Disclosed is an ion-exchange membrane that includes a molecular barrier for influencing permeation selectivity through the membrane. The membrane includes fluorinated carbon backbone chains and fluorinated side chains that extend off of the fluorinated carbon backbone chains. The fluorinated side chains include acid groups for ionic conductivity. The acid groups surround and define permeable domains that are free of the fluorinated carbon backbone chains. Molecular barriers are located in the permeable domains and influence permeability through the domains.

Disclosed is an ion-exchange membrane that includes a molecular barrier for influencing permeation selectivity through the membrane. The membrane includes fluorinated carbon backbone chains and fluorinated side chains that extend off of the fluorinated carbon backbone chains. The fluorinated side chains include acid groups for ionic conductivity. The acid groups surround and define permeable domains that are free of the fluorinated carbon backbone chains. Molecular barriers are located in the permeable domains and influence permeability through the domains.

A recirculation fuel cell device, which can be utilized on a submarine, may include a fuel cell with an anode side and a cathode side, wherein both the anode and cathode sides have input and output sides. The device may include a first inlet for oxygen and a second inlet for hydrogen. The device may further include a cathode-side connection between the output side of the cathode side and the input side of the cathode side, and an anode-side connection between the output side of the anode side and the input side of the anode side. A water separator may be disposed in the cathode-side connection, and a gas discharge valve for a continuous release of process gases may be disposed on the output side of the cathode side of the fuel cell. Operation of the device may involve recirculating an anode gas stream in its entirety.

A recirculation fuel cell device, which can be utilized on a submarine, may include a fuel cell with an anode side and a cathode side, wherein both the anode and cathode sides have input and output sides. The device may include a first inlet for oxygen and a second inlet for hydrogen. The device may further include a cathode-side connection between the output side of the cathode side and the input side of the cathode side, and an anode-side connection between the output side of the anode side and the input side of the anode side. A water separator may be disposed in the cathode-side connection, and a gas discharge valve for a continuous release of process gases may be disposed on the output side of the cathode side of the fuel cell. Operation of the device may involve recirculating an anode gas stream in its entirety.

An anion exchange resin having a hydrophobic unit with divalent hydrophobic groups bonded to each other via an ether bond, the divalent hydrophobic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group, carbon-carbon bond or the like; and a hydrophilic unit having divalent hydrophilic groups bonded to each other via carbon-carbon bond, the divalent hydrophilic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group or carbon-carbon bond, the aromatic ring or at least one of the aromatic rings having an anion exchange group are bonded via carbon-carbon bond.

The present application relates to an ion transport material, an electrolyte membrane including the same, and a method for manufacturing the same, and more specifically, provides an ion transport material in which inorganic particles are dispersed in a peripheral portion of a sulfonic acid group of a partially fluorinated polymer containing sulfonic acid, an electrolyte membrane including the same, and a method for manufacturing the same.

The present application relates to an ion transport material, an electrolyte membrane including the same, and a method for manufacturing the same, and more specifically, provides an ion transport material in which inorganic particles are dispersed in a peripheral portion of a sulfonic acid group of a partially fluorinated polymer containing sulfonic acid, an electrolyte membrane including the same, and a method for manufacturing the same.

In one aspect, a method of forming an electrode for an electrochemical device is disclosed. In one embodiment, the method includes the steps of mixing at least a first amount of a catalyst and a second amount of an ionomer or uncharged polymer to form a solution and delivering the solution into a metallic needle having a needle tip. The method further includes the steps of applying a voltage between the needle tip and a collector substrate positioned at a distance from the needle tip, and extruding the solution from the needle tip at a flow rate such as to generate electrospun fibers and deposit the generated fibers on the collector substrate to form a mat with a porous network of fibers. Each fiber in the porous network of the mat has distributed particles of the catalyst. The method also includes the step of pressing the mat onto a membrane.

In one aspect, a method of forming an electrode for an electrochemical device is disclosed. In one embodiment, the method includes the steps of mixing at least a first amount of a catalyst and a second amount of an ionomer or uncharged polymer to form a solution and delivering the solution into a metallic needle having a needle tip. The method further includes the steps of applying a voltage between the needle tip and a collector substrate positioned at a distance from the needle tip, and extruding the solution from the needle tip at a flow rate such as to generate electrospun fibers and deposit the generated fibers on the collector substrate to form a mat with a porous network of fibers. Each fiber in the porous network of the mat has distributed particles of the catalyst. The method also includes the step of pressing the mat onto a membrane.

A method of manufacturing an ion-conducting membrane. comprising the steps of: (a) providing a substrate; (b) depositing a first dispersion onto the substrate to form a first layer, wherein the first dispersion comprises an ion-conducting polymer; (c) depositing a second dispersion onto the first dispersion to form a second layer on the first layer, wherein the second dispersion comprises an ion-conducting polymer; (d) providing a reinforcing component comprising pores so that the second dispersion impregnates at least some of the pores of the reinforcing component; and (e) drying the first and second layers, wherein step (e) is performed after steps (c) and (d).