A high-temperature fuel cell system includes a reformer that reforms a hydrocarbon-based raw fuel to generate a reformed gas containing hydrogen, a fuel cell that generates power by using the reformed gas and an oxidant gas, and a burner that heats the reformer. The burner includes an anode-off-gas gathering portion that has an anode-off-gas ejection hole and at which an anode off-gas discharged from an anode of the fuel cell gathers. The anode-off-gas gathering portion surrounds a first cathode-off-gas passing area through which a cathode off-gas discharged from a cathode of the fuel cell passes. The anode-off-gas ejection hole is formed such that the anode off-gas ejected upward from the anode-off-gas ejection hole approaches the cathode off-gas passing upward through the first cathode-off-gas passing area. The anode off-gas ejected from the anode-off-gas ejection hole and the cathode off-gas that has passed through the first cathode-off-gas passing area are burned.

A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

Disclosed is a fuel supplying apparatus, for a direct carbon fuel cell, which has improved output density by ensuring the flow properties of an anode medium. The fuel supplying apparatus for a direct carbon fuel cell comprises: a flow pipe which forms a flow path around a tube-shaped cell contained in an anode medium in which a carbon fuel is mixed; and a bubbling means which provides a gas from below the flow pipe to the inside of the anode medium and thus enables the anode medium to flow by the upward movement of the gas. Consequently, the carbon fuel is forcibly provided to the anode of the tube-shaped cell by the flow of the anode medium which is linked with the upward movement of the gas.

Disclosed is a fuel supplying apparatus, for a direct carbon fuel cell, which has improved output density by ensuring the flow properties of an anode medium. The fuel supplying apparatus for a direct carbon fuel cell comprises: a flow pipe which forms a flow path around a tube-shaped cell contained in an anode medium in which a carbon fuel is mixed; and a bubbling means which provides a gas from below the flow pipe to the inside of the anode medium and thus enables the anode medium to flow by the upward movement of the gas. Consequently, the carbon fuel is forcibly provided to the anode of the tube-shaped cell by the flow of the anode medium which is linked with the upward movement of the gas.

Systems and methods are provided integrating an annular pre-reformer as part of an anode recuperator of a fuel cell system.

Systems and methods are provided integrating an annular pre-reformer as part of an anode recuperator of a fuel cell system.

The present disclosure relates to nickel/aluminum-containing catalyst materials useful, for example, as reforming catalysts, processes for making them, and processes for using them in molten carbonate fuel cells. In one aspect, the disclosure provides a catalyst material including an alumina carrier in an amount in the range of about 5 wt % to about 75 wt %; and a mixed metal oxide in an amount in the range of about 25 wt % to about 95 wt %, the mixed metal oxide including at least about 90 wt % of oxides of nickel and aluminum, the mixed metal oxide having an atomic ratio of nickel to aluminum in the range of about 60:40 to about 90:10, the mixed metal oxide being substantially free of zirconium, in the form of a composite of the alumina carrier and the mixed metal oxide.

A fuel cell system is disclosed, which includes an anode recirculation loop having a fuel cell stack for generating power, a flowmeter, a current sensor and a processor. The flowmeter is configured for measuring a fuel flow rate provided into the anode recirculation loop. The current sensor is configured for measuring a current drawn from the fuel cell stack. The processor is configured for determining a steam to carbon ratio in the anode recirculation loop based on the measured fuel flow rate and the measured current. The fuel cell system further includes a temperature sensor for measuring a temperature in the anode recirculation loop. The process is configured for determining the steam to carbon ration further based on the measured temperature. A method for operating the fuel cell system and a fuel cell power plant are also disclosed.

In various aspects, systems and methods are provided for operating a molten carbonate fuel cell at increased fuel utilization and/or increased CO.sub.2 utilization. This can be accomplished in part by performing an effective amount of an endothermic reaction within the fuel cell stack in an integrated manner. This can allow for a desired temperature differential to be maintained within the fuel cell.