Magnetic powder includes: at least one epsilon-phase iron oxide-based compound selected from the group consisting of -Fe.sub.2O.sub.3 and a compound represented by Formula (1); and a surface treatment layer including a silane compound on at least a part of a surface. The magnetic powder has an average particle diameter of 8 nm to 20 nm. The content ratio of carbon atoms of the silane compound included in the surface treatment layer to iron atoms of the at least one epsilon-phase iron oxide-based compound selected from the group consisting of -Fe.sub.2O.sub.3 and the compound represented by Formula (1) is 0.05% to 0.5% in terms of the number of atoms. A manufacturing method thereof and applications thereof are also provided. In Formula (1), A represents at least one metal element other than Fe and a represents a number that satisfies a relationship of 0<a<2.
-A.sub.aFe.sub.2-aO.sub.3(1)

Magnetic powder includes: at least one epsilon-phase iron oxide-based compound selected from the group consisting of -Fe.sub.2O.sub.3 and a compound represented by Formula (1); and a surface treatment layer including a silane compound on at least a part of a surface. The magnetic powder has an average particle diameter of 8 nm to 20 nm. The content ratio of carbon atoms of the silane compound included in the surface treatment layer to iron atoms of the at least one epsilon-phase iron oxide-based compound selected from the group consisting of -Fe.sub.2O.sub.3 and the compound represented by Formula (1) is 0.05% to 0.5% in terms of the number of atoms. A manufacturing method thereof and applications thereof are also provided. In Formula (1), A represents at least one metal element other than Fe and a represents a number that satisfies a relationship of 0<a<2.
-A.sub.aFe.sub.2-aO.sub.3(1)

A method for making iron-based oxide magnetic particle powders having particular peak intensity and diffraction intensities, comprising neutralizing an aqueous solution containing a trivalent iron ion, alone or with a substituting metal (M), a step of adding hydroxycarboxylic acid to the neutralized solution to create a second solution including the hydroxycarboxylic acid D, another neutralizing step for the second solution, a coating step of silicon oxide coating iron oxyhydroxide with or without the substituted metal element found in the second neutralized solution, and heating the coated iron oxyhydroxide with or without the substituted metal element to form a silicon oxide coated iron oxide with or without the substituted metal element. After the second neutralization step, there is no water washing. As a result, the molar ratio D/(Fe+M) is between 0.125 and 1.0 and the silicon oxide coating can be uniform and the formation reaction of the hydroxide is not retarded.

A method for making iron-based oxide magnetic particle powders having particular peak intensity and diffraction intensities, comprising neutralizing an aqueous solution containing a trivalent iron ion, alone or with a substituting metal (M), a step of adding hydroxycarboxylic acid to the neutralized solution to create a second solution including the hydroxycarboxylic acid D, another neutralizing step for the second solution, a coating step of silicon oxide coating iron oxyhydroxide with or without the substituted metal element found in the second neutralized solution, and heating the coated iron oxyhydroxide with or without the substituted metal element to form a silicon oxide coated iron oxide with or without the substituted metal element. After the second neutralization step, there is no water washing. As a result, the molar ratio D/(Fe+M) is between 0.125 and 1.0 and the silicon oxide coating can be uniform and the formation reaction of the hydroxide is not retarded.

The present invention provides a ferrite sintered magnet comprising ferrite crystal grains having a hexagonal structure, wherein the ferrite sintered magnet comprises metallic elements at an atomic ratio represented by formula (1). In formula (1), R is at least one element selected from the group consisting of Bi and rare-earth elements, and R comprises at least La. In formula (1), w, x, z and m satisfy formulae (2) to (5). The above-mentioned ferrite sintered magnet further has a coefficient of variation of a size of the crystal grains in a section parallel to a c axis of less than 45%.

Ca.sub.1-w-xR.sub.wSr.sub.xFe.sub.zCo.sub.m(1)

0.360w=0.420(2)

0.110x0.173(3)

8.51z9.71(4)

0.208m0.269(5)

The present invention provides a ferrite sintered magnet comprising ferrite crystal grains having a hexagonal structure, wherein the ferrite sintered magnet comprises metallic elements at an atomic ratio represented by formula (1). In formula (1), R is at least one element selected from the group consisting of Bi and rare-earth elements, and R comprises at least La. In formula (1), w, x, z and m satisfy formulae (2) to (5). The above-mentioned ferrite sintered magnet further has a coefficient of variation of a size of the crystal grains in a section parallel to a c axis of less than 45%.

Ca.sub.1-w-xR.sub.wSr.sub.xFe.sub.zCo.sub.m(1)

0.360w=0.420(2)

0.110x0.173(3)

8.51z9.71(4)

0.208m0.269(5)

A ferrite core according to an embodiment of the present invention includes a plurality of grains including Mn at 30 to 40 mol %, Zn at 5 to 15 mol %, and Fe at 50 to 60 mol %, and a plurality of grain boundaries disposed between the plurality of grains, wherein the plurality of grains and the plurality of grain boundaries include Co, Ni, SiO.sub.2, CaO, and Ta.sub.2O.sub.5, content of the Co and the Ni in the plurality of grains is two or more times higher than content of the Co and the Ni in the plurality of grain boundaries, content of the SiO.sub.2, the CaO, and the Ta.sub.2O.sub.5 in the plurality of grain boundaries is two or more times higher than content of the SiO.sub.2, the CaO, and the Ta.sub.2O.sub.5 in the plurality of grains, a magnetic permeability is 3000 or more, and a core loss is 800 or less.

A ferrite core according to an embodiment of the present invention includes a plurality of grains including Mn at 30 to 40 mol %, Zn at 5 to 15 mol %, and Fe at 50 to 60 mol %, and a plurality of grain boundaries disposed between the plurality of grains, wherein the plurality of grains and the plurality of grain boundaries include Co, Ni, SiO.sub.2, CaO, and Ta.sub.2O.sub.5, content of the Co and the Ni in the plurality of grains is two or more times higher than content of the Co and the Ni in the plurality of grain boundaries, content of the SiO.sub.2, the CaO, and the Ta.sub.2O.sub.5 in the plurality of grain boundaries is two or more times higher than content of the SiO.sub.2, the CaO, and the Ta.sub.2O.sub.5 in the plurality of grains, a magnetic permeability is 3000 or more, and a core loss is 800 or less.

[Solving Means] A method of producing a magnetic powder includes: coating a surface of each of silica-coated precursor particles with at least one type of coating agent of a metal chloride or a sulfate; and firing the precursor particles coated with the coating agent.

[Solving Means] A method of producing a magnetic powder includes: coating a surface of each of silica-coated precursor particles with at least one type of coating agent of a metal chloride or a sulfate; and firing the precursor particles coated with the coating agent.