Provided is a fuel cell system capable of further increasing electric power generation efficiency, compared to the current circumstances, with respect to a fuel cell SOFC that generates electric power by supplying a reformed gas obtained by steam reforming to a fuel electrode. A steam reformer that reforms a hydrocarbon fuel by a steam reforming reaction; a fuel cell that operates by introducing a reformed gas to a fuel electrode; and an anode off-gas circulation path that removes condensed water while cooling an anode off-gas, and introduces the anode off-gas to the steam reformer are provided. A condensation temperature in a condensing device is controlled by a control unit that controls a steam partial pressure of the anode off-gas circulated to the steam reformer, and S/C adjustment is adapted to high-efficiency electric power generation.

A fuel cell system herein may include a battery configured to supply electric power to a fuel cell auxiliary device used for activating a fuel cell stack. When remaining electric energy in the battery is higher than an electric energy threshold upon activation of the fuel cell stack, a controller of the fuel cell system may start outputting current from the fuel cell stack after a fuel concentration in the fuel cell stack reaches a predetermined fuel concentration threshold, and when the remaining electric energy decreases below the electric energy threshold while the fuel concentration is being increased, the controller may start outputting current from the fuel cell stack regardless of the fuel concentration in the fuel cell stack. The current can be obtained from the fuel cell stack even when the remaining electric energy in the battery is low.

A fuel cell system herein may include a battery configured to supply electric power to a fuel cell auxiliary device used for activating a fuel cell stack. When remaining electric energy in the battery is higher than an electric energy threshold upon activation of the fuel cell stack, a controller of the fuel cell system may start outputting current from the fuel cell stack after a fuel concentration in the fuel cell stack reaches a predetermined fuel concentration threshold, and when the remaining electric energy decreases below the electric energy threshold while the fuel concentration is being increased, the controller may start outputting current from the fuel cell stack regardless of the fuel concentration in the fuel cell stack. The current can be obtained from the fuel cell stack even when the remaining electric energy in the battery is low.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

Disclosed are a fuel cell system capable of maintaining hydrogen density of the exhaust gas discharged from the fuel cell system at a level below the tolerance limit so that any fears about fire and/or explosion can be dispelled and the safety of the system can be remarkably improved, and a humidifier therefor. The fuel cell system of the present invention comprises a fuel cell stack; and a humidifier configured to (i) humidify an air supplied from outside by means of an off-gas discharged from the fuel cell stack and (ii) supply the humidified air to the fuel cell stack, wherein the off-gas is mixed with at least a portion of the humidified air in the humidifier.

A fuel supply control system and method for a fuel cell are disclosed. The system includes: a fuel cell configured to receive a fuel gas and an oxidation gas and generate electric power; a recirculation line configured to circulate gas containing the fuel gas and connected to a fuel electrode of the fuel cell; a discharge valve provided in the recirculation line and configured to allow the gas to be discharged to the outside when open; a discharge amount estimator configured to estimate a discharge amount of the discharged gas based on a supply amount of the fuel gas supplied to the recirculation line, a consumption amount of the fuel gas consumed in the fuel cell, and a change in the amount of the gas in the recirculation line; an offset calculator configured to calculate the discharge amount of the gas estimated by the discharge amount estimator with the discharge valve closed, as a discharge offset; and a controller configured to control opening/closing of the discharge valve.

A system for estimating the amount of purge of a fuel cell is provided. The system includes a fuel cell that generates power by receiving hydrogen at an anode side and receives oxygen at a cathode side. A recirculation line is connected with the anode side of the fuel cell, and the gas included hydrogen therein is circulated in the recirculation line. A flow amount estimator estimates the flow amount of gas inside the recirculation line. A purge valve is positioned in the recirculation line and discharges the gas in the recirculation line to the outside when opened. A purge amount estimator estimates the amount of purge for each gas discharged through the purge valve by reflecting the flow amount of the gas estimated by the flow amount estimator.

An electrolyte manufacturing device includes an electrolytic cell including a diaphragm separating an anode chamber from a cathode chamber, a circulator circulating an anolyte to the anode chamber and circulating a catholyte to the cathode chamber, and a power source supplying current. A cathode in the electrolytic cell includes a carbon fiber layer on a plane facing the diaphragm. The electrolytic cell includes an anode net placed between the anode and the diaphragm, and a cathode net placed between the cathode and the diaphragm. The circulator circulates the anolyte at a flow rate that is greater than the flow rate of the catholyte and is equal to or greater than twice the volume of gaseous oxygen generated in the anode chamber per unit time at 0° C.

An electrolyte manufacturing device includes an electrolytic cell including a diaphragm separating an anode chamber from a cathode chamber, a circulator circulating an anolyte to the anode chamber and circulating a catholyte to the cathode chamber, and a power source supplying current. A cathode in the electrolytic cell includes a carbon fiber layer on a plane facing the diaphragm. The electrolytic cell includes an anode net placed between the anode and the diaphragm, and a cathode net placed between the cathode and the diaphragm. The circulator circulates the anolyte at a flow rate that is greater than the flow rate of the catholyte and is equal to or greater than twice the volume of gaseous oxygen generated in the anode chamber per unit time at 0° C.

A fuel cell system includes a fuel cell in which cells are stacked, a voltage sensor that detects a voltage in unit of one or more of the cells, a control unit that determines an operating point of the fuel cell and causes the fuel cell to operate. The control unit causes the fuel cell to operate at a low efficiency operating point having a lower efficiency than an efficiency of a reference operating point in a warm-up operation. In the warm-up operation, the control unit calculates a total number of the cells in which the voltage detected by the voltage sensor is equal to or less than a predetermined first reference voltage and calculates an exhaust hydrogen concentration based on the total number or the cells.