each placed between a collecting port and a corresponding communication port.

A caulk composition includes: at least one powder component and at least one binder component. The powder component is a ball-milled powder component comprising ceria, zirconia, alumina, or a combination thereof. The powder component is a heat-treated powder component that has been heated to a temperature of at least 1500 C. The powder component is present in a concentration range of 65 wt % to 75 wt % of the caulk composition. The powder component has a particle size distribution of 95% less than 25 m and 90% greater than 1 m. The binder component is present in a concentration range of 25 wt % to 35 wt % of the caulk composition.

A caulk composition includes: at least one powder component and at least one binder component. The powder component is a ball-milled powder component comprising ceria, zirconia, alumina, or a combination thereof. The powder component is a heat-treated powder component that has been heated to a temperature of at least 1500 C. The powder component is present in a concentration range of 65 wt % to 75 wt % of the caulk composition. The powder component has a particle size distribution of 95% less than 25 m and 90% greater than 1 m. The binder component is present in a concentration range of 25 wt % to 35 wt % of the caulk composition.