Patent classifications
H01M8/1058
Porous nano-fiber mats to reinforce proton conducting membranes for PEM applications
A method of manufacturing a proton conducting fuel cell composite membrane includes the step of electrospinning a non-charged polymeric material, such as PVDF and PSF, into fiber mats. The fibers are fused to one another to provide a welded porous mat. The welded porous mat is filled with proton conducting electrolyte, such as PFSA polymer, to generate a proton conducting composite membrane. The resulting proton conducting fuel cell membrane comprises a randomly oriented, three dimensional interlinked fiber lattice structure filled with proton conducting electrolyte, such as PFSA polymer.
Porous nano-fiber mats to reinforce proton conducting membranes for PEM applications
A method of manufacturing a proton conducting fuel cell composite membrane includes the step of electrospinning a non-charged polymeric material, such as PVDF and PSF, into fiber mats. The fibers are fused to one another to provide a welded porous mat. The welded porous mat is filled with proton conducting electrolyte, such as PFSA polymer, to generate a proton conducting composite membrane. The resulting proton conducting fuel cell membrane comprises a randomly oriented, three dimensional interlinked fiber lattice structure filled with proton conducting electrolyte, such as PFSA polymer.
FABRICATION METHOD OF A MEMBRANE ELECTRODE ASSEMBLY (MEA), MEA, CELL AND USES THEREOF
The present invention refers to fabrication method of a membrane electrode assembly (MEA), to MEA obtainable by said method, to a cell comprising said MEA, to the use of the MEA and the cell for the electrochemical detection of analytes, and to the use of the MEA and the cell for storing and/or delivering electricity.
FABRICATION METHOD OF A MEMBRANE ELECTRODE ASSEMBLY (MEA), MEA, CELL AND USES THEREOF
The present invention refers to fabrication method of a membrane electrode assembly (MEA), to MEA obtainable by said method, to a cell comprising said MEA, to the use of the MEA and the cell for the electrochemical detection of analytes, and to the use of the MEA and the cell for storing and/or delivering electricity.
Zero polar distance ion exchange membrane and preparation method thereof
A zero polar distance ion exchange membrane. A polymer membrane is compositely prepared by a perfluorinated ion exchange resin and a reinforcing material, and the polymer membrane is converted into an ion exchange membrane. A non-electrode porous gas release layer is adhered to at least one side of the ion exchange membrane. The non-electrode porous gas release layer is formed by drying after adhering a dispersion liquid to an ion exchange membrane layer surface. The dispersion liquid is formed by dispersing perfluorinated sulphonic acid resin broken micro-particles in a sulphonic acid resin aqueous alcohol solution. The prepared zero polar distance ion exchange membrane is used in the chlor-alkali industry, stably and effectively treats an alkali metal chloride solution having a high impurity content, is able to better suited for operating in a zero polar distance electrolysis cell under high current density conditions, and has a very low surface resistance. Also provided is a preparation method for the zero polar distance ion exchange membrane. The preparation method has a simple and reasonable process, and facilitates industrial production.
PROTON EXCHANGE MEMBRANE AND MANUFACTURING METHOD THEREOF
A manufacturing method of a proton exchange membrane is provided, which includes the steps as follows. The hydroxyl groups are disposed on the surface of a substrate by a hydrophilic treatment. The hydroxyl groups on the substrate are chemically modified with a coupling agent by a sol-gel process. The substrate is exposed to an amino acid with a phosphonate radical so that the amino acid containing a phosphonate radical can be chemically bonded with the coupling agent. The chemically bonded substrate is immersed in phosphoric acid for absorbing the phosphoric acid. The substrate blended with the phosphoric acid is placed between at least two leak-proof films for the purpose of preventing the leakage of the absorbed phosphoric acid. The proton exchange membrane manufactured by this method enable to retain the phosphoric acid in organic/inorganic complex form and micron/nano complex pore size.
REINFORCED COMPOSITE MEMBRANE, AND MEMBRANE-ELECTRODE ASSEMBLY AND FUEL CELL WHICH COMPRISE SAME
A reinforced composite membrane with improved ion conductivity and wettability is provided. Provided in one embodiment of the present disclosure is a reinforced composite membrane comprising a porous support and an ionomer layer, which comprises an ion conductor filling the pores inside the porous support, wherein the porous support comprises a first surface and a second surface opposite to the first surface, and the first surface is reformed to contain a first hydrophilic functional group.
MEMBRANE-SEAL ASSEMBLY
Disclosed is a reinforced membrane-seal assembly, the reinforced membrane-seal assembly including: an inner region and a border region and wherein the inner region includes ion-conducting component and the border region includes seal component; wherein first and second planar porous reinforcing components each extend across the inner region into the border region and wherein the pores of each of the first and second planar porous reinforcing components in the inner region are impregnated with ion-conducting component and the pores of each of the first and second planar porous reinforcing components in the border region are impregnated with seal component is disclosed. Also disclosed is a catalyst-coated reinforced membrane-seal assembly, a reinforced membrane-seal electrode assembly and an electrochemical device including the reinforced membrane-seal assembly.
PROCESS
A process for manufacturing a reinforced membrane-seal assembly includes: (i) providing a carrier material; (ii) providing a planar reinforcing component having one or more first regions including pores and a second region including pores, the first regions being patches and non-continuous and the second region surrounding the first regions and being continuous; (iii) depositing an ion-conducting component; (iv) drying the ion-conducting component; (v) depositing a seal component; (vi) drying the seal component (vii) removing the carrier material. In embodiments, ion-conducting component fills the pores in the first regions and seal component fills the pores in the second region; steps (ii), (iii) and (v) can be carried out in any order; step (iv) is carried out subsequent to step (iii); step (vi) is carried out subsequent to step (v); and steps (iv) and (vi) are carried out subsequent to step (ii). Also disclosed is an assembly prepared by such process.
PROCESS
A process for manufacturing a reinforced membrane-seal assembly includes: (i) providing a carrier material; (ii) providing a planar reinforcing component having one or more first regions including pores and a second region including pores, the first regions being patches and non-continuous and the second region surrounding the first regions and being continuous; (iii) depositing an ion-conducting component; (iv) drying the ion-conducting component; (v) depositing a seal component; (vi) drying the seal component (vii) removing the carrier material. In embodiments, ion-conducting component fills the pores in the first regions and seal component fills the pores in the second region; steps (ii), (iii) and (v) can be carried out in any order; step (iv) is carried out subsequent to step (iii); step (vi) is carried out subsequent to step (v); and steps (iv) and (vi) are carried out subsequent to step (ii). Also disclosed is an assembly prepared by such process.