Described herein are methods of forming an electrocatalyst structure on an electrode, comprising depositing a first layer on the electrode using atomic layer deposition (ALD), wherein the first layer comprises a plurality of discrete nanoparticles of a first electrocatalyst, and depositing one or more of a second layer on the first layer and the electrode using ALD, wherein the one or more second layer comprises a second electrocatalyst, wherein the first layer and the one or more second layers, collectively, form a multi-layer electrocatalyst structure on the electrode. Also described are electrodes having a multi-layer electrocatalyst structure. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

According to an embodiment, a laminated catalyst includes a first catalyst layer mainly including a noble metal mainly containing Pt, a second catalyst layer mainly including a mixture of an oxide of a noble metal mainly containing Ir and Ru and a noble metal mainly containing Pt, and a third catalyst layer mainly including an oxide of a noble metal mainly containing Ir and Ru The first catalyst layer, the second catalyst layer, and the third catalyst layer are laminated in order.

According to embodiments of the present disclosure, a solid oxide fuel cell includes a cathode, an anode, and a solid oxide electrolyte between the anode and the cathode. The solid oxide electrolyte includes a solid oxide, and the anode includes a porous scaffold. The porous scaffold includes a solid oxide having metal-based catalysts disposed on one or more surfaces of the porous scaffold. In embodiments, at least one ammonia decomposition layer is disposed proximate the surface of the porous scaffold and is configured to convert ammonia into hydrogen and nitrogen for subsequent feed of hydrogen to the anode. The ammonia decomposition layer also includes a metal decomposition catalyst.

According to embodiments of the present disclosure, a solid oxide fuel cell includes a cathode, an anode, and a solid oxide electrolyte disposed between the anode and the cathode. The anode includes a porous scaffold that includes a solid oxide having one or more metal nanoparticles disposed on one or more surfaces of the porous scaffold. The porous scaffold and the solid oxide electrolyte are formed from La.sub.0.8Sr.sub.0.2Ga.sub.0.83Mg.sub.0.17O.sub.2.815 (LSGM), and the metal nanoparticles are selected from the group consisting of platinum, nickel, gold, and combinations thereof. Methods of synthesizing ammonia using the fuel cell are also described.

A method for producing a catalyst-coated membrane includes: preparing and/or providing a first ink having a first ink composition, comprising substrated catalyst particles proton-conducting ionomer and dispersing agent, in which the fraction of the substrated catalyst particles remains behind the fraction of the proton-conducting ionomer; preparing and/or providing at least one second ink having a second ink composition, comprising the substrated catalyst particles, the proton-conducting ionomer and the dispersing agent, in which the fraction of the proton-conducting ionomer remains behind the fraction of the substrated catalyst particles, unwinding a weblike proton-conducting membrane material provided on a roll; applying at least one layer of the first ink with a first application tool onto at least one section of the membrane material; and applying at least one layer of the second ink with a second application tool onto an outermost layer of the first ink deposited onto the membrane material

A fuel cell membrane-electrode assembly includes a support material including a ceramic material and iridium oxide, wherein a weight fraction of iridium oxide, based on metallic iridium, with respect to the total weight of the support material, is at most 50 wt%, and the support material has a weight loss of less than 3 wt%, based on the weight fraction of the iridium oxide on exposure of the support material to a 3.3 vol% hydrogen stream in argon at a temperature of 80° C. for 12 hours.

The catalyst for electrodes comprises: a porous support which has nanopores having a pore diameter of from 1 nm to 20 nm and micropores having a pore diameter of less than 1 nm; and a plurality of catalyst particles which are supported by the support. The catalyst particles are supported by both inner portions and outer portions of mesopores of the support, and contain Pt (zerovalent). If an analysis of the particle size distribution of the catalyst particles is performed using three-dimensional reconstructed images obtained through a STEM-based electron tomography measurement, the condition of formula (S1), namely (100×(N10/N20)≤8.0) is satisfied, where N10 represents the number of noble metal particles that are not in contact with pores having a pore diameter of 1 nm or more; and N20 represents the number of catalyst particles that are supported by the inner portions of the nanopores of the support.

A membrane electrode assembly (MEA) includes an ionically-conductive proton exchange membrane. Further, the MEA includes an anode contacting a first side of the membrane. The anode includes an anode gas diffusion layer (GDL). Further, the anode includes a first anode catalyst layer containing first catalyst particles, a hydrophobic polymer bonding agent, and a first ionomer bonding agent that lacks functional chains on a molecular backbone. The anode also includes a second anode catalyst layer containing second catalyst particles and a second ionomer bonding agent that includes functional chains on a molecular backbone. The MEA also includes a cathode contacting a second side of the membrane and comprising third catalyst particles and a cathode GDL.

The manufacturing method of a palladium transition metal core-based core-shell electrode catalyst according to an exemplary embodiment of the present disclosure includes a first step of preparing a slurry by irradiating ultrasonic wave to a dispersion solution including a solvent, a platinum precursor, a palladium precursor, a carbon support, and a transition metal precursor, a second step of preparing a solid material by filtering, washing, and drying the slurry prepared in the first step, and a third step of preparing a core-shell electrode catalyst by thermally treating the solid prepared in the second step in a specific gas atmosphere.

In one aspect, the disclosure relates to method of forming an electrocatalyst structure on an electrode, comprising depositing a first layer on the electrode using atomic layer deposition (ALD), wherein the first layer comprises a plurality of discrete nanoparticles of a first electrocatalyst, and depositing one or more of a second layer on the first layer and the electrode using ALD, wherein the one or more second layer comprises a second electrocatalyst, wherein the first layer and the one or more second layers, collectively, form a multi-layer electrocatalyst structure on the electrode. Also disclosed are electrodes having a multi-layer electrocatalyst structure. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.