The hybrid battery system includes a primary battery pack, a secondary battery pack, a battery control unit, a battery pack positive terminal, and a battery pack negative terminal. The battery control unit includes a management module and a variable resistor. The primary battery pack supplies power at lower temperatures, while the secondary battery pack supplies power at higher temperatures. The primary battery pack is unsafe at higher temperatures, and the primary cells within the primary battery pack are modified to mitigate the dangers that previously rendered the primary battery pack unusable in a hybrid battery pack at higher temperatures. The invention includes the method of safely operating the hybrid battery system with the modified primary battery cells of the primary battery pack.

The invention provides filamentous organism-derived carbonaceous materials doped with organic and/or inorganic compounds, and methods of making the same. In certain embodiments, these carbonaceous materials are used as electrodes in solid state batteries and/or lithium-ion batteries. In another aspect, these carbonaceous materials are used as a catalyst, catalyst support, adsorbent, filter and/or other carbon-based material or adsorbent. In yet another aspect, the invention provides battery devices incorporating the carbonaceous electrode materials.

A lithium secondary battery includes a cathode including a cathode current collector and a cathode active material layer disposed on at least one surface of the cathode current collector, the cathode active material layer including a cathode active material including first cathode active material particles, each of which has a single particle shape; an anode facing the cathode; and a non-aqueous electrolyte including a non-aqueous organic solvent that contains a fluorine-based organic solvent, a lithium salt and an additive.

A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

Positive electrode active material particles that inhibit a decrease in capacity due to charge and discharge cycles are provided. A high-capacity secondary battery, a secondary battery with excellent charge and discharge characteristics, or a highly-safe or highly-reliable secondary battery is provided. A novel material, active material particles, and a storage device are provided. The positive electrode active material particle includes a first region and a second region in contact with the outside of the first region. The first region contains lithium, oxygen, and an element M that is one or more elements selected from cobalt, manganese, and nickel. The second region contains the element M, oxygen, magnesium, and fluorine. The atomic ratio of lithium to the element M (Li/M) measured by X-ray photoelectron spectroscopy is 0.5 or more and 0.85 or less. The atomic ratio of magnesium to the element M (Mg/M) is 0.2 or more and 0.5 or less.

An electrolyte for a lithium secondary battery according to exemplary embodiments may include a lithium salt; a solvent composed of a non-aqueous solvent and including a carbonate solvent; and an additive including a bis(fluorosulfonyl)imide alkali metal salt. Accordingly, it is possible to provide an electrolyte for a lithium secondary battery having excellent high-temperature characteristics, and a lithium secondary battery including the same.

Lithium tetrafluoro(malonato)phosphate compounds are useful as additives in lithium ion battery applications. The compounds are represented by Formula (I): MPF.sub.4[—O(C═O)—(CX′X″)—(C═O)O—]; wherein M is Li or Na; each X′ and X″ independently is selected from the group consisting of H, alkyl, fluoro-substituted alkyl, and F; or wherein the X′ and X″ together are —CR.sub.2—(CR′.sub.2).sub.m—CR″.sub.2—; each R, R′ and R″ independently is selected from the group consisting of H methyl, trifluoromethyl, and F; and in is 0 or 1. These compounds can be prepared in high purity and a high yield by reaction of a metal hexafluorophosphate with a bis-silyl malonate compound. A similar oxalato compound, lithium tetrafluoro(oxalato)phosphate), can be made in the same manner, but using a bis-silyl oxalate in place of the bis-silyl malonate. Advantageously, the compounds can be formed, in situ, in a LiPF.sub.6-containing electrolyte solution.

Separators, materials, and processes for producing electrochemical cells, for example, lithium (Li) metal batteries, and electrochemical cells produced therefrom. Such a separator includes a permeable membrane formed of a first polymer that is hydrophobic and has oppositely-disposed first and second surfaces, a second polymer that is hydrophilic and is incorporated into the first surface of the first polymer so that the first surface of the first polymer is a hydrophilic surface, and a conductive composite layer on the hydrophilic surface. The composite layer contains at least one layer of a carbonaceous material and an aqueous binder that binds the carbonaceous material together and to the hydrophilic.

This invention provides nonaqueous electrolyte solutions for lithium batteries. The nonaqueous electrolyte solutions comprise a liquid electrolyte medium; a lithium-containing salt; and at least one oxygen-containing brominated flame retardant.

A secondary battery that can withstand at least high temperature is achieved by designing the structure of the secondary battery. The secondary battery uses: a positive electrode active material obtained by a formation method including a first step of forming a first mixture by pulverizing magnesium fluoride, lithium fluoride, a nickel source, and an aluminum source and then mixing the pulverized materials with powder of lithium cobalt oxide, and a second step of forming a second mixture by heating the first mixture at a temperature lower than an upper temperature limit of the lithium cobalt oxide; and an electrolyte solution to which LiBOB is added.