Patent classifications
H10K85/1135
PEDOT IN PEROVSKITE SOLAR CELLS
The present invention relates to a process for the production of a layered body (1), at least comprising the process steps: I) provision of a photoactive layer comprising a material having a perovskite type crystal structure; II) superimposing the photoactive layer at least partially with a coating composition A) comprising an electrically conductive polymer a) and an organic solvent b); III) at least partial removal of the organic solvent b) from the coating composition A) superimposed in process step II), thereby obtaining an electrically conductive layer superimposed on the photoactive layer. The present invention also relates to a layered body obtainable by this process, to dispersions, to an electronic device, to a process for the preparation of a photovoltaic device and to the photovoltaic device that is obtainable by this process.
OPTOELECTRONIC DEVICE
The invention provides an optoelectronic device comprising a photoactive region, which photoactive region comprises: an n-type region comprising at least one n-type layer; a p- type region comprising at least one p-type layer; and, disposed between the n-type region and the p-type region: a layer of a perovskite semiconductor without open porosity. The perovskite semiconductor is generally light-absorbing. In some embodiments, disposed between the n-type region and the p-type region is: (i) a first layer which comprises a scaffold material, which is typically porous, and a perovskite semiconductor, which is typically disposed in pores of the scaffold material; and (ii) a capping layer dis -posed on said first layer, which capping layer is said layer of a perovskite semiconductor without open porosity, wherein the perovskite semiconductor in the capping layer is in contact with the perovskite semiconductor in the first layer. The layer of the perovskite semiconductor without open porosity (which may be said capping layer) typically forms a planar heterojunction with the n-type region or the p-type region. The invention also provides processes for producing such optoelectronic devices which typically involve solution deposition or vapour deposition of the perovskite. In one embodiment, the process is a low temperature process; for instance, the entire process may be performed at a temperature or temperatures not exceeding 150° C.
COMPOSITION FOR HOLE COLLECTING LAYER OF ORGANIC PHOTOELECTRIC CONVERSION ELEMENT
Provided is a composition for a hole collecting layer of an organic photoelectric conversion element, the composition containing a solvent and an electron transporting substance comprising a polythiophene derivative that includes a repeating unit represented by formula (1) or formula (1′).
##STR00001##
(In formula (1) and formula (1′), R.sup.1 denotes an alkyl group having 1-6 carbon atoms or a fluorine atom. In formula (1), M denotes a hydrogen atom, an alkali metal selected from the group consisting of Li, Na and K, NH(R.sup.2).sub.3 or HNC.sub.5H.sub.5. R.sup.2 groups are each independently a hydrogen atom or an optionally substituted alkyl group having 1-6 carbon atoms.)
PEROVSKITE NANOCRYSTALLINE PARTICLES AND OPTOELECTRONIC DEVICE USING SAME
Provided are perovskite nanocrystalline particle and an optoelectronic device using the same. The perovskite nanocrystalline particle may include a perovskite nanocrystalline structure while being dispersible in an organic solvent. Accordingly, the perovskite nanocrystalline particle in accordance with the present invention has therein a perovskite nanocrystal having a crystalline structure in which FCC and BCC are combined; forms a lamellar structure in which an organic plane and an inorganic plane are alternately stacked; and can show high color purity since excitons are confined to the inorganic plane. In addition, the perovskite nanocrystalline particle have a particle size greater than or equal to a Bohr diameter beyond a quantum confinement effect, and simultaneously can implement high emission efficiency and emission wavelength which is almost not dependent on particle size. Furthermore, the perovskite nanocrystalline particle in accordance with the present invention, as a nanoparticle which is dispersible in an organic solvent, is applicable in various electronic devices such as light emitting devices, lasers, solar cells, etc.
LIGHT-EMITTING LAYER FOR PEROVSKITE LIGHT-EMITTING DEVICE, METHOD FOR MANUFACTURING SAME, AND PEROVSKITE LIGHT-EMITTING DEVICE USING SAME
Provided are: a light-emitting layer for a perovskite light-emitting device; a method for manufacturing the same; and a perovskite light-emitting device using the same. The method of the present invention for manufacturing a light-emitting layer for an organic and inorganic hybrid perovskite light-emitting device comprises a step of forming a first nanoparticle thin film by coating, on a member for coating a light-emitting layer, a solution comprising organic and inorganic perovskite nanoparticles including an organic and inorganic perovskite nanocrystalline structure. Thereby, a nanoparticle light emitter has therein an organic and inorganic hybrid perovskite having a crystalline structure in which FCC and BCC are combined; forms a lamella structure in which an organic plane and an inorganic plane are alternatively stacked; and can show high color purity since excitons are confined to the inorganic plane. In addition, it is possible to improve the luminescence efficiency and luminance of a device by making perovskite as nanoparticles and then introducing the same into a light-emitting layer.
LUMINOUS MEMBER, METHOD OF DRIVING LUMINOUS MEMBER, NON-VOLATILE MEMORY DEVICE, SENSOR, METHOD OF DRIVING SENSOR, AND DISPLAY APPARATUS
Provided are a luminous member, a method of driving the luminous member, a non-volatile memory device, a sensor, a method of driving the sensor, and a display apparatus. The luminous member includes a first electrode; a second electrode facing the first electrode; an emission layer, which is disposed on a main surface of the first electrode and emits light by power applied between the first electrode and the second electrode; and a ferrodielectric layer disposed between the emission layer and the second electrode, wherein AC power applied to the luminous member is controlled based on polarity or magnitude of a residual polarization generated in the ferrodielectric layer, thereby adjusting emission characteristics of the emission layer.
Conjugated polymers
The invention relates to novel polymers containing repeating units based on benzo[2,1,3]thiadiazole-5,6-dicarboxylic acid bis-ester, monomers and methods for their preparation, their use as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, and to OE and OPV devices comprising these polymers.
Aromatic amine derivative, and organic electroluminescent element containing same
An aromatic amine derivative represented by the following formula (1): wherein Z.sub.1 is a group represented by the following formula (2); Z.sub.2 is a group represented by the following formula (3) or (3′); and P and Q are independently a group represented by the following formula (4) or (5): ##STR00001##
QUANTUM-DOT LIGHT EMITTING DIODE, METHOD OF FABRICATING THE QUANTUM-DOT LIGHT EMITTING DIODE AND QUANTUM-DOT LIGHT EMITTING DISPLAY DEVICE
The present disclosure provides a quantum dot (QD) light emitting diode including: a first electrode; a second electrode facing the first electrode; a QD emitting material layer positioned between the first electrode and the second electrode and including a QD and an organic material; a hole auxiliary layer positioned between the first electrode and the QD emitting material layer; and an electron auxiliary layer positioned between the QD emitting material layer and the second electrode, wherein the organic material has a highest occupied molecular orbital (HOMO) level higher than a material of the hole auxiliary layer.
PEROVSKITE NANOCRYSTAL PARTICLE LIGHT EMITTING BODY WITH CORE-SHELL STRUCTURE, METHOD FOR FABRICATING SAME, AND LIGHT EMITTING ELEMENT USING SAME
Provided are a core-shell structured perovskite nanocrystalline particle light-emitting body, a method of preparing the same, and a light emitting device using the same. The core-shell structured organic-inorganic hybrid perovskite nanocrystalline particle light-emitting body or metal halide perovskite nanocrystalline particle light-emitting body is able to be dispersed in an organic solvent, and has a perovskite nanocrystal structure and a core-shell structured nanocrystalline particle structure. Therefore, in the perovskite nanocrystalline particle light-emitting body of the present invention, as a shell is formed of a substance having a wider band gap than that of a core, excitons may be more dominantly confined in the core, and durability of the nanocrystal may be improved to prevent exposure of the core perovskite to the air using a perovskite or inorganic semiconductor, which is stable in the air, or an organic polymer.