The present disclosure is directed to an energy storage device having improved thermal performance. More specifically, the energy storage device includes a housing with side walls that define an internal volume. The side walls include bottom and front side walls, with the front side wall having an air inlet and outlet configured to circulate cooling air therethrough. The energy storage device also includes a plurality of cells arranged in a matrix within the internal volume atop the bottom side wall. Further, the cells define a top surface. Further, the energy storage device includes an exhaust manifold adjacent to the front side wall between at least a portion of the cells and the air inlet. Thus, the exhaust manifold is configured to direct airflow from the top surface towards the bottom side wall and then to the air outlet so as to provide an airflow barrier between cooling air entering the air inlet and the cells.

A redox flow battery that is charged and discharged by supply of a positive electrode electrolyte and a negative electrode electrolyte to a battery cell including a positive electrode, a negative electrode, and a diaphragm interposed between the positive electrode and the negative electrode, wherein the positive electrode electrolyte and the negative electrode electrolyte are molten salts, the positive electrode electrolyte contains a trivalent titanium ion and a tetravalent titanium ion, and the negative electrode electrolyte contains a divalent titanium ion and a trivalent titanium ion.

The present invention provides a method of preparing an electrode for a lithium secondary battery which includes forming a first electrolyte layer by immersing an electrode current collector in a composition for forming the first electrolyte layer and applying a current, and forming a second electrolyte layer by immersing the electrode current collector having the first electrolyte layer formed thereon in a composition for forming the second electrolyte layer and applying a current, wherein one of the composition for forming the first electrolyte layer and the composition for forming the second electrolyte layer is a composition for forming an organic electrolyte layer, and another one is a composition for forming an inorganic electrolyte layer, and the composition for forming an inorganic electrolyte layer includes a compound represented by Formula 1.