A cell stack device may include a cell stack of connected cells, a manifold configured to fix lower ends of the cells and supply a reaction gas into gas flow passages of the cells, and a reaction gas supply pipe connected to the manifold and configured to supply the reaction gas to the manifold. The manifold may include an insertion portion connecting the reaction gas supply pipe to the manifold, and a gap between the insertion portion and the reaction gas supply pipe. The manifold may further include a first joining portion joining the insertion portion and the reaction gas supply pipe and configured to seal an end of the gap. In a cross-section along an insertion direction of the reaction gas supply pipe, the first joining portion may have a meniscus shape, and a joint length is longer than a thickness of the reaction gas supply pipe.

A single fuel cell according to the present disclosure includes a power generation section, a power non-generation section which does not include the power generation section, and an oxygen-ion-insulating gas seal film arranged so as to cover the surface of the power non-generation section, and the gas seal film is configured by a structure formed by firing a material containing MTiO.sub.3 (M: alkaline earth metal element) and metal oxide. The structure may include a first structure and a second structure which are different in composition, the first structure may include components derived from MTiO.sub.3 in larger amounts than the second structure, the second structure may include a metal element contained in the metal oxide in a larger amount than the first structure, and the area ratio of the second structure in the structure may be not less than 1% and not more than 50%.

A single fuel cell according to the present disclosure includes a power generation section, a power non-generation section which does not include the power generation section, and an oxygen-ion-insulating gas seal film arranged so as to cover the surface of the power non-generation section, and the gas seal film is configured by a structure formed by firing a material containing MTiO.sub.3 (M: alkaline earth metal element) and metal oxide. The structure may include a first structure and a second structure which are different in composition, the first structure may include components derived from MTiO.sub.3 in larger amounts than the second structure, the second structure may include a metal element contained in the metal oxide in a larger amount than the first structure, and the area ratio of the second structure in the structure may be not less than 1% and not more than 50%.

The present invention relates to a glass composition capable of being used as a sealant, and a solid oxide fuel cell using same. The sealant glass composition according to the present invention comprises 10-45 wt % of SiO.sub.2, 0.1-20 wt % of B.sub.2O.sub.3, 40-65 wt % of BaO, 0.1-20 wt % of CaO, and 0.1-15 wt % of at least one of Al.sub.2O.sub.3 and ZrO.sub.2, and unlike existing sealant glass compositions, can be suitably used in solid oxide fuel cells operating at intermediate temperatures, and exhibits an advantageous effect in keeping a decrease in sealing adhesion strength to a minimum, even after prolonged use.

The present invention relates to a glass composition capable of being used as a sealant, and a solid oxide fuel cell using same. The sealant glass composition according to the present invention comprises 10-45 wt % of SiO.sub.2, 0.1-20 wt % of B.sub.2O.sub.3, 40-65 wt % of BaO, 0.1-20 wt % of CaO, and 0.1-15 wt % of at least one of Al.sub.2O.sub.3 and ZrO.sub.2, and unlike existing sealant glass compositions, can be suitably used in solid oxide fuel cells operating at intermediate temperatures, and exhibits an advantageous effect in keeping a decrease in sealing adhesion strength to a minimum, even after prolonged use.

A gasket sealing material for a fuel cell comprising: at least 25% dry w/w chemically exfoliated vermiculite; and at least 15% dry w/w plate-like filler; wherein the plate-like filler has an average particle size of less than or equal to 10 μm. Gaskets, fuel cells, uses of the gasket and sealing material are also defined.

A gasket sealing material for a fuel cell comprising: at least 25% dry w/w chemically exfoliated vermiculite; and at least 15% dry w/w plate-like filler; wherein the plate-like filler has an average particle size of less than or equal to 10 μm. Gaskets, fuel cells, uses of the gasket and sealing material are also defined.

The present disclosure relates to a sealing arrangement, comprising: an elastomeric sealing element, which comprises a foamed material containing microspheres, and a metal layer having a surface structuring, the surface structuring comprising a plurality of depressions, wherein the sealing element is configured as a coating of the metal layer and is arranged at least in some areas on the surface structuring, wherein a concentration of the microspheres in the sealing element, measured perpendicular to the surface of the metal layer, is inhomogeneous. The disclosure additionally relates to a plate assembly, to an electrochemical system, and to a method for producing the sealing arrangement.

The present disclosure relates to a sealing arrangement, comprising: an elastomeric sealing element, which comprises a foamed material containing microspheres, and a metal layer having a surface structuring, the surface structuring comprising a plurality of depressions, wherein the sealing element is configured as a coating of the metal layer and is arranged at least in some areas on the surface structuring, wherein a concentration of the microspheres in the sealing element, measured perpendicular to the surface of the metal layer, is inhomogeneous. The disclosure additionally relates to a plate assembly, to an electrochemical system, and to a method for producing the sealing arrangement.

A fuel cell stack is provided that includes a top end plate, a bottom end plate, a plurality of fuel cells provided between the top end plate and the bottom end plate, at least one bipolar plate, a plurality of hollow fasteners, and a plurality of sleeves. Each of the at least one bipolar plate is formed between two of the plurality of fuel cells. The plurality of hollow fasteners and the plurality of sleeves extend through holes in each of the top end plate, the bottom end plate, the plurality of fuel cells and the at least one bipolar plate. Each of the plurality of sleeves surrounds one of the plurality of hollow fasteners. Each of the plurality of hollow fasteners comprises a top surface, a hole in the top surface, a side surface, and a plurality of holes formed in the side surface.