An oxide includes a compound represented by Formula 1, a compound represented by Formula 2, or a combination thereof:
Li.sub.1−x+y−zTa.sub.2−xM.sub.xP.sub.1−yQ.sub.yO.sub.8−zX.sub.z  Formula 1
wherein, in Formula 1, M is an element having an oxidation number of 5+ or 6+, Q is an element having an oxidation number of 4+, X is a halogen atom, a pseudohalogen, or a combination thereof,
0≤x<0.6, 0≤y<1, and 0≤z<1, wherein x and y are not 0 at the same time,
Li.sub.1−x+yTa.sub.2−xM.sub.xP.sub.1−yQ.sub.yO.sub.8.zLiX  Formula 2
wherein, in Formula 2, M is an element having an oxidation number of 5+ or 6+, Q is an element having an oxidation number of 4+, X is a halogen atom, a pseudohalogen or a combination thereof, 0≤x<0.6, 0≤y<1, and 0≤z<1, wherein x and y are not 0 at the same time, and
wherein in Formulas 1 and 2, M, Q, x, y, and z are independently selected.

The invention discloses a recycling method for oxide-based solid electrolyte with original phase, method of fabricating lithium battery and green battery thereof, which is adapted to recycle the solid-state or quasi-solid lithium batteries after discard. The oxide-based solid electrolyte is only used as an ion transport pathway, and does not participate in the insertion and extraction of lithium ions during charge and discharge cycles. Its crystal structure dose not be destroyed. Therefore, the original phase recycle of the oxide-based solid electrolyte is achieved without damage the structure or materials. The recycled the oxide-based solid electrolyte can be re-used to reduce the manufacturing cost of the related lithium battery.

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

A lithium-ion battery comprising an anode, a cathode, a lithium-ion permeable and electrically insulating separator that electrically separates the anode from the cathode, and an artificial solid-electrolyte interface (SEI) layer disposed between the anode and the separator wherein (a) the artificial SEI layer has a lithium-ion conductivity greater than 10.sup.−6 S/cm and (b) the anode comprises (i) multiple particles of an anode active material selected from the group consisting of silicon (Si), germanium (Ge), phosphorus (P), tin (Sn), lead (Pb), antimony (Sb), bismuth (Bi), zinc (Zn), aluminum (Al), titanium (Ti), nickel (Ni), cobalt (Co), cadmium (Cd), alloys thereof, alloys thereof with lithium (Li), and combinations thereof; (ii) 0-10% (preferably 0.1%-5%) by weight of a conductive additive; and (iii) 0-10% (preferably 0-5%) by weight of a binder resin. Also provided is a method of producing such a battery.

A ceramic powder material containing: a first garnet-type compound containing Li, La, and Zr; and a second garnet-type compound containing Li, La, and Zr and having a composition different from a composition of the first garnet-type compound, in which the first garnet-type compound and the second garnet-type compound are represented by Formula [1] Li.sub.7-(3x+y)M1.sub.xLa.sub.3Zr.sub.2-yM2.sub.yO.sub.12, where Ml is Al or Ga, M2 is Nb or Ta, the first garnet-type compound satisfies 0≤(3x+y)≤0.5, and the second garnet-type compound satisfies 0.5<(3x+y)≤1.5.

A method is provided for fabricating a component material for a battery cell. The method comprises the steps of: providing a partially-fabricated battery cell, the partially-fabricated battery cell comprising a substrate having a planar deposition surface consisting of a first face of the substrate and a first battery component layer provided on the planar deposition surface, the substrate having a plurality of further surfaces, the planar deposition surface and the plurality of further surfaces defining the body of the substrate therebetween; wherein: the first battery component layer contains charge-carrying metal species and has an exposed surface; one or more electrically conductive or semi-conductive pathways extend through at least a portion of the substrate, each of the one or more pathways connecting the planar deposition surface to one of the plurality of further surfaces; and the partially-fabricated battery cell is held in position within a deposition chamber by a holding structure and each site of connection between one of the one or more pathways and the holding structure is electrically insulating; the method further comprising the step of depositing a second battery component layer on the first battery component layer, wherein the depositing comprises forming a plasma within the deposition chamber.

Provided are a positive electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same. The positive electrode for a rechargeable lithium battery includes a current collector, a first positive electrode active material layer on the current collector and including a first positive electrode active material, and a second positive electrode active material layer on the first positive electrode active material layer and including a second positive electrode active material, wherein the first positive electrode active material layer includes ceramic particles, a particle diameter of each of the ceramic particles is in a range from about 10 nm to about 500 nm, and the ceramic particles are included only in the first positive electrode active material layer.

The present disclosure provides a cobalt-free lamellar cathode material and a method for preparing the cobalt-free lamellar cathode material, a cathode piece and a lithium ion battery. The cobalt-free lamellar cathode material comprises a LiNi.sub.xMn.sub.yO.sub.2 crystal, wherein x+y=1, 0.55≤x≤0.95, 0.05≤y≤0.45; and a lithium ion conductor, the lithium ion conductor being attached to at least part of a surface of the LiNi.sub.xMn.sub.yO.sub.2 crystal. The cobalt-free lamellar cathode material has the advantages of low cost, low surface impedance and good conductivity. Lithium ions have high diffusion velocity and electrochemical activity in the cobalt-free lamellar cathode material. A lithium ion battery manufactured by the cobalt-free lamellar cathode material has the advantages of high charge specific capacity, high discharge specific capacity, high first effect, good cycle performance and good rate capability.

The present invention provides a method for manufacturing a positive electrode material for an electricity storage device that can reduce excessive reactions between particles of a positive electrode active material precursor powder and between the positive electrode active material precursor powder and a solid electrolyte during thermal treatment to achieve excellent charge and discharge characteristics. A method for manufacturing a positive electrode material for an electricity storage device includes the step of subjecting a raw material containing a positive electrode active material precursor powder made of an amorphous oxide material to thermal treatment, wherein the positive electrode active material precursor powder has a crystallization temperature of 490° C. or lower.

Provided are a composite oxide powder from which dense solid electrolyte objects having a high ion conductivity can be produced and a method for producing the composite oxide powder. The composite oxide powder is composed of particles comprising lithium (Li), lanthanum (La), zirconium (Zr), and oxygen (O) and having a cubic garnet-type crystal structure, and has a volume particle size distribution in which the 50% diameter (D50) is 1,000 nm or smaller, the composite oxide powder having a pyrochlore phase content of 10 mass % or less.