Disclosed herein are aspects of fuel cell systems (10) and methods having a fuel cell assembly (20); a coolant module (30) configured to provide coolant to the fuel cell assembly, the coolant module comprising a coolant storage (32) tank fluidly connected to the fuel cell assembly (20) and a coolant tank heater comprising one or more catalytic heating elements (55) arranged proximate to the coolant storage tank (32) to heat the coolant, wherein the one or more catalytic heating elements (55) includes a catalyst material that combusts hydrogen and ignites spontaneously.

This invention pertains to methods for controlling thermal aspects during operation of a solid oxide fuel cell (SOFC) system, including controlling target cathode and anode inlet stream temperatures and differential temperatures defined by the anode and cathode inlet and outlet streams. In one aspect, thermal management is achieved by controlling a combustion stream temperature and by employing one heat exchanger having two cold side pathways. In another aspect, thermal management is achieved by controlling a temperature of a combustion stream distributed through a cathode feed heat exchanger and an anode feed heat exchanger, optionally with bypassing a portion of the cathode air stream around the cathode feed heat exchanger. In another aspect, thermal management is achieved by employing a cathode feed heat exchanger to heat a cathode air stream and by employing an equalizer heat exchanger to equilibrate temperatures of the resulting heated cathode air stream and an anode fuel stream.

An integrated fuel cell system includes fuel cells, fuel heat exchangers, air heat exchangers, and tail gas oxidizers. The tail gas oxidizers oxidize a (second) portion of fuel received from the fuel cells with effluent that is output from the fuel cells. Fuel cell stacks are fluidly coupled with the fuel heat exchangers and the tail gas oxidizers such that the fuel that is output from the fuel cells is split into a first portion that is directed back into the fuel heat exchangers and a second portion that is directed into the tail gas oxidizers.

An assembly comprising a SOEC/SOFC-type solid oxide stack, and a clamping system for the stack. The assembly further comprises a system for superheating the gases at the inlet of the stack, comprising: a heating plate integrated within the thickness of at least one of the upper and lower clamping plates of the clamping system; an upper or lower end plate for superheating the gases, comprising a circuit through which the gases to be heated flow; and an inlet duct for the gases to be heated.

The present disclosure provides methods for turbine-based energy recovery from exhaust streams in fuel cell systems. The fuel cell systems can include an expansion turbine (200) arranged to capture electrical energy from cathode exhaust streams. The cathode exhaust streams (151a, 151b, 151c) can be flowed through an intercooler (250) to be preheated prior to entering the expansion turbine (200), with heat added by transferring heat from a compressed air flow. The methods can include operating the fuel cell system in a temperature-boost mode that includes reducing fan operation related to a condenser to reduce liquid recapture from an exhaust stream and increase exhaust stream temperature for use in turbine-based energy recovery. The temperature-boost mode can be controlled to limit the operation time based on coolant fluid levels in the fuel cell system.

A system for supplying hydrogen using waste heat of a fuel cell includes: a fuel cell to produce electric power using hydrogen; an internal cooling line in which a cooling medium flows and configured to pass through the fuel cell while cooling the fuel cell with the cooling medium; a solid hydrogen storage provided on a downstream side of the fuel cell on the internal cooling line and configured to discharge the hydrogen through absorption of waste heat of the heated cooling medium and to supply the discharged hydrogen to the fuel cell; and a hydrogen supply line to connect the solid hydrogen storage and the fuel cell and to supply the discharged hydrogen. In particular, the internal cooling line is reconnected to the fuel cell after passing through the solid hydrogen storage and provides the cooled cooling medium to the fuel cell.

An apparatus includes an integrated heat exchanger and reactor module. The integrated heat exchanger and reactor module includes a heat exchanger channel, and a reactor channel which is thermally coupled to the heat exchanger channel. The reactor channel includes a layer of catalyst material that is configured to produce hydrogen by endothermic catalytic decomposition of ammonia, which flows through the reactor channel, using thermal energy that is absorbed by the reactor channel from the heat exchanger channel.

The present invention relates to a fuel cell system (1a; 1b; 1c; 1d) comprising: at least one fuel cell stack (2) with an anode portion (3) and a cathode portion (4); a reformer-heat exchanger (5) with a cold side which is upstream of the anode portion (3) and forms a reformer (6) and a hot side which is downstream of the cathode portion (4) and forms a heat exchanger (7); and an afterburner (8) downstream of the heat exchanger (7) for combusting anode exhaust gas from the anode portion (3) and/or cathode exhaust gas from the cathode portion (4), the heat exchanger (7) being situated directly downstream of the cathode portion (4) and being in fluid communication with the cathode portion (4) by means of a cathode exhaust gas line (9) in order for the cathode exhaust gas to be fully conducted through the heat exchanger (7). The invention also relates to a method for controlling the temperature of a fuel cell system (1a; 1b; 1ce; 1d) according to the invention.

Provided is a method of controlling a fuel cell system having a fuel cell stack, a reformer configured to reform a raw fuel and supply the reformed raw fuel to the fuel cell stack, a fuel flow rate control unit configured to control a flow rate of the raw fuel supplied to the reformer, an air supply pipe configured to supply oxygen to the raw fuel, and a combustor configured to mix a cathode discharged gas and an anode discharged gas discharged from the fuel cell stack and combust the mixed gas. The method of controlling the fuel cell system includes detecting at least one of a current value generated from the fuel cell stack and an oxygen supply amount supplied from the air supply pipe; estimating a composition of the anode discharged gas on the basis of at least one of the current value and the oxygen supply amount; and controlling a temperature of the combustor by adjusting the flow rate of the raw fuel using the fuel flow rate control unit on the basis of the estimated composition of the anode discharged gas.

A fuel cell system includes: a fuel cell that includes a cathode and an anode and generates electricity by reducing a mediator at the cathode; a regenerator that oxidizes, with an oxidant, the mediator reduced by the cathode; an oxidant feed path that is connected to the regenerator, wherein through the oxidant feed path, the oxidant to be supplied to the regenerator flows; a reformer; a combustor that heats the reformer; and a first heat exchanger that exchanges heat between combustion exhaust discharged from the combustor and the oxidant to be supplied to the regenerator.