A fuel cell system includes a fuel cell, a fuel gas supply line, an oxidizing agent gas supply line, a fuel gas discharge line, and a reformer provided in the fuel gas supply line. A first circulating line circulates the fuel gas from the fuel gas discharge line to an upstream side of the reformer in the fuel gas supply line as a first circulating gas. The circulation device is provided in the fuel gas supply line, and suctions the first circulating gas by using the flow of the fuel gas flowing through the fuel gas supply line as a driving flow. A second circulating line circulates the fuel gas from a downstream side of the circulation device in the fuel gas supply line or the fuel gas discharge line to the upstream side of the circulation device in the fuel gas supply line as a second circulating gas.

A reactor containing a heat exchanger is disclosed, which can be operated with co-current or counter-current flow. Also disclosed is a system that includes a reactor having a reformer and a vaporizer, a fuel supply, and a water supply. The reactor includes a source of combustion gas, a reformer operative to receive reformate, and a vaporizer operative to receive water. The reformer and vaporizer each include a stack assembly formed by a combination of separator shims and channel shims. The separator shims and channel shims are stacked in a regular pattern to form two sets of channels within the stack assembly. One set of channels will have vertical passageways at either end and a horizontal flowpath between them, while the other set of channels has only a horizontal flowpath.

The disclosure relates to a fuel cell apparatus in which a stable installation state may be maintained even when a size thereof is reduced. A fuel cell apparatus according to the present disclosure may include a fuel cell module including fuel cells housed in a housing; a plurality of auxiliary machines which operate the fuel cell module; and an exterior case, shaped in a rectangular prism, which houses the fuel cell module and the auxiliary machines. A gravity center of the fuel cell apparatus may be located below a level equal to half a height of the exterior case.

A fuel cell module includes fuel cells, a gas supply system, a first accumulator, a second accumulator, and power connection. The fuel cells are arranged in a cell stack having a first axial end and a second axial end. The gas supply system is configured to supply gas for the operation of the fuel cells, the fuel cells being stacked in an axial direction. The first accumulator is arranged at the first axial end of the cell stack. The second accumulator is arranged at the second axial end of the cell stack. The power connection is electrically conductively connected to the second accumulator, and is arranged at the gas supply system. The cell stack is arranged within an insulation sheath and the gas supply system is arranged partly outside the insulation sheath and the power connection is arranged outside the insulation sheath.

Various designs and configurations of and methods of operating fuel cell units, fuel cell systems and combined heat and power systems are provided that permit efficient thermal management of such units and systems to improve their operation.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

A hydrogen generation electricity system for producing electricity from hydrogen using a hydrogen carrier substance, comprising: a reaction chamber arranged for generating a H2 gas stream by converting the hydrogen carrier substance; wherein the reaction chamber comprises an inlet arranged for receiving the hydrogen carrier substance; an output conduit for exiting the H2 gas stream; a fuel cell arranged for producing electric energy by converting hydrogen; the output conduit is arranged for supplying the H2 gas stream from the reaction chamber to the fuel cell; the system further comprising: a humidity determining unit arranged for determining a humidity level of the H2 gas stream; a water providing means for providing H2O to the reaction chamber; and a water vapour control means arranged for controlling the water vapour level in the reaction chamber, in response to the determined humidity level, wherein the generated H2 gas stream comprises hydrogen and water vapour.

A fuel cell stack assembly and method of operating the same are provided. The assembly includes a fuel cell stack column and side baffles disposed on opposing sides of the column. The side baffles and the fuel cell stack may have substantially the same coefficient of thermal expansion at room temperature. The side baffles may have a laminate structure in which one or more channels are formed.

A low-temperature dehydrogenation method includes a dehydrogenation reaction of a reactant including a piperidine-based compound substituted with one or more alkyl groups. The dehydrogenation reaction takes place in the presence of a catalyst including an active metal. The active metal includes platinum (Pt), palladium (Pd), or a mixture thereof that is supported on a carrier including a composite metal oxide having alumina (Al.sub.2O.sub.3) and an additional metal oxide different from alumina, at a low temperature of 150° C. to 250° C., to produce hydrogen.

Provided are an electrochemical element and the like that have both durability and high performance as well as excellent reliability. The electrochemical element includes a metal support, and an electrode layer formed on/over the metal support. The metal support is made of any one of a Fe—Cr based alloy that contains Ti in an amount of 0.15 mass % or more and 1.0 mass % or less, a Fe—Cr based alloy that contains Zr in an amount of 0.15 mass % or more and 1.0 mass % or less, and a Fe—Cr based alloy that contains Ti and Zr, a total content of Ti and Zr being 0.15 mass % or more and 1.0 mass % or less.