Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

A bipolar plate for an electrochemical reactor, including at least one anode sheet and one cathode sheet, each having an internal face and an external face, the anode and cathode sheets being in contact with each other via their internal face, each anode and cathode sheet including, on its external face, channels for circulating reactive fluids, the channels demarcating, at the internal faces of the anode and cathode sheets, cooling pipes for a flow of a heat transfer fluid, the channels of the anode and cathode sheets including alternating bosses and indentations, the bosses of the anode sheet being arranged in a staggered manner and the bosses of the cathode sheet being arranged in a staggered manner.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

A hydrogen generation electricity system for producing electricity from hydrogen using a hydrogen carrier substance, comprising: a reaction chamber arranged for generating a H2 gas stream by converting the hydrogen carrier substance; wherein the reaction chamber comprises an inlet arranged for receiving the hydrogen carrier substance; an output conduit for exiting the H2 gas stream; a fuel cell arranged for producing electric energy by converting hydrogen; the output conduit is arranged for supplying the H2 gas stream from the reaction chamber to the fuel cell; the system further comprising: a humidity determining unit arranged for determining a humidity level of the H2 gas stream; a water providing means for providing H2O to the reaction chamber; and a water vapour control means arranged for controlling the water vapour level in the reaction chamber, in response to the determined humidity level, wherein the generated H2 gas stream comprises hydrogen and water vapour.

A hydrogen production system comprises a hydrogen pyrolysis reactor which has a hydrocarbon input, an electrical input and at least one hydrogen output. The hydrogen production system also comprises a hydrogen-fuelled generator. Means are provided to route part of the hydrogen from one of the at least one hydrogen outputs to the hydrogen-fuelled generator. The hydrogen-fuelled generator then generates an electrical output, which is routed to the electrical input of the hydrocarbon pyrolysis reactor. A related method of operating a hydrogen production system is also described.

The present disclosure relates generally to portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power. In particular, an electricity generation device for powering a battery comprising a formic acid reservoir containing a liquid consisting of formic acid; a reaction chamber capable of using a catalyst and heat to convert the formic acid to hydrogen and carbon dioxide; a fuel cell that generates electricity; a delivery system for moving converted hydrogen into the fuel cell; and a battery powered by electricity generated by the fuel cell is provided.

An apparatus includes an integrated heat exchanger and reactor module. The integrated heat exchanger and reactor module includes a heat exchanger channel, and a reactor channel which is thermally coupled to the heat exchanger channel. The reactor channel includes a layer of catalyst material that is configured to produce hydrogen by endothermic catalytic decomposition of ammonia, which flows through the reactor channel, using thermal energy that is absorbed by the reactor channel from the heat exchanger channel.

A fuel cell system comprising a fuel cell stack, an evaporator for evaporating a mixture of methanol and water to be forwarded through a catalytic reformer for producing portions of free hydrogen. The fuel cell stack being composed of a number of proton exchange membrane fuel cells each featuring electrodes in form of an anode and a cathode for delivering an electric current. The system provides an enhanced system for evaporating the liquid fuel using a pre-evaporator, which partly evaporates the fuel, followed by a nozzle, which atomizes the fuel into a fine mist, before being passed to the final evaporation zone. This configuration ensures minimal fuel accumulation in the system and fast load transition's.

A preparation method of a direct ethanol fuel cell includes synthesizing electrolytes, preparing a cathode and an anode, and clamping the electrolytes between the cathode and the anode to get direct ethanol fuel cell. The electrolytes are synthesized by polymerizing sodium acrylate with an initiator to get a hydrogel, and the hydrogel is soaked in a harsh alkaline solution. The cathode is synthesized by coating N,S codoped carbon catalyst onto a current collector, where the N,S codoped carbon catalyst is synthesized by mixing and preheating silica powder, sucrose and trithiocyanuric acid to get a mixed powder, and mixing and heating the mixed powder with poly tetra fluoroethylene so as to get the N,S codoped carbon catalyst. The anode is synthesized by coating Pt-Ru/C catalyst onto a current collector.

An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an in oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.