The present disclosure relates to a semiconductor device and a manufacturing method, and more particularly to a semiconductor interconnect structure incorporating a graphene barrier layer. The present disclosure provides a method of forming a graphene barrier layer on select surfaces using a self-assembly monolayer (SAM). The SAM layer can be selectively formed on dielectric surfaces and annealed to form thin graphene barrier layers. The thickness of the graphene barrier layers can be selected by choosing different alkyl groups of the SAM layer.

Semiconductor devices are provided which have MIM (metal-insulator-metal) capacitor structures that are integrated within air gaps of on-chip interconnect structures, as well as methods for integrating MIM capacitor formation as part of an air gap process flow for fabricating on-chip interconnect structures. For example, a semiconductor device includes a dielectric layer with a first pattern of metal lines and second pattern of metal lines. Air gaps are disposed in spaces between the metal lines. Portions of the spaces between the metal lines of the first pattern of metal lines include a conformal layer of insulating material disposed on sidewalls of the metal lines and metallic material that fills the spaces between the metal lines. The first pattern of metal lines comprises a first capacitor electrode, the metallic fill material comprises a second capacitor electrode, and the conformal layer of insulating material comprises an insulating layer of a MIM capacitor structure.

An interconnect dielectric material having an opening formed therein is first provided. A surface nitridation process is then performed to form a nitridized dielectric surface layer within the interconnect dielectric material. A metal layer is formed on the nitridized dielectric surface layer and then an anneal is performed to form a metal nitride layer between the metal layer and the nitridized dielectric surface layer. A portion of the originally deposited metal layer that is not reacted with the nitridized dielectric surface is then selectively removed and thereafter an electrical conducting structure is formed directly on the metal nitride layer that is present in the opening.

Methods of forming an interconnect of an IC are disclosed. The methods etch a wire trench opening partially into an ILD layer using a hard mask, and form a metal liner sidewall spacer on sidewalls of the wire trench opening, prior to etching via openings that create a via-wire opening with the wire trench opening. The metal liner sidewall spacer protects against chamfering during the via etch and/or removal of an etch stop layer over conductive structures in an underlying ILD layer. In one embodiment, a barrier liner is deposited over the metal liner sidewall spacer, creating a double layered sidewall spacer on the sidewalls of the wire trench opening portion of the via-wire opening. A conductor is deposited to form a unitary via-wire conductive structure. An interconnect includes the double layered sidewall spacer on the sidewalls of a wire trench opening portion of the via-wire conductive structure.

Methods of forming a self-aligned via comprising recessing a first metallization layer comprising a set of first conductive lines that extend along a first direction on a first insulating layer on a substrate. A second insulating layer is formed on the first insulating layer. A via is formed through the second insulating layer to one of the first conductive lines. Semiconductor devices comprising the self-aligned via and apparatus for forming the self-aligned via are also disclosed.

The present disclosure relates to a semiconductor device and a manufacturing method, and more particularly to a semiconductor interconnect structure incorporating a graphene barrier layer. The present disclosure provides a method of forming a graphene barrier layer on select surfaces using a self-assembly monolayer (SAM). The SAM layer can be selectively formed on dielectric surfaces and annealed to form thin graphene barrier layers. The thickness of the graphene barrier layers can be selected by choosing different alkyl groups of the SAM layer.

Some embodiments relate to a semiconductor device manufacturing process. In the process, a substrate is provided, and a sacrificial layer is formed over the substrate. An opening is patterned through the sacrificial layer, and the opening is filled with conductive material. The sacrificial layer is removed while the conductive material is left in place. A first dielectric layer is formed along sidewalls of the conductive material that was left in place.

An interconnect dielectric material having an opening formed therein is first provided. A surface nitridation process is then performed to form a nitridized dielectric surface layer within the interconnect dielectric material. A metal layer is formed on the nitridized dielectric surface layer and then an anneal is performed to form a metal nitride layer between the metal layer and the nitridized dielectric surface layer. A portion of the originally deposited metal layer that is not reacted with the nitridized dielectric surface is then selectively removed and thereafter an electrical conducting structure is formed directly on the metal nitride layer that is present in the opening.

Advanced dual damascene interconnects that exhibit controlled via resistance and, in some instances, controlled line resistance are provided. In one embodiment, the structure includes an interconnect level having a combined via/line opening located therein. A diffusion barrier liner is located in at least the via portion of the combined via/line opening. A first metallic structure composed of an electrically conductive metal or metal alloy having a first bulk resistivity is located in at least the via portion of the combined via/line opening. A second metallic structure composed of an electrically conductive metal or metal alloy that has a second bulk resistivity that is higher than the first bulk resistivity is located in at least the line portion of the combined via/line opening. In accordance with the present application, second metallic structure is in direct contact with the first metallic structure.

Advanced dual damascene interconnects have been provided in which a metallic seed liner composed of an electrically conductive metal or metal alloy having a first bulk resistivity is located on sidewall surfaces and a bottom wall of a first metallic structure that is present in a via portion of a combined via/line opening that is present in an interconnect dielectric material layer. The first metallic structure is composed of an electrically conductive metal or metal alloy that has a second bulk resistivity that is higher than the first bulk resistivity. In some embodiments, a second metal structure is present on a topmost surface of the first metallic structure. The second metallic structure is composed of an electrically conductive metal or metal alloy that differs from the electrically conductive metal or metal alloy of the first metallic structure.