A method of producing a rechargeable lithium battery cell, the method comprising (a) preparing a liquid electrolyte solution comprising an ion-conducting polymer dispersed in a first liquid solvent and an optional lithium salt dissolved in the first liquid solvent; (b) impregnating the electrolyte solution into the cathode, the anode, a porous structure of the separator, or the battery cell; (c) removing the first liquid solvent; and (d) impregnating a second liquid solvent, comprising an optional lithium salt dissolved therein, into the cathode, the anode, the separator porous structure, or the battery cell; wherein the ion-conducting polymer comprises a polymer having an ion conductivity from 10.sup.−8 S/cm to 10.sup.−2 S/cm when measured at room temperature without the presence of a liquid solvent and the polymer does not occupy more than 25% by weight of the cathode, not counting a current collector weight.

The disclosure provides a primary battery and an electrode assembly thereof. The electrode assembly includes a separator, a positive electrode, and a negative electrode current collector. The separator has a positive electrode side and a negative electrode side opposite to each other. The positive electrode is located at the positive electrode side of the separator, and the positive electrode includes a positive electrode current collector and a positive electrode material. The negative electrode current collector is located at the negative electrode side of the separator. The electrode assembly does not include a negative electrode material before charging or activation.

Electrolytes and electrolyte additives for energy storage devices comprising sulfonate or carboxylate salt based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a sulfonate or carboxylate salt based compound.

Electrolytes and electrolyte additives for energy storage devices comprising benzoyl peroxide based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a benzoyl peroxide based compound.

An electrochemical device includes a negative electrode plate and an electrolyte. The negative electrode plate includes a negative active material. A specific surface area of the negative active material is A m.sup.2/g and 0.3≤A≤4. The electrolyte includes fluorocarboxylate and fluorocarbonate. Based on a mass of the electrolyte, a mass percent of the fluorocarboxylate is X % and a mass percent of the fluorocarbonate is Y %, 5≤Y≤70, and the electrochemical device satisfies 50≤X+Y≤85, and 6≤Y/A≤200. The synergy between the negative active material and the electrolyte can effectively improve cycle performance of the electrochemical device under high voltages, and alleviate lithium plating of the negative electrode.

The present disclosure is directed to fluoride (F) ion batteries and F shuttle batteries comprising an anode with a solid electrolyte interphase (SEI) layer, a cathode comprising a core shell structure, and a liquid fluoride battery electrolyte. According to some aspects, the components therein enable discharge and recharge at room-temperature.

Some aspects of the invention are related to lithium batteries, and more specifically, to in-situ control of solid electrolyte interface for enhanced cycle performance in lithium metal batteries. In some embodiments, the electrochemical cell comprises a solid electrolyte interphase (SEI) layer that is rich in inorganic materials (e.g., LiF, Li.sub.2O, Li.sub.2CO.sub.3) and has various advantageous properties (e.g., improved anode stability, etc.). Some embodiments are directed to methods of electrical energy storage and use of an electrochemical cell. In some cases, the methods comprise applying anisotropic force and/or formation voltage to a cell and forming an inorganic rich SEI layer in-situ.

A metallic salt including at least one anion having a heterocyclic aromatic structure represented by one of Formulae 1 to 3; and a metallic cation: ##STR00001##
wherein, in Formulae 1 to 3, each X is independently N, P, or As, one of A.sub.1 and A.sub.2 is an electron-donating group, and the other one is an electron-withdrawing group, ring Ar.sub.1 and ring Ar.sub.2 are as defined herein, L is a linker group as defined herein, m is an integer from 1 to 5, and n is an integer from 0 to 5.

Electrolytes and electrolyte additives for energy storage devices comprising dihydrofuranone based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a dihydrofuranone based compound.

An electrolyte for a lithium metal battery includes a nonaqueous aprotic organic solvent, a lithium salt dissolved in the nonaqueous aprotic organic solvent and, by volume, from 1% to 10% of a flame retardant additive. The flame retardant additive is at least one of an organophosphate compound, an organophosphite compound, organophosphonate compound, or a phosphazene compound.