A solid electrolytic capacitor that comprises an anode that contains a dielectric formed on a sintered porous body is provided. The sintered porous body is formed from a valve metal powder having a specific charge of about 100,000 microFarads*Volts per gram or more. The solid electrolyte overlies the anode, and includes an intrinsically conductive polymer containing repeating units having the following formula (I): ##STR00001##
wherein, R is (CH.sub.2).sub.a—O—(CH.sub.2).sub.b; a is from 0 to 10; b is from 1 to 18; Z is an anion; and X is a cation.

An electrolytic capacitor includes an anode body having a porous structure, an anode lead partially embedded in the anode body, a dielectric layer formed on a surface of the anode body, and a cathode part that covers at least part of the dielectric layer. The anode body has a first region in which first particles sintered together and a second region in which second particles sintered together. The average particle diameter D1 of the first particles is smaller than the average particle diameter D2 of the second particles. The volume-based pore diameter distribution of the anode body with the dielectric layer has a first peak in a range of less than or equal to 0.5 μm in pore diameter, and a second peak in a range of more than 0.5 μm in pore diameter.

An improved capacitor is provided wherein the capacitor has an improved bond between the anode and anode wire. The anode comprises a pressed anode powder comprising a first density region and a second density region wherein the second density region has a higher density than the first density region. An anode wire extends into the second density region wherein the anode wire in the second density region is distorted by compression. This allows for better utilization of the metal powder surface area by allowing a lower bulk press density and lower sinter temperature while still achieving the necessary wire pull strength. In addition, this invention when utilized with deoxidation steps, results in sufficient wire pull strengths not possible otherwise.

An electrolytic capacitor including a capacitor element that includes an anode body being porous, a dielectric layer formed on the surface of the anode body, and a solid electrolyte layer covering at least part of the dielectric layer. The anode body has a plurality of principal surfaces and a corner portion. The corner portion includes a plurality of side portions connecting between the principal surfaces, and one or more vertex portions connecting between the principal surfaces. A surface layer X of at least part of the corner portion is more compact in texture than a surface layer Y of the principal surface adjacent to the surface layer X.

An electrode holder and a method for producing an electrode for an aluminum electrolytic capacitor are provided that enable prevention of exfoliation of a porous layer during chemical formation even when the porous layer is formed on an aluminum electrode so as to have a thickness of 200 micrometers or greater. When an aluminum electrode 10 having at least one surface 11 on which a porous layer 17 having a thickness of 200 micrometers or greater is formed is subjected to chemical formation in a chemical formation solution, the aluminum electrode 10 is held by an electrode holder 50. The electrode holder 50 includes: an insulating first support plate 51 configured to overlap the one surface 11 of the aluminum electrode 10; an insulating second support plate 52 configured to overlap the other surface 12 of the aluminum electrode 10; and a connecting part 53 configured to connect the first support plate 51 and the second support plate 52 to each other. A portion of the first support plate 51 that overlaps the porous layer 17 while being in contact therewith is formed with a porous member 510.

Provided is an improved capacitor formed by a process comprising: providing an anode comprising a dielectric thereon wherein the anode comprises a sintered powder wherein the powder has a powder charge of at least 45,000 μFV/g; and forming a first conductive polymer layer encasing at least a portion of the dielectric by applying a first slurry wherein the first slurry comprises a polyanion and a conductive polymer and wherein the polyanion and conductive polymer are in a weight ratio of greater than 3 wherein the conductive polymer and polyanion forms conductive particles with an average particle size of no more than 20 nm.

A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.

A solid electrolytic capacitor comprising a capacitor element is provided. The capacitor element comprises a sintered porous anode body; a dielectric that overlies the anode body; and a solid electrolyte that overlies the dielectric and that includes a conductive polymer and a depolarizer.

An electrolytic capacitor includes an anode body having a porous structure, an anode lead partially embedded in the anode body, a dielectric layer formed on a surface of the anode body, and a cathode part that covers at least part of the dielectric layer. The anode body has a first region in which first particles sintered together and a second region in which second particles sintered together. The average particle diameter D1 of the first particles is smaller than the average particle diameter D2 of the second particles. The volume-based pore diameter distribution of the anode body with the dielectric layer has a first peak in a range of less than or equal to 0.5 μm in pore diameter, and a second peak in a range of more than 0.5 μm in pore diameter.

A solid electrolytic capacitor and method for making the capacitor are provided. The capacitor includes a sintered porous anode body formed from a valve metal, a metallic physical vapor deposition (PVD) layer disposed directly on a planar surface of the anode body, a dielectric, a cathode, and anode and cathode terminations. The dielectric overlies at least a portion of the anode body and is also formed within the anode body. The cathode overlies at least a portion of the dielectric that overlies the anode body and includes a solid electrolyte, and a portion of a lower surface of the metallic PVD layer is free of both the dielectric and solid electrolyte. The anode termination is electrically connected to the portion of the lower surface of the metallic PVD layer that is free of both the dielectric and solid electrolyte, and the cathode termination is electrically connected to the solid electrolyte.