Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated CO.sub.2 utilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated CO.sub.2 utilization.

A redox flow battery system includes an anolyte having a first ionic species in solution; a catholyte having a second ionic species in solution, where the redox flow battery system is configured to reduce the first ionic species in the anolyte and oxidize the second ionic species in the catholyte during charging; a first electrode in contact with the anolyte, where the first electrode includes channels for collection of particles of reduced metallic impurities in the anolyte; a second electrode in contact with the catholyte; and a separator separating the anolyte from the catholyte. A method of reducing metallic impurities in an anolyte of a redox flow battery system includes reducing the metallic impurities in the anolyte; collecting particles of the reduced metallic impurities; and removing the collected particles using a cleaning solution.

A system for estimating a concentration of hydrogen in a fuel cell is provided. The system includes a hydrogen supply line supplying the hydrogen to the fuel cell and a time measurement sensor measuring a time duration from a point in time when an operation of the fuel cell ends to a point in time when the fuel cell restarts. A controller estimates an amount of air introduced into the fuel cell during the time duration using the measured time duration and estimates a concentration of hydrogen in the hydrogen supply line at the time of restarting the fuel cell based on the measured time duration and the estimated amount of introduced air.

The fuel cell system includes a fuel cell arranged to receive ambient air at a cathode inlet, and a tank arrangement fluidly connectable to the cathode inlet. The fuel cell system is configured to supply oxygen based fluid from the tank arrangement when a toxic substance level of the ambient environment is above the predetermined threshold limit.

A system and method for cooling and humidifying a cathode subsystem of a fuel cell for an automobile. The system includes a compressor, an air input line including an intercooler configured to cool air output by the compressor, a fluid output line including a fluid injection system, a cathode stack configured to receive air via the air input line and output a fluid to the fluid output line, and an electronic processor. The electronic processor is configured to control the fluid injection system such that the fluid output from the cathode stack is injected into the air input line.

Methods of determining concentrations and/or amounts of redox-active elements at each valence state in an electrolyte solution of a redox flow battery are provided. Once determined, the concentrations and/or amounts of the redox-active elements at each valence state can be used to determine side-reactions, make chemical adjustments, periodically monitor battery capacity, adjust performance, or to otherwise determine a baseline concentration of the redox-active ions for any purpose.

The invention relates to a method for switching off a fuel cell system (100) having a fuel cell stack (10), that has anode chambers (13) and cathode chambers (12), and a cathode supply (20) having a cathode supply path (21) for supplying an oxygenated cathode operating gas into the cathode chambers (12), a compressor (23) arranged in the cathode supply path(21) and a cathode exhaust path (22) for discharging a cathode exhaust gas from the cathode chambers (12).

The method comprises the steps of:

(a) Maintenance of the cathode chambers (12) under excess pressure while preventing a flow of cathode operating gas through the cathode chambers (12) while keeping the cathode operating gas that is present in the cathode chambers (12) oxygen-depleted;

(b) Expansion of the oxygen-depleted cathode operating gas present in the cathode chambers (12) via the cathode supply path (31) [sic] and/or the cathode exhaust path (22), and

(c) Separation of the cathode chambers (12) from the environment.

Systems and methods for improving conditions for anion contaminant removal in a cathode of a PEMFC system are presented. A fuel cell system consistent with certain embodiments may include a cathode compartment having a compressor coupled thereto. The compressor may be configured to receive an input cathode gas via a compressor input and supply the input cathode gas to the cathode compartment via a compressor output. The fuel cell system may further include a cathode gas recirculation value coupled to the cathode compartment configured to receive a cathode exhaust gas output and to selectively provide at least a portion of the cathode exhaust gas output to the compressor input. Consistent with certain embodiments disclosed herein, the compressor may be further configured to supply at least a portion of the cathode exhaust gas output to the cathode compartment via the compressor output.

A Method and device for measurement is disclosed in operation, an undivided cell sensor immersed at any desirable point of the positive electrolyte circuit is constantly supplied at a controlled fixed DC bias voltage between the positive metal electrode and the porous carbon counter-electrode by an appropriate voltage regulator of adequate power capability, or cyclically at two or more different voltages, all within a range that includes the region between 0.35V and 0.45V, measuring simultaneously the current flowing across the undivided cell sensor at the fixed voltage or voltages bias. By correlating the paired voltage and current values, using a look up table compiled at calibration, estimated values of the degree of oxidation or state of charge of the redox ion couple of the positive electrolyte solution are produced.

A diagnostic system for determining the cathode gas quality of a fuel cell system has a fuel cell stack, with a diagnostic fuel cell which can be connected at the cathode side to a cathode supply line and at the anode side to an anode supply line of the fuel cell system. The diagnostic system furthermore comprises a detection unit which is configured to detect a measured value or the measured value time curve of the diagnostic fuel cell operating with the cathode gas provided via the cathode supply line and with the anode gas provided via the anode supply line. The present disclosure moreover relates to a fuel cell system having a diagnostic system, and to a corresponding method.